Iridium(IV) chloride hydrate - ≥99.9% metals basis, Ir ≥56% , CAS No.10025-97-5

CAS: 10025-97-5 Cat. No.: I119463 Peso molecular: 334.03（anhydrous） Número EC: 233-048-8 PubChem CID: 24815

GRADE & PURITY ≥99.9% metals basis, Ir ≥56%

Synonyms

Iridium tetrachloride hydrate | Tetrachloroiridium hydrate

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Specifications

Sinónimos

Iridium tetrachloride hydrate | Tetrachloroiridium hydrate

Especificaciones y pureza

≥99.9% metals basis, Ir ≥56%

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥99.9% metals basis

Nombres e identificadores

• Sonrisas canónicas: O.Cl[Ir](Cl)(Cl)Cl
• IUPAC Name: tetrachloroiridium
• InChIKey: CALMYRPSSNRCFD-UHFFFAOYSA-J
• INCHI: 1S/4ClH.Ir/h4*1H;/q;;;;+4/p-4
• Isómeros SMILES: Cl[Ir](Cl)(Cl)Cl
• CAS alternativo: 207399-11-9
• PubChem CID: 24815
• Peso molecular: 334.03（anhydrous）

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Clase Transition metal salts
      • Subclass Transition metal chlorides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Clase: Transition metal salts
• Subclass: Transition metal chlorides
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal chlorides
• Alternative Parents: Inorganic chloride salts
• Molecular Framework: Not available
• Substituents: Transition metal chloride - Inorganic chloride salt - Inorganic salt
• Descripción: This compound belongs to the class of inorganic compounds known as transition metal chlorides. These are inorganic compounds in which the largest halogen atom is Chlorine, and the heaviest metal atom is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Hygroscopic
• Punto de fusión (°C): >350°C
• Peso molecular: 334.000 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 334.835 Da
• Monoisotopic Mass: 332.838 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 19.100
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

Referencias

1. Zeyu Guan, Jiankun Li, Shiyi Li, Keyu Wang, Linfeng Lei, Yixing Wang, Linzhou Zhuang, Zhi Xu.  (2023)  The transient covering of iridium species with ultrathin carbon shells via Joule-heating for robust acidic water oxidation.  Materials Chemistry Frontiers,  8  (3): (824-835).  [PMID:] [10.1039/D3QM00973D]

2. Yiming Jiang, Juncai Leng, Shiqi Zhang, Tingyi Zhou, Mingxuan Liu, Shuoming Liu, Yahui Gao, Jianwei Zhao, Lei Yang, Li Li, Wei Zhao.  (2023)  Modulating Water Splitting Kinetics via Charge Transfer and Interfacial Hydrogen Spillover Effect for Robust Hydrogen Evolution Catalysis in Alkaline Media.  Advanced Science,  10  (24): (2302358).  [PMID:37350571] [10.1002/advs.202302358]

3. Ye Zhang, Xia Kang, Dong-Xue Liu, Ze-Yu Chen.  (2022)  Highly efficient dehydrogenation of hydrazine borane over CoIr/TiO2 catalyst.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2022.08.252]

4. Tao Liu, Yuxin Chen, Yaming Hao, Jianxiang Wu, Ran Wang, Limin Gu, Xuejing Yang, Qiang Yang, Cheng Lian, Honglai Liu, Ming Gong.  (2022)  Hierarchical anions at the electrode-electrolyte interface for synergized neutral water oxidation.  Chem,      [PMID:] [10.1016/j.chempr.2022.06.012]

5. Weibin Chen, Yuxin Xie, Xuehui Gao, Lei Li, Zhan Lin.  (2022)  Simultaneous optimization of CoIr alloy nanoparticles and 2D graphitic-N doped carbon support in CoIr@CN by Ir doping for enhanced oxygen and hydrogen evolution reactions.  Journal of Materials Chemistry A,  10  (29): (15543-15553).  [PMID:] [10.1039/D2TA03496D]

6. You Xu, Mengying Liu, Mingzhen Wang, Tianlun Ren, Kaili Ren, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang.  (2021)  Methanol electroreforming coupled to green hydrogen production over bifunctional NiIr-based metal-organic framework nanosheet arrays.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2021.120753]

7. Chunlei Peng, Wanpeng Zhao, Zhaoxia Li, Zhaoyu Kuang, Guofeng Cheng, Jeffery T. Miller, Shuhui Sun, Hangrong Chen.  (2021)  Eutectic molten salt assisted synthesis of highly defective and flexible ruthenium oxide for efficient overall water splitting.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2021.131707]

