Hoveyda-Grubbs Catalyst® M710 - ≥99.95% metals basis , CAS No.1025728-56-6

CAS: 1025728-56-6 Cat. No.: H283995 Peso molecular: 737.64 Número EC: 689-387-0

GRADE & PURITY ≥99.95% metals basis

Synonyms

Umicore Hoveyda-Grubbs Catalyst M710;Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][(2-isopropoxy)(5-trifluoroacetamido)benzylidene]ruthenium(II), Hoveyda-Grubbs Catalyst® M71, [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro

Storage

Store at 2-8°C

Shipped In

Wet ice

Descripción general

Product class
N-Heterocyclic Carbene Ligands, M-C, Homogeneous Catalysts, Carbene Ligands, Hoveyda-Grubbs Catalyst® 2nd Generation, Alkoxybenzylidene Ligands, SIMes

Reaction type
Alkene Metathesis, Cross Metathesis, Ring Closing Metathesis, Self Metathesis

Chemical properties

Chemical formula

C33H38N3Cl2F3O2Ru

Empirical formula

Molecular weight

737.65

Metal

Ru

Theoretical metal content

14

Physical state

powder

Color

green

Metal purity

99.95

Applications & references

Cross metathesis of terpenoids.

Reference: WO2012 004414

Ring closing metathesis of functionalized α,ω-dienes forming trisubstituted C-C double bonds.

Reference: J. Org. Chem. 2008, 73, 4225 (DOI: 10.1021/jo800203d)

Ring closing metathesis of functionalized enynes.

Reference: Eur. J. Org. Chem. 2009, 4254 (DOI: 10.1002/ejoc.200900407)

Cross metathesis with methyl acrylate.

Reference: Eur. J. Org. Chem. 2009, 4254 (DOI: 10.1002/ejoc.200900407)

Formation of trisubstituted alkens via cross metathesis.

Reference: Eur. J. Org. Chem. 2009, 4254 (DOI: 10.1002/ejoc.200900407)

Specifications

Sinónimos

Umicore Hoveyda-Grubbs Catalyst M710;Dichloro[1, 3-bis(2, 4, 6-trimethylphenyl)-2-imidazolidinylidene][(2-isopropoxy)(5-trifluoroacetamido)benzylidene]ruthenium(II), Hoveyda-Grubbs Catalyst® M71, [1, 3-Bis(2, 4, 6-trimethylphenyl)-2-imidazolidinylidene]dichloro

Especificaciones y pureza

≥99.95% metals basis

Información jurídica

This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through aladdin, its affiliates or their autho

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥99.95% metals basis

Nombres e identificadores

• Sonrisas canónicas: CC(C)OC1=C(C=C(NC(C(F)(F)F)=O)C=C1)C=[Ru](Cl)(Cl)=C2N(C3=C(C)C=C(C)C=C3C)CCN2C4=C(C)C=C(C)C=C4C
• InChIKey: TUXRUOWNSPNNTK-UHFFFAOYSA-L
• INCHI: 1S/C21H26N2.C12H12F3NO2.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7(2)18-10-5-4-9(6-8(10)3)16-11(17)12(13,14)15;;;/h9-12H,7-8H2,1-6H3;3-7H,1-2H3,(H,16,17);2*1H;/q;;;;+2/p-2
• WGK Alemania: 3
• Número ONU: 1325
• Peso molecular: 737.64
• Reaxy-Rn: 43455367
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=43455367&ln=