Glufosinate-ammonium - analytical standard , CAS No.77182-82-2

CAS: 77182-82-2 Cat. No.: G114499 Peso molecular: 198.16 Beilstein Registry Number: 8163399 Número EC: 278-636-5

GRADE & PURITY Analytical standard

Synonyms

2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid amine | F20360 | SCHEMBL15668 | Glufosinate ammonium, 95% | Ammonium 2-amino-4(hydroxymethylphosphinyl)butanoate | HY-W019870 | azanium;2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid | Glufosinate-amm

Storage

Room temperature

Shipped In

Normal

Specifications

Sinónimos

2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid amine | F20360 | SCHEMBL15668 | Glufosinate ammonium, 95% | Ammonium 2-amino-4(hydroxymethylphosphinyl)butanoate | HY-W019870 | azanium;2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid | Glufosinate-amm

Especificaciones y pureza

analytical standard

Condiciones de almacenamiento de almacenamiento

Room temperature

Enviado en

Normal

Grado

Analytical standard

Nombres e identificadores

• Sonrisas canónicas: CP(=O)(CCC(C(=O)O)N)O.N
• IUPAC Name: 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid;azane
• InChIKey: ZBMRKNMTMPPMMK-UHFFFAOYSA-N
• INCHI: 1S/C5H12NO4P.H3N/c1-11(9,10)3-2-4(6)5(7)8;/h4H,2-3,6H2,1H3,(H,7,8)(H,9,10);1H3
• Isómeros SMILES: CP(=O)(CCC(C(=O)O)N)O.N
• WGK Alemania: 1
• RTECS: EK7713600
• Peso molecular: 198.16
• Beilstein: 8163399
• Reaxy-Rn: 8163399
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=8163399&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic acids and derivatives
    • Clase Carboxylic acids and derivatives
      • Subclass Amino acids, peptides, and analogues
        • Level5 Amino acids and derivatives
          • Level6 Alpha amino acids and derivatives
            • Level7 Alpha amino acids

• Kingdom: Organic compounds
• Superclass: Organic acids and derivatives
• Clase: Carboxylic acids and derivatives
• Subclass: Amino acids, peptides, and analogues
• Intermediate Tree Nodes: Amino acids and derivatives - Alpha amino acids and derivatives
• Direct Parent: Alpha amino acids
• Alternative Parents: Fatty acids and conjugates Carboxylic acid salts Amino acids Monocarboxylic acids and derivatives Carboxylic acids Organopnictogen compounds Organophosphorus compounds Organic zwitterions Organic salts Organic oxides Monoalkylamines Hydrocarbon derivatives Carbonyl compounds
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Alpha-amino acid - Fatty acid - Carboxylic acid salt - Amino acid - Carboxylic acid - Monocarboxylic acid or derivatives - Organic nitrogen compound - Hydrocarbon derivative - Organic salt - Organic zwitterion - Primary amine - Organophosphorus compound - Organooxygen compound - Organonitrogen compound - Organic oxide - Primary aliphatic amine - Organopnictogen compound - Organic oxygen compound - Carbonyl group - Amine - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as alpha amino acids. These are amino acids in which the amino group is attached to the carbon atom immediately adjacent to the carboxylate group (alpha carbon).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Punto de inflamación (°F): >100 °C
• Punto de inflamación (°C): >100°C
• Punto de fusión (°C): 215°C
• Peso molecular: 198.160 g/mol
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 198.077 Da
• Monoisotopic Mass: 198.077 Da
• Topological Polar Surface Area: 102.000 Ų
• Heavy Atom Count: 12
• Formal Charge: 0
• Complexity: 193.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 1
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

1. He Mei, Xiaolei Zhu, Ziqian Li, Jiahui Jiang, Huili Wang, Xuedong Wang, Peipei Zhou.  (2023)  Manganese dioxide nanosheet-modulated ratiometric fluoroprobe based on carbon quantum dots from okra for selective and sensitive dichlorvos detection in foods.  FOOD CHEMISTRY,      [PMID:37741246] [10.1016/j.foodchem.2023.137507]

2. Qi Shao, Chunhui Jiang, Xu Chen, Anguan Wang, Linchuan Lu, Liang Chen, Hongfei Lu.  (2023)  Sensing of organophosphorus pesticides by fluorescent complexes based on purine-hydrazone receptor and copper (II) and its application in living-cells imaging.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,      [PMID:37031483] [10.1016/j.saa.2023.122676]