8. Qi Xue, Hui-Ying Sun, Ya-Nan Li, Ming-Jun Zhong, Fu-Min Li, Xinlong Tian, Pei Chen, Shi-Bin Yin, Yu Chen.  (2021)  Au@Ir core-shell nanowires towards oxygen reduction reaction.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2021.129760]

9. Xiaoqian Jiang, Xiaoyu Wang, Anqi Lin, Hui Wei.  (2021)  In Situ Exsolution of Noble-Metal Nanoparticles on Perovskites as Enhanced Peroxidase Mimics for Bioanalysis.  ANALYTICAL CHEMISTRY,      [PMID:33797896] [10.1021/acs.analchem.1c00721]

10. Jingru Wang, Shanhui Zhu, Yunwei Wang, Yingyong Wang, Guoqiang Jin, Xili Tong, Xiangyun Guo.  (2020)  Enhanced activity of Ru-Ir nanoparticles over SiC for hydrogenation of levulinic acid at room-temperature.  MATERIALS RESEARCH BULLETIN,      [PMID:] [10.1016/j.materresbull.2020.111128]

11. Jinhui Zhu, Min Wei, Qinghao Meng, Zhenyu Chen, Yepeng Fan, Syed Waqar Hasan, Xiaoran Zhang, Dandan Lyu, Zhi Qun Tian, Pei Kang Shen.  (2020)  Ultrathin-shell IrCo hollow nanospheres as highly efficient electrocatalysts towards the oxygen evolution reaction in acidic media.  Nanoscale,  12  (47): (24070-24078).  [PMID:33241831] [10.1039/D0NR06601J]

12. You Xu, Xingjie Chai, Mengying Liu, Tianlun Ren, Shanshan Yu, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang.  (2020)  Two-Dimensional NiIr@N-Doped Carbon Nanocomposites Supported on Ni Foam for Electrocatalytic Overall Water Splitting.  CHEMISTRY-A EUROPEAN JOURNAL,  26  (63): (14496-14501).  [PMID:32841440] [10.1002/chem.202003473]

13. Qinxin Luo, Dan Lin, Wenqi Zhan, Wanqun Zhang, Lulu Tang, Jingjing Luo, Zhan Gao, Peng Jiang, Miao Wang, LuYuan Hao, Kaibin Tang.  (2020)  Hexagonal Perovskite Ba0.9Sr0.1Co0.8Fe0.1Ir0.1O3−δ as an Efficient Electrocatalyst towards the Oxygen Evolution Reaction.  ACS Applied Energy Materials,      [PMID:] [10.1021/acsaem.0c01192]

14. Feng Guo, Hongtao Zou, Qilu Yao, Bin Huang, Zhang-Hui Lu.  (2020)  Monodispersed bimetallic nanoparticles anchored on TiO2-decorated titanium carbide MXene for efficient hydrogen production from hydrazine in aqueous solution.  RENEWABLE ENERGY,      [PMID:] [10.1016/j.renene.2020.04.047]

15. Wendan Nie, Yixing Luo, Qifeng Yang, Gang Feng, Qilu Yao, Zhang-Hui Lu.  (2019)  An amine-functionalized mesoporous silica-supported PdIr catalyst: boosting room-temperature hydrogen generation from formic acid.  Inorganic Chemistry Frontiers,  7  (3): (709-717).  [PMID:] [10.1039/C9QI01375J]

16. Qilu Yao, Meng He, Xiaoling Hong, Xiaoliang Zhang, Zhang-Hui Lu.  (2019)  MoOx-modified bimetallic alloy nanoparticles for highly efficient hydrogen production from hydrous hydrazine.  Inorganic Chemistry Frontiers,  6  (6): (1546-1552).  [PMID:] [10.1039/C9QI00379G]

17. Junnan Li, Ziwei Pan, Kebin Zhou.  (2018)  Enhanced photocatalytic oxygen evolution activity by formation of Ir@IrOx(OH)y core–shell heterostructure.  NANOTECHNOLOGY,  29  (40): (405705).  [PMID:30015623] [10.1088/1361-6528/aad3f4]

18. Lu Wangting, Zhang Geng, Wei Feng, Li Wenhui, Cheng Kun, Ding Fei, Zhang Jiying, Zheng Wanquan.  (2017)  Shape-controlled synthesis of Pd nanocrystals in an aqueous solution by using amphiphilic triblock copolymers as both the stabilizer and the reductant.  COLLOID AND POLYMER SCIENCE,  295  (4): (703-707).  [PMID:] [10.1007/s00396-017-4041-9]

