Dimethylketene Methyl Trimethylsilyl Acetal - ≥95%(GC) , CAS No.31469-15-5

CAS: 31469-15-5 Cat. No.: D155637 Peso molecular: 174.32 Beilstein Registry Number: 1362890 Número EC: 629-515-4

GRADE & PURITY ≥95%(GC)

Synonyms

MTDA | 1-Propene, 1-methoxy-2-methyl-1-(trimethylsilyloxy)- | 1-Methoxy-2-methylprop-1-en-1-ol, TMS derivative | [(1-methoxy-2-methylprop-1-en-1-yl)oxy]trimethylsilane | Methyl trimethylsilyl dimethylketene acetal, 95% | BCP18684 | (R)-2-[[6-(3-Amino-1-pi

Storage

Room temperature

Shipped In

Normal

Specifications

Sinónimos

MTDA | 1-Propene, 1-methoxy-2-methyl-1-(trimethylsilyloxy)- | 1-Methoxy-2-methylprop-1-en-1-ol, TMS derivative | [(1-methoxy-2-methylprop-1-en-1-yl)oxy]trimethylsilane | Methyl trimethylsilyl dimethylketene acetal, 95% | BCP18684 | (R)-2-[[6-(3-Amino-1-pi

Especificaciones y pureza

≥95%(GC)

Condiciones de almacenamiento de almacenamiento

Room temperature

Enviado en

Normal

Pureza

≥95%(GC)

Nombres e identificadores

• Pubchem Sid: 504759232
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504759232
• Sonrisas canónicas: CC(=C(OC)O[Si](C)(C)C)C
• IUPAC Name: (1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
• InChIKey: JNOGVQJEBGEKMG-UHFFFAOYSA-N
• INCHI: 1S/C8H18O2Si/c1-7(2)8(9-3)10-11(4,5)6/h1-6H3
• Isómeros SMILES: CC(=C(OC)O[Si](C)(C)C)C
• WGK Alemania: 3
• Número ONU: 3271
• Grupo de embalaje: III
• Peso molecular: 174.32
• Beilstein: 1362890
• Reaxy-Rn: 1362893
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1362893&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Clase Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Clase: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes
• Direct Parent: Trialkylheterosilanes
• Alternative Parents: Ketene silyl acetals Ketene acetals Silyl enol ethers Organic metalloid salts Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylheterosilane - Ketene silyl acetal - Ketene acetal or derivatives - Organic metalloid salt - Silyl enol ether - Organic oxygen compound - Hydrocarbon derivative - Organic salt - Organooxygen compound - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Moisture Sensitive
• Índice de refracción: 1.42
• Punto de inflamación (°F): 86 °F
• Punto de inflamación (°C): 30 °C
• Punto de ebullición (°C): 52 °C/22 mmHg
• Peso molecular: 174.310 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 174.108 Da
• Monoisotopic Mass: 174.108 Da
• Topological Polar Surface Area: 18.500 Ų
• Heavy Atom Count: 11
• Formal Charge: 0
• Complexity: 152.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

Referencias

1. Chenmin Yao, Jian Yu, Yake Wang, Chuliang Tang, Cui Huang.  (2018)  Acidic pH weakens the bonding effectiveness of silane contained in universal adhesives.  DENTAL MATERIALS,      [PMID:29525358] [10.1016/j.dental.2018.02.004]