GRADE & PURITY ≥98%

Synonyms

FT-0625267 | Iodonium, diphenyl-, hexafluorophosphate(1-) | AKOS015833806 | diphenyliodanium;hexafluorophosphate | SY101117 | W-105410 | Diphenyliodonium hexafluorophosphate(V) | D2238 | Iodonium, diphenyl-, hexafluorophosphate(1-) (1:1) | A831742 | Iodon

Storage

Protected from light,Room temperature,Argon charged

Shipped In

Normal

Descripción general

Descripción del producto:

Catalizador para la polimerización fotoquímica de diversos monómeros.
Fotoiniciador catiónico. Generador de fotoácidos.

Aplicación del producto：

El hexafluorofosfato de difeniliodonio se utiliza como fotoiniciador catiónico y generador de fotoácidos. Actúa como catalizador para la polimerización fotoquímica de varios monómeros. Además, se utiliza como reactivo arilante y oxidante en síntesis orgánica.

Specifications

Sinónimos

FT-0625267 | Iodonium, diphenyl-, hexafluorophosphate(1-) | AKOS015833806 | diphenyliodanium;hexafluorophosphate | SY101117 | W-105410 | Diphenyliodonium hexafluorophosphate(V) | D2238 | Iodonium, diphenyl-, hexafluorophosphate(1-) (1:1) | A831742 | Iodon

Especificaciones y pureza

≥98%

Condiciones de almacenamiento de almacenamiento

Protected from light, Room temperature, Argon charged

Enviado en

Normal

Pureza

≥98%

Nombres e identificadores

• Pubchem Sid: 504761358
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504761358
• Sonrisas canónicas: C1=CC=C(C=C1)[I+]C2=CC=CC=C2.F[P-](F)(F)(F)(F)F
• IUPAC Name: diphenyliodanium;hexafluorophosphate
• InChIKey: DSSRLRJACJENEU-UHFFFAOYSA-N
• INCHI: 1S/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-7(2,3,4,5)6/h1-10H;/q+1;-1
• Isómeros SMILES: C1=CC=C(C=C1)[I+]C2=CC=CC=C2.F[P-](F)(F)(F)(F)F
• WGK Alemania: 3
• PubChem CID: 2737136
• Peso molecular: 426.08
• Beilstein: 4343861
• Reaxy-Rn: 4224192

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Halobenzenes

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Halobenzenes
• Intermediate Tree Nodes: Not available
• Direct Parent: Iodobenzenes
• Alternative Parents: Aryl iodides Organoiodides Organic salts Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Iodobenzene - Aryl iodide - Aryl halide - Hydrocarbon derivative - Organic salt - Organoiodide - Organohalogen compound - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as iodobenzenes. These are aromatic compounds containing one or more iodine atoms attached to a benzene.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.
• Sensibilidad: Light and Moisture sensitive
• Punto de fusión (°C): 139-144℃
• Peso molecular: 426.080 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 2
• Exact Mass: 425.947 Da
• Monoisotopic Mass: 425.947 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 20
• Formal Charge: 0
• Complexity: 179.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

1. Jia Liu, Junxia Deng, Fangzheng Zhao, Tong Wu, Jinfeng Xing.  (2023)  A highly stretchable, adhesive, anti-freezing hydrogel with prominent antibacterial property rapidly prepared by photopolymerization for wound dressing.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2023.133087]

2. Siyuan Yu, Yanting Zhou, Chunyue Zhao, Han Liu, Zhiyun Xue, Jinfeng Xing.  (2023)  Rapid fabrication of monodisperse PMMA microspheres through dispersion photopolymerization under green LED irradiation.  REACTIVE & FUNCTIONAL POLYMERS,      [PMID:] [10.1016/j.reactfunctpolym.2023.105594]

3. Zonghua Wang, Xiaoran Zhang, Shuo Yao, Jiaxin Zhao, Chuanjian Zhou, Junling Wu.  (2022)  Development of low-shrinkage dental adhesives via blending with spiroorthocarbonate expanding monomer and unsaturated epoxy resin monomer.  Journal of the Mechanical Behavior of Biomedical Materials,      [PMID:35709601] [10.1016/j.jmbbm.2022.105308]

