Lithium tetraborate - ≥99% , CAS No.12007-60-2

CAS: 12007-60-2 Cat. No.: L106301 Peso molecular: 169.12 Número EC: 234-514-3

GRADE & PURITY ≥99%

Synonyms

AKOS015903581 | F71328 | Boric acid (H2B407), dilithium salt | Lithium tetraborate, 99% | [Li+].[Li+].[O-]B(OB=O)OB([O-])OB=O | L0387 | AKOS032949838 | EINECS 234-514-3 | dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate | UNII-G5N01T5TYY |

Storage

Argon charged,Room temperature

Shipped In

Normal

Descripción general

Lithium tetraborate is a spectroscopic fluxing agent which is used for fusing basic oxides, glass, alumino-silicates, ceramics, carbonates, cement, steel, aluminum, soil, concrete mixes, bauxites, magnesites and rare earth oxides.

Specifications

Sinónimos

AKOS015903581 | F71328 | Boric acid (H2B407), dilithium salt | Lithium tetraborate, 99% | [Li+].[Li+].[O-]B(OB=O)OB([O-])OB=O | L0387 | AKOS032949838 | EINECS 234-514-3 | dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate | UNII-G5N01T5TYY |

Especificaciones y pureza

≥99%

Condiciones de almacenamiento de almacenamiento

Argon charged, Room temperature

Enviado en

Normal

Pureza

≥99%

Nombres e identificadores

• Pubchem Sid: 488198970
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488198970
• Sonrisas canónicas: [Li+].[Li+].B(=O)OB([O-])OB([O-])OB=O
• IUPAC Name: dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate
• InChIKey: PSHMSSXLYVAENJ-UHFFFAOYSA-N
• INCHI: 1S/B4O7.2Li/c5-1-9-3(7)11-4(8)10-2-6;;/q-2;2*+1
• Isómeros SMILES: [Li+].[Li+].B(=O)OB([O-])OB([O-])OB=O
• WGK Alemania: 1
• Peso molecular: 169.12
• Reaxy-Rn: 22940621
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=22940621&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Clase Alkali metal oxoanionic compounds
      • Subclass Alkali metal borates

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Clase: Alkali metal oxoanionic compounds
• Subclass: Alkali metal borates
• Intermediate Tree Nodes: Not available
• Direct Parent: Alkali metal borates
• Alternative Parents: Miscellaneous borates Metalloid salts Inorganic oxides Inorganic lithium salts
• Molecular Framework: Not available
• Substituents: Borate - Alkali metal borate - Inorganic lithium salt - Inorganic oxide - Inorganic salt - Inorganic metalloid salt
• Descripción: This compound belongs to the class of inorganic compounds known as alkali metal borates. These are inorganic compounds in which the largest oxoanion is borate, and in which the heaviest atom not in an oxoanion is an alkali metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Punto de fusión (°C): 930°C
• Peso molecular: 169.200 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 4
• Exact Mass: 170.034 Da
• Monoisotopic Mass: 170.034 Da
• Topological Polar Surface Area: 108.000 Ų
• Heavy Atom Count: 13
• Formal Charge: 0
• Complexity: 110.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

XLogP3

Referencias

1. Kai Zhang, Pan Xue, Jianghua Wu, Liyun Wu, Nanyang Wang, Tao Xu, Kaiping Zhu, Jun Pu, Qiulong Li, Yu Deng, Yagang Yao, Jin Zhang.  (2023)  Reaction Pathway Analysis of B/Li2O in a Li–B–O System for Boron Nitride Nanotube Growth.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.3c00838]

2. Tao Zhang, Liwei Zhuang, Dan Li, Lingzong Meng, Tianlong Deng, Yafei Guo, Yong Ma.  (2022)  Solid–Liquid Phase Equilibria and Boron Species Distribution in the Quaternary System LiCl–LiBO2–Li2B4O7–H2O at T = 323.15 K and P = 0.1 MPa.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/acs.jced.2c00261]

3. Lan Yang, Lele Chen, Tao Zhang, Dan Li, Lingzong Meng, Tianlong Deng, Yafei Guo.  (2020)  Solubility determination and thermodynamic modeling of solid−liquid equilibria in the LiBO2−Li2B4O7−H2O system at 298.15 K and 323.15 K.  FLUID PHASE EQUILIBRIA,      [PMID:] [10.1016/j.fluid.2020.112783]

4. Lan Yang, Lingzong Meng, Tongjie Ge, Dan Li, Tianlong Deng, Yafei Guo.  (2019)  Solubility Measurement and Thermodynamic Modeling of Solid–Liquid Equilibria in the MCl–M2B4O7–H2O (M = Li, Na) Systems.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/acs.jced.9b00561]

5. Zhu Min, Chen Changlin.  (2018)  Hydrogenolysis of glycerol to 1,3-propanediol over Li2B4O7-modified tungsten–zirconium composite oxides supported platinum catalyst.  Reaction Kinetics Mechanisms and Catalysis,  124  (2): (683-699).  [PMID:] [10.1007/s11144-018-1379-z]

6. Yada Li, Weiqiang Wang, Huiying Liu, Jingwu Lei, Jingying Zhang, Hongzhi Zhou, Min Qi.  (2018)  Formation and in vitro/in vivo performance of “cortex-like” micro/nano-structured TiO2 coatings on titanium by micro-arc oxidation.  Materials Science & Engineering C-Materials for Biological Applications,      [PMID:29549953] [10.1016/j.msec.2018.02.023]

7. Jun Qu, Xuewei Li, Zhiwu Lei, Zhao Li, Min Chen, Qiwu Zhang.  (2016)  Mechano-Hydrothermal Synthesis of Tetraborate Pillared Li–Al Layered Double Hydroxides.  JOURNAL OF THE AMERICAN CERAMIC SOCIETY,  99  (4): (1151-1154).  [PMID:] [10.1111/jace.14196]

8. Hongyu Qi, Jiaxin Han, Lin Xing, Jia Xu, Yushan Liu, Xun Wang, Tao Zhang, Yong Ma, Lingzong Meng.  (2025)  Solid and Liquid Phase Equilibrium in the Quinary System LiCl–Li2SO4–LiBO2–Li2B4O7–H2O at 323.15 K.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/acs.jced.5c00204]

9. Dazhao Wang, Jianbei Qiu, Dacheng Zhou, Songhan Hu, Yugeng Wen, Ke Zhang, Qi Wang, Yong Yang, Hao Wu, Zhangwen Long, Xizheng Li, Jiacheng Pi, Enhao Cao.  (2020)  Lithium doping induced self-crystallization of CsPbBr3 nanocrystal glass with improved quantum yield and stability.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2020.127777]