Iodine monochloride - ACS , CAS No.7790-99-0

CAS: 7790-99-0 Cat. No.: I102762 Peso molecular: 162.36 Beilstein Registry Number: 3587194 Número EC: 232-236-7

GRADE & PURITY ACS

Synonyms

iodonium chloride | Chlorine iodide (ClI) | FT-0627251 | Iodomono chloride | Chloroiodide | IODINE MONOCHLORIDE

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice,FedEx DG Service

Descripción general

Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.

Application：

Iodine monochloride is used as a catalyst in organic synthesis. It is the source of electrophilic iodine in the synthesis of certain aromatic iodides. It is used to determine the iodine value of a substance.

Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.
Iodine monochloride may be used in the synthesis of the following: 2-(4-haloisoquinolin-1-yl)ethanol derivatives；5-iodosalicylaldehydes；5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines；(±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol；(±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol.

Specifications

Sinónimos

iodonium chloride | Chlorine iodide (ClI) | FT-0627251 | Iodomono chloride | Chloroiodide | IODINE MONOCHLORIDE

Especificaciones y pureza

ACS

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Protected from light, Argon charged

Enviado en

Wet ice, FedEx DG Service

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Grado

ACS

Nombres e identificadores

• Sonrisas canónicas: ClI
• InChIKey: QZRGKCOWNLSUDK-UHFFFAOYSA-N
• INCHI: 1S/ClI/c1-2
• Isómeros SMILES: ClI
• WGK Alemania: 3
• RTECS: NN1650000
• Número ONU: 17923498(liquid)
• Grupo de embalaje: II
• Peso molecular: 162.36
• Beilstein: 3587194

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Homogeneous non-metal compounds
    • Clase Homogeneous halogens

• Kingdom: Inorganic compounds
• Superclass: Homogeneous non-metal compounds
• Clase: Homogeneous halogens
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Homogeneous halogens
• Alternative Parents: Inorganic chloride salts
• Molecular Framework: Not available
• Substituents: Homogeneous halogen - Inorganic chloride salt - Inorganic salt
• Descripción: This compound belongs to the class of inorganic compounds known as homogeneous halogens. These are inorganic non-metallic compounds in which the largest atom is a nobel gas.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Soluble in water, alcohol, ether, carbon disulfide.
• Sensibilidad: Moisture & Light & Air & Heat sensitive
• Punto de inflamación (°C): 40°C
• Punto de ebullición (°C): 97 °C
• Punto de fusión (°C): 112°C
• Peso molecular: 162.360 g/mol
• XLogP3: 1.700
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 161.873 Da
• Monoisotopic Mass: 161.873 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 2
• Formal Charge: 0
• Complexity: 2.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

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