Diethylzinc solution - 1.0 M in Hexane , CAS No.557-20-0

CAS: 557-20-0 Cat. No.: D107431 Peso molecular: 123.51 Beilstein Registry Number: 3587207 Número EC: 209-161-3

GRADE & PURITY 1.0 M in Hexane

Synonyms

AC-1790 | EINECS 209-161-3 | (C2H5)2Zn | DTXSID4052217 | MFCD00009021 | HQWPLXHWEZZGKY-UHFFFAOYSA-N | Zinkdiethyl | Diethylzinc, purum, >=95.0% (KT) | Zinc diethyl | Zn(C2H5)2 | AKOS009145267 | Diethylzinc, elec. gr. | zinc;ethane | CHEBI:51496 | UNII-S0W

Storage

Room temperature,Argon charged

Shipped In

FedEx DG Service

Descripción general

Employed together with a Rh (I) catalyst to prepare α-trifluoromethyl ketones from α,β-unsaturated ketones.

Diethylzinc solution can be used as a reagent to prepare:

• α-trifluoromethyl ketones from α, β-unsaturated ketones with Rh (I) catalyst.

• Alkynylzinc reagents which are used in cross-coupling reactions.

• Chiral secondary alcohols from aromatic and aliphatic aldehydes in presence of camphor-derived β-amino alcohol.

• 1, 4 conjugate addition product with enones.

• α-fluoroacrylates from aldehydes and ketones.

Specifications

Sinónimos

AC-1790 | EINECS 209-161-3 | (C2H5)2Zn | DTXSID4052217 | MFCD00009021 | HQWPLXHWEZZGKY-UHFFFAOYSA-N | Zinkdiethyl | Diethylzinc, purum, >=95.0% (KT) | Zinc diethyl | Zn(C2H5)2 | AKOS009145267 | Diethylzinc, elec. gr. | zinc;ethane | CHEBI:51496 | UNII-S0W

Especificaciones y pureza

1.0 M in Hexane

Condiciones de almacenamiento de almacenamiento

Room temperature, Argon charged

Enviado en

FedEx DG Service

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Nota

The diethylzinc reagent in the alkane system will produce zinc powder precipitation, shaking and turbidity, which is a product characteristic and does not affect the activity of conventional use

Nombres e identificadores

• Isómeros SMILES: C[CH2-].C[CH2-].[Zn+2]
• WGK Alemania: 2
• Número ONU: 1366
• Peso molecular: 123.51
• Beilstein: 3587207
• Reaxy-Rn: 16917908
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=16917908&ln=

Propiedades químicas y físicas

• Solubilidad: It is miscible with ether, benzene, and petroleum ether.
• Sensibilidad: Air sensitive, Moisture Sensitive
• Índice de refracción: 1.5
• Punto de inflamación (°F): -9.4 °F
• Punto de inflamación (°C): -18 °C
• Punto de ebullición (°C): 124°
• Punto de fusión (°C): -28°
• Peso molecular: 123.500 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 122.007 Da
• Monoisotopic Mass: 122.007 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 3.600
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

XLogP3

Referencias

1. Yuhe Bi, Sheng Cao, Peng Yu, Zhentao Du, Yunjun Wang, Jinju Zheng, Bingsuo Zou, Jialong Zhao.  (2023)  Reducing Emission Linewidth of Pure-Blue ZnSeTe Quantum Dots through Shell Engineering toward High Color Purity Light-Emitting Diodes.  Small,  19  (45): (2303247).  [PMID:37420332] [10.1002/smll.202303247]

2. Linfeng Li, Yaoqi Huang, Wenbin Li, Liyi Zou, Xi Wu, Yuanyuan Li, Xiaomin Cheng.  (2023)  Regulation of thermal conductivity of microencapsulated phase change materials via atomic layer deposition.  Journal of Energy Storage,      [PMID:] [10.1016/j.est.2023.107668]

