Grubbs Catalyst® M310 - ≥99.95% metals basis , CAS No.1031262-76-6

CAS: 1031262-76-6 Cat. No.: G283992 Peso molecular: 747.76 Número EC: 664-475-1 PubChem CID: 87410271

GRADE & PURITY ≥99.95% metals basis

Synonyms

1031262-76-6|Dichloro(1,3-dimesitylimidazolidin-2-ylidene)(3-phenyl-1H-inden-1-ylidene)(pyridin-2-yl)ruthenate(II)|[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro-(3-phenyl-1H-inden-1-ylidene)(pyridyl)ruthenium(II)|SCHEMBL2588240|AMY7544

Storage

Store at 2-8°C

Shipped In

Wet ice

Descripción general

Product class
M-N, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Grubbs Catalyst® 2nd Generation, SIMes, Pyridyl Ligands

Reaction type
Alkene Metathesis, Cross Metathesis, Enyne Metathesis, Ring Closing Metathesis, Ring Opening Metathesis Polymerization, Self Metathesis

Chemical properties

Chemical formula

C41H41N3Cl2Ru

Empirical formula

[(SIMes)Ru(py)(Ind)Cl2]

Molecular weight

747.71

Metal

Ru

Theoretical metal content

14

Physical state

powder

Color

brown

Metal purity

99.95

Applications & references

Ring closing metathesis in acetic acid.

Reference: Beilstein J. Org. Chem. 2010, 6, 1188 (DOI:10.3762/bjoc.6.136)

Ring closing metathesis of acrylates.

Reference: Beilstein J. Org. Chem. 2010, 6, 1188 (DOI:10.3762/bjoc.6.136)

Ring closing en-yne metathesis.

Reference: Beilstein J. Org. Chem. 2010, 6, 1188 (DOI:10.3762/bjoc.6.136)

Cross metathesis of functionalized allylic alcohols.

Reference: Beilstein J. Org. Chem. 2010, 6, 1188 (DOI:10.3762/bjoc.6.136)

Ring opening metathesis polymerization.

Reference: Eur. J. Org. Chem. 2009, 655 (DOI: 10.1002/ejoc.200800973)

Specifications

Sinónimos

1031262-76-6 | Dichloro(1, 3-dimesitylimidazolidin-2-ylidene)(3-phenyl-1H-inden-1-ylidene)(pyridin-2-yl)ruthenate(II) | [1, 3-Bis(2, 4, 6-trimethylphenyl)-2-imidazolidinylidene]dichloro-(3-phenyl-1H-inden-1-ylidene)(pyridyl)ruthenium(II) | SCHEMBL2588240 | AMY7544

Especificaciones y pureza

≥99.95% metals basis

Información jurídica

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through aladdin, its affiliates or their autho

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥99.95% metals basis

Nombres e identificadores

• Sonrisas canónicas: CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=C3C=C(C4=CC=CC=C43)C5=CC=CC=C5)(Cl)Cl)C6=C(C=C(C=C6C)C)C)C.C1=CC=N[C-]=C1
• IUPAC Name: [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium;2H-pyridin-2-ide
• InChIKey: YRYDLLLFIIYFGS-UHFFFAOYSA-L
• INCHI: 1S/C21H26N2.C15H10.C5H4N.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;1-2-4-6-5-3-1;;;/h9-12H,7-8H2,1-6H3;1-9,11H;1-4H;2*1H;/q;;-1;;;+2/p-2
• Isómeros SMILES: CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=C3C=C(C4=CC=CC=C43)C5=CC=CC=C5)(Cl)Cl)C6=C(C=C(C=C6C)C)C)C.C1=CC=N[C-]=C1
• WGK Alemania: 3
• PubChem CID: 87410271
• Peso molecular: 747.76