3. Xiaoning Liao, Xiaoyao Luo, Yiyang Li, Ying Zhou, Qi Liang, Kehuai Feng, María Belén Camarada, Jianhua Xiong.  (2023)  An antifouling electrochemical sensor based on multiwalled carbon nanotubes functionalized black phosphorus for highly sensitive detection of carbendazim and corresponding response mechanisms analyses.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2023.108671]

4. Zhi Zhou, Xingzhen Ni, Zhongjie Wu, Jia Tang.  (2021)  Physiological and transcriptomic analyses reveal the threat of herbicides glufosinate and glyphosate to the scleractinian coral Pocillopora damicornis.  ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY,      [PMID:34915224] [10.1016/j.ecoenv.2021.113074]

5. Fenglian Qi, Yunhe Lan, Zihui Meng, Chunxiao Yan, Shuguang Li, Min Xue, Yifei Wang, Lili Qiu, Xuan He, Xueyong Liu.  (2018)  Acetylcholinesterase-functionalized two-dimensional photonic crystals for the detection of organophosphates.  RSC Advances,  8  (51): (29385-29391).  [PMID:35548014] [10.1039/C8RA04953J]

6. Yaqing Chang, Zhe Zhang, Jinhui Hao, Wenshu Yang, Jilin Tang.  (2016)  A simple label free colorimetric method for glyphosate detection based on the inhibition of peroxidase-like activity of Cu(Ⅱ).  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2016.01.048]

7. Yaowei Zhu, Ruijie Tang, Jun Zhao, Changlong Jiang, Lingfei Li, Bianhua Liu.  (2025)  Design and application of metal-organic framework based chemo-fluorescent sensor for selective sensing of the full spectrum of tetracyclines in complex samples.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.160281]

8. Xinyue Lu, Qiyan Zhang, Zejia Wang, Xuanzhi Cheng, Huiru Yan, Shuyi Cai, Huawei Zhang, Qikun Liu.  (2024)  Development of an inducible DNA barcoding system to understand lineage changes in Arabidopsis regeneration.  DEVELOPMENTAL CELL,      [PMID:39591964] [10.1016/j.devcel.2024.10.023]

9. Xin Liu, Shiyue Niu, Bin Yang, Jia Liu, Liqian Niu, Xian Wang, Daqian Song, Shuyun Bi.  (2025)  Fabrication of BSA-protected AgNPs modified MIL-53(Al) as SERS substrate for trace determination of diquat and dipterex.  TALANTA,      [PMID:40154046] [10.1016/j.talanta.2025.128002]

10. Dong Li, Xumin Wang, Tiantian Liu, Yaping Song, Yujiao Song, Shuhan Yu, Xin Liu, Han Wang, Yingjie Wang, Jianchao Cui, Limin Wang, Da Zhang, Hongxia Zhang.  (2025)  AtDIVARICATA1 promotes flowering through regulating flowering integrators and GA biosynthesis in Arabidopsis.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:40541872] [10.1016/j.ijbiomac.2025.145316]

11. Zhiquan Qiang, Zhen Zeng, Danfeng Ma, Jinzhe Li, Yuang Zhao, Tao Qin.  (2025)  NAC Transcription Factor LpNAC22 Positively Regulates Drought Tolerance in Perennial Ryegrass.  PLANT CELL AND ENVIRONMENT,      [PMID:40537946] [10.1111/pce.70022]

12. Xiaodan Zhang, Songhe Zhang, Hongyu Guo, Wenjie Yuan, Xin Lv, Tilang Zhang, Shuaijie Jiang.  (2025)  The combined pollution of imidacloprid and glufosinate-ammonium aggravates toxicity on Hydrilla verticillata and epiphytic microbial community.  AQUATIC TOXICOLOGY,      [PMID:41270333] [10.1016/j.aquatox.2025.107648]

13. Dong Li, Xumin Wang, Yujiao Song, Jianchao Sun, Shuhan Yu, Bowei Zhu, Xin Liu, Guodong Zhao, Tongsheng Zhao, Limin Wang.  (2025)  Transcription Factor BnaC04.MYB89 Negatively Regulates Seed Fatty Acid Biosynthesis in Brassica napus.  Plants-Basel,  14  (22):   [PMID:41304649] [10.3390/plants14223495]