3. Xingfang Xiao, Bowen Zhang, Pei Lyu, Fengxiang Chen, Qian Zhang, Jiuxiao Sun, Zhan Jiang, Xin Liu, Weilin Xu.  (2022)  Controllable coating of zinc oxide on protein-based fibers/fabrics for superior antibacterial performance preserving wearable abilities.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2022.155487]

4. Linfeng Li, Xi Wu, Xiaomeng Zhu, Yuanyuan Li, Liyi Zou, Xiuli Wang, Wenbin Li, Xiaomin Cheng.  (2022)  ZnO-Reinforced Thermal Regulating Microcapsules with Double-Layer Shell via Atomic Layer Deposition.  Advanced Materials Interfaces,  9  (17): (2200541).  [PMID:] [10.1002/admi.202200541]

5. Linfeng Li, Pengju Yu, Yuanyuan Li, Xi Wu, Wenbin Li, Xiaomin Cheng.  (2021)  A Facile Approach to Fabricating Antibacterial Textile with High Efficiency and Compact Process.  Advanced Materials Interfaces,  8  (21): (2101197).  [PMID:] [10.1002/admi.202101197]

6. Chi Ma, Chengxiang Shi, Yakun Liu, Lun Pan, Xiangwen Zhang, Ji-Jun Zou.  (2021)  Synthesis and Performance of Strained Multicyclic Hydrocarbons as Highly Potential High-Energy-Density Fuels.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.1c00734]

7. Hongcheng Yang, Yizun Liu, Junjie Hao, Haodong Tang, Shihao Ding, Zhaojin Wang, Fan Fang, Dan Wu, Wenda Zhang, Haochen Liu, Bing Xu, Rui Lu, Lei Yang, Pai Liu, Kai Wang, Xiao Wei Sun.  (2021)  Alloyed Green-Emitting CdZnSeS/ZnS Quantum Dots with Dense Protective Layers for Stable Lighting and Display Applications.  ACS Applied Materials & Interfaces,      [PMID:34184525] [10.1021/acsami.1c07647]

8. Li Yunxia, Du Wenjuan, Fu Zhiguang, Wang Huanhuan, Wang Jiexin, Le Yuan, Zhang Jianjun, Wen Ning.  (2018)  pH-Responsive Polycarbonate Copolymer-based Nanoparticles for Targeted Anticancer Drug Delivery.  CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,  34  (6): (1041-1050).  [PMID:] [10.1007/s40242-018-8147-5]

9. Ning Li, Yu Tian, Jianhui Zhao, Wei Zhan, Jinying Du, Lingchao Kong, Jun Zhang, Wei Zuo.  (2018)  Ultrafast selective capture of phosphorus from sewage by 3D Fe3O4@ZnO via weak magnetic field enhanced adsorption.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2018.02.029]

10. Yang Yi, Song Haiping, He Dan, Zhang Shuai, Dai Shizhong, Lin Shixian, Meng Rong, Wang Chu, Chen Peng R..  (2016)  Genetically encoded protein photocrosslinker with a transferable mass spectrometry-identifiable label.  Nature Communications,  7  (1): (1-10).  [PMID:27460181] [10.1038/ncomms12299]

11. Liu Bo, Liu Dong-tao, Li Shi-hui, Sun Guang-ping, Cui Dong-mei.  (2015)  High trans-1,4 (co)polymerization of β-myrcene and isoprene with an iminophosphonamide lanthanum catalyst.  CHINESE JOURNAL OF POLYMER SCIENCE,  34  (1): (104-110).  [PMID:] [10.1007/s10118-016-1729-0]

12. Ruiduan Li, Jianjun Zhang, Jianfeng Chen, Wei Teng, Jiexin Wang, Caixia Li.  (2014)  Preparation and Characterization of Biological Non-toxic Hybrid Nanoparticles Based on Lactide and Poly(ethylene glycol) Loading Docetaxel for Anticancer Drug Delivery.  CHINESE JOURNAL OF CHEMICAL ENGINEERING,      [PMID:] [10.1016/j.cjche.2014.09.012]