19. Yuan Gao, Ming Hou, Zhigang Shao, Changkun Zhang, Xiaoping Qin, Baolian Yi.  (2015)  Highly effective oxygen reduction activity and durability of antimony-doped tin oxide modified PtPd/C electrocatalysts.  RSC Advances,  5  (85): (69479-69486).  [PMID:] [10.1039/C5RA10162J]

20. Liao Yujia, Chen Wen, Ding Yutian, Xie Lei, Yang Qi, Wu Qilong, Liu Xianglong, Zhu Jinliang, Feng Renfei, Fu Xian-Zhu, Luo Shuiping, Luo Jing-Li.  (2025)  Boosting Alcohol Oxidation Electrocatalysis with Multifactorial Engineered Pd1/Pt Single-Atom Alloy-BiOx Adatoms Surface.  Nano-Micro Letters,  17  (1): (1-14).  [PMID:40025287] [10.1007/s40820-025-01678-4]

21. Jiang Chang, He Hongyuan, Guo Hongquan, Zhang Xiaoxin, Han Qingyang, Weng Yanhong, Fu Xianzhu, Zhu Yinlong, Yan Ning, Tu Xin, Sun Yifei.  (2024)  Transfer learning guided discovery of efficient perovskite oxide for alkaline water oxidation.  Nature Communications,  15  (1): (1-15).  [PMID:39060252] [10.1038/s41467-024-50605-5]

22. Qianlin Ju, Tao Chen, Qianhui Xie, Manli Wang, Kaige Zhao, Tong Liu, Liang Fu, Haozhi Wang, Zelin Chen, Changjiu Li, Yida Deng.  (2024)  Ultrafine IrMnOx Nanocluster Decorated Amorphous PdS Nanowires as Efficient Electrocatalysts for High C1 Selectivity in the Alkaline Ethanol Oxidation Reaction.  ACS Applied Materials & Interfaces,      [PMID:38904246] [10.1021/acsami.4c04578]

23. Shui Yu, Tao Zhou, Xiaoting Huang, Yuqing Tang, Pei Kang Shen, Zhi Qun Tian.  (2025)  Ruthenium-iridium-cobalt alloy hollow nanospheres with high lattice strain for efficient oxygen evolution reaction in proton exchange membrane water electrolysis.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:40695002] [10.1016/j.jcis.2025.138473]

24. Bingjie Zhang, Chunyan Wang, Fulin Yang, Shuli Wang, Ligang Feng.  (2025)  Work function-induced spontaneous built-in electric field in Ir/MoSe2 for efficient PEM water electrolysis.  CHINESE JOURNAL OF CATALYSIS,      [PMID:] [10.1016/S1872-2067(25)64685-7]

25. Shiyu Wan, Guangying Fu, Dongyan Xu, Peng Lu, Valentin Valtchev.  (2025)  Ultra-fine palladium‑gold alloy nanoclusters anchored on amino-grafted self-pillared pentasil zeolite for efficient dehydrogenation of formic acid.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.167734]

26. Cunpeng Duan, Jiahui Xiao, Yanzhi Sun, Junqing Pan.  (2025)  Synergistic effects in Iridium-Decorated metal oxide nanotubes as advanced anodic catalysts for sustainable lead recovery process.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2025.150783]

27. Cunpeng Duan, Jiahui Xiao, Yanzhi Sun, Junqing Pan.  (2025)  Thermally activating IrCoP@CNT: A double-phase synergistic catalyst for ultra-efficient acidic oxygen evolution and sustainable Lead electrodeposition.  JOURNAL OF ELECTROANALYTICAL CHEMISTRY,      [PMID:] [10.1016/j.jelechem.2025.119464]

28. Weibin Chen, Yanhui Song, Lei Li, Junjie Guo, Zhan Lin.  (2023)  Stabilizing iridium sites via interface and reconstruction regulations for water oxidation in alkaline and acidic media.  Journal of Energy Chemistry,      [PMID:] [10.1016/j.jechem.2023.10.055]

29. Wenjie Xue, Hongxia Liu, Baohua Mao, Honglei Liu, Minghuang Qiu, Chengguang Yang, Xinqing Chen, Yuhan Sun.  (2020)  Reversible hydrogenation and dehydrogenation of N-ethylcarbazole over bimetallic Pd-Rh catalyst for hydrogen storage.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2020.127781]