4. Junjie Li, Yuanyuan Peng, Jhair Peña, Jinfeng Xing.  (2021)  An initiating system with high efficiency for PEGDA photopolymerization at 532 nm.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,      [PMID:] [10.1016/j.jphotochem.2021.113216]

5. Negar Mahmoudi Meimand, James Kit Hon Tsoi, Michael Francis Burrow, Jingwei He, Kiho Cho.  (2024)  A comparative study on the mechanical and antibacterial properties of BPA-free dental resin composites.  DENTAL MATERIALS,      [PMID:38926013] [10.1016/j.dental.2024.06.024]

6. Mingyue Wu, Guohui Wang, Mihan Zhang, Jinchao Li, Chenglong Wang, Guangdong Sun, Jinhuan Zheng.  (2024)  A Tough and Piezoelectric Poly (acrylamide/ N, N-dimethylacrylamide) Hydrogel-based Flexible Wearable Sensors.  Soft Matter,      [PMID:39148339] [10.1039/D4SM00363B]

7. Shuotian Wang, Haizhi Dou, Yanjing Gao, Fang Sun.  (2024)  Enhanced photopolymerization and properties of UV-cured films with a tetrafunctional oxetane-based organosilicon monomer.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2024.108821]

8. Jiahui Li, Boxuan Peng, Siyuan Yu, Fangzheng Zhao, Qiqi Han, Shuaibing Huang, Fengmin Jin, Jinfeng Xing.  (2024)  P(AAS-co-AMPS-Na)/SA/laponite composite hydrogel beads with excellent performance prepared by photopolymerization under green LED irradiation for adsorption of malachite green.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2024.128990]

9. Mei Wu, Xin Zhao, Bowen Li, Wenhao Zhang, Hao Zeng, Xuao Zhang, Weichuan Xu, Lingling Bi, Zhiqiang Chen, Jinlong Jiang.  (2024)  Photochemical synthesis of hierarchical adsorbents for gaseous iodine capture and storage.  JOURNAL OF SOLID STATE CHEMISTRY,      [PMID:] [10.1016/j.jssc.2024.124904]

10. Siyuan Yu, Xian Shao, Tong Wu, Zheng Liu, Pei Yu, Jinfeng Xing.  (2024)  Preparation of PMMA-Based Temperature/pH Responsive Nanoparticles Encapsulating 5-Fluorouracil and Methotrexate In Situ by One-Pot Dispersion Photopolymerization.  MACROMOLECULAR BIOSCIENCE,      [PMID:38197551] [10.1002/mabi.202300469]

11. Fangzheng Zhao, Junxia Deng, Tong Wu, Jia Liu, Rijie Wang, Jinfeng Xing.  (2024)  Terpolymer-Hydroxyapatite Hybrid Hydrogel Prepared by Photopolymerization Under Green LED Irradiation for Wound Hemostasis.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.3c02901]

12. Qingyun Liu, Boxuan Peng, Jiahui Li, Fangzheng Zhao, Enchang Liu, Huizhen Han, Tong Wu, Jinfeng Xing.  (2025)  Double-network carboxymethyl chitosan/chondroitin sulfate hydrogel microspheres prepared by green-LED-triggered droplet photopolymerization for malachite green adsorption.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:40816399] [10.1016/j.ijbiomac.2025.146898]

13. Rosalind Sin Man Chan, Sang Jin Lee, Fang Wang, Tianyu Zhou, Ravi Kishan, Ho Cheung Shum, Weifa Yang, Yu-xiong Su, James Kit Hon Tsoi, Ashish D. Diwan, B. Gangadhara Prusty, Kiho Cho.  (2025)  Engineered 3D-Printable Nanohydroxyapatite Biocomposites with Cold Plasma-Tailored Surface Features to Boost Osseointegration.  ACS Applied Materials & Interfaces,      [PMID:40223336] [10.1021/acsami.4c22032]

14. Zhongyuan Wu, Yuwei Zhao, Aihua Li, Ting Wang, David C. Watts, Nicholas G. Fischer, Hang Wang, Jing Fu.  (2025)  Engineering a Self-Defensive Restoration-Tooth Interface via Bioactive nMgO/E-POSS Bulk-Fill Resin Composites for Enhanced Dental Restorations.  Advanced Healthcare Materials,      [PMID:41292415] [10.1002/adhm.202502057]