13. Li Chao, Ji Yang, Wang Can, Liang Shujing, Pan Fei, Zhang Chunlei, Chen Feng, Fu Hualin, Wang Kan, Cui Daxiang.  (2014)  BRCAA1 antibody- and Her2 antibody-conjugated amphiphilic polymer engineered CdSe/ZnS quantum dots for targeted imaging of gastric cancer.  Nanoscale Research Letters,  9  (1): (1-13).  [PMID:24940175] [10.1186/1556-276X-9-244]

14. An-lin Zhang, Li-wen Yang, Nian-fa Yang, Yan-ling Liu.  (2014)  The synthesis of chiral amino diol tridentate ligands and their enantioselective induction during the addition of diethylzinc to aldehydes.  TETRAHEDRON-ASYMMETRY,      [PMID:] [10.1016/j.tetasy.2013.11.007]

15. Bo Chen, Wanmeng Wang, Meilin Hu, Yunkai Liang, Ning Wang, Changyi Li, Ying Li.  (2024)  “Photo-Thermo-Electric” Dental Implant for Anti-Infection and Enhanced Osteoimmunomodulation.  ACS Nano,      [PMID:39192736] [10.1021/acsnano.4c05859]

16. Zhiyu Huang, Aixin Tong, Tonghe Xing, Annan He, Yuxin Luo, Yu Zhang, Mengqi Wang, Sijie Qiao, Zhicheng Shi, Fengxiang Chen, Weilin Xu.  (2024)  A triple-crosslinking strategy for high-performance regenerated cellulose fibers derived from waste cotton textiles.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:38471604] [10.1016/j.ijbiomac.2024.130779]

17. Yu Zhang, Tonghe Xing, Zhiyu Huang, Annan He, Yuxin Luo, Ying Hong, Mengqi Wang, Zhicheng Shi, Aixin Tong, Sijie Qiao, Guizhen Ke, Tao Zhao, Fengxiang Chen, Weilin Xu.  (2024)  An innovative strategy towards highly efficient flame-retardant silk.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.151356]

18. Bi Yuhe, Sun Jianhui, Cao Sheng, Li Qiuyan, Zheng Jinju, Yuan Xi, Wang Yunjun, Zou Bingsuo, Zhao Jialong.  (2025)  Highly efficient and eco-friendly green quantum dot light-emitting diodes through interfacial potential grading.  Nature Communications,  16  (1): (1-10).  [PMID:39994198] [10.1038/s41467-025-57304-9]

19. Yinghao Xu, Yaoqi Huang, Linfeng Li, Muyang Gu, Yuanyuan Li, Xiaomin Cheng.  (2024)  Modulation and optimisation of the properties of n-decanoic acid-tetradecanol phase change materials by nanocomposite carbon materials prepared by atomic layer deposition methods.  Materials Today Communications,      [PMID:] [10.1016/j.mtcomm.2024.108650]

20. Sijie Qiao, Zhicheng Shi, Yu Zhang, Gengrun Zhang, Zhiyu Huang, Annan He, Ming Chen, Guizhen Ke, Jia Yuan, Shichang Chen, Fengxiang Chen.  (2025)  Colorful polyester with high-efficiency flame retardant and anti-dripping properties.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.166544]

21. Mingrui Liu, Guangmin Li, Shunsheng Wei, Hongfei Liu, Gaoling Yang.  (2025)  Ligand-Induced Chiroptical Properties in Nanocrystals with Different Core–Shell Band Structures.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.4c06205]

22. Dongfang Zhao, Tianqi Li, Lihang Jiang, Zheng Li, Zhibo Li.  (2026)  Selective Synthesis and Polymerization of Methyl-1,4-dioxan-2-one toward Closed-Loop Recyclable Poly(ether-alt-ester) from Methyl Glycolate and Propylene Oxide.  BIOMACROMOLECULES,      [PMID:41706116] [10.1021/acs.biomac.5c02468]