meso-Tetraphenylporphyrin (TPP) - ≥97% , CAS No.917-23-7

CAS: 917-23-7 Cat. No.: M115646 Peso molecular: 614.74 Beilstein Registry Number: 379542 Número EC: 213-025-9

GRADE & PURITY ≥97%

Synonyms

F14722 | meso-Tetraphenylporphyrine | 5,10,15,20-Tetraphenyl-21H,23H-porphine, 97% | NSC640184 | NSC-640184 | 5,10,15,20-tetraphenylporphyrin | NSC18506 | NSC-18506 | meso-Tetraphenylporphine, low chlorin | NSC 18506 | Tetraphenylporphryin | meso-Tetraphe

Storage

Room temperature,Argon charged

Shipped In

Normal

Descripción general

Ultra-high sensitive spectrophotometric reagent for Cu

Specifications

Sinónimos

F14722 | meso-Tetraphenylporphyrine | 5, 10, 15, 20-Tetraphenyl-21H, 23H-porphine, 97% | NSC640184 | NSC-640184 | 5, 10, 15, 20-tetraphenylporphyrin | NSC18506 | NSC-18506 | meso-Tetraphenylporphine, low chlorin | NSC 18506 | Tetraphenylporphryin | meso-Tetraphe

Especificaciones y pureza

≥97%

Condiciones de almacenamiento de almacenamiento

Room temperature, Argon charged

Enviado en

Normal

Pureza

≥97%

Nombres e identificadores

• Pubchem Sid: 488202415
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488202415
• Sonrisas canónicas: C1=CC=C(C=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C=C4)C9=CC=CC=C9)N3
• IUPAC Name: 5,10,15,20-tetraphenyl-21,23-dihydroporphyrin
• InChIKey: YNHJECZULSZAQK-UHFFFAOYSA-N
• INCHI: 1S/C44H30N4/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36/h1-28,45,48H
• Isómeros SMILES: C1=CC=C(C=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C=C4)C9=CC=CC=C9)N3
• WGK Alemania: 3
• Peso molecular: 614.74
• Beilstein: 379542
• Reaxy-Rn: 14378777
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=14378777&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Clase Tetrapyrroles and derivatives
      • Subclass Porphyrins

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Clase: Tetrapyrroles and derivatives
• Subclass: Porphyrins
• Intermediate Tree Nodes: Not available
• Direct Parent: Porphyrins
• Alternative Parents: Benzene and substituted derivatives Pyrroles Heteroaromatic compounds Azacyclic compounds Organonitrogen compounds Hydrocarbon derivatives Organic anions
• Molecular Framework: Aromatic heteropolycyclic compounds
• Substituents: Porphyrin - Benzenoid - Monocyclic benzene moiety - Heteroaromatic compound - Pyrrole - Azacycle - Organic nitrogen compound - Hydrocarbon derivative - Organonitrogen compound - Organic anion - Aromatic heteropolycyclic compound
• Descripción: This compound belongs to the class of organic compounds known as porphyrins. These are compounds containing a fundamental skeleton of four pyrrole nuclei united through the alpha-positions by four methine groups to form a macrocyclic structure.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Insoluble in water; chloroform: 1 mg/mL, clear to opaque
• Sensibilidad: air sensitive&light sensitive
• Punto de fusión (°C): >300°C
• Peso molecular: 614.700 g/mol
• XLogP3: 10.400
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 614.247 Da
• Monoisotopic Mass: 614.247 Da
• Topological Polar Surface Area: 57.400 Ų
• Heavy Atom Count: 48
• Formal Charge: 0
• Complexity: 851.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Huang Ouyang, Kunpeng Song, Irshad Hussain, Bien Tan.  (2023)  Amine-Impregnated Porous Organic Polymers with Chemisorption Sites for Highly Efficient CO2 Chemical Conversion under Ambient Conditions.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.3c00235]

2. Shiliang Zhu, Ke Li, Shuai Qin, Jianguo Lin, Ling Qiu.  (2023)  Cerenkov radiation induced chemo-photodynamic therapy using ROS-responsive agent.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,      [PMID:] [10.1016/j.jphotochem.2023.114641]

3. Bin Du, Qian Tang, Wei Chen, Xiang Rong, Ke Zhang, Dandan Ma, Zhaolan Wei, Wei Chen.  (2023)  Insight into the purification of algael water by a novel flocculant with enhanced branched nanochitosan structure.  JOURNAL OF ENVIRONMENTAL MANAGEMENT,      [PMID:36701886] [10.1016/j.jenvman.2023.117283]

4. Huang Ouyang, Kunpeng Song, Jing Du, Zhen Zhan, Bien Tan.  (2021)  Creating chemisorption sites for enhanced CO2 chemical conversion activity through amine modification of metalloporphyrin-based hypercrosslinked polymers.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2021.134326]

5. Zhong Yuanyuan, Zhang Li, Sun Shian, Zhou Zhenghao, Ma Yunsu, Hong Hao, Yang Dongzhi.  (2021)  Sequential drug delivery by injectable macroporous hydrogels for combined photodynamic-chemotherapy.  JOURNAL OF NANOBIOTECHNOLOGY,  19  (1): (1-14).  [PMID:34688292] [10.1186/s12951-021-01066-1]

6. Ke Wang, Yuxia Liu, Shiting Wang, Zhifeng Dai, Yubing Xiong.  (2021)  Synergistic catalysis of metalloporphyrins and phosphonium ionic liquids for the efficient transformation of CO2 under ambient conditions.  Journal of CO2 Utilization,      [PMID:] [10.1016/j.jcou.2021.101519]

7. Canhuang Li, Siyong Wu, Yijing Qiu, Dongsheng Lu.  (2020)  Phosphorus-Containing C12H27O4P as Functional Electrolyte Additives for High-Voltage LiNi0.5Mn1.5O4/Graphite Li-Ion Batteries with Excellent Electrochemical Performance.  Advanced Materials Interfaces,  8  (3): (2001588).  [PMID:] [10.1002/admi.202001588]

8. Lixin Zang, Huimin Zhao.  (2020)  Correlation between the Triplet-State Energy of Metalloporphyrins and Oxygen Response of Their Phosphorescence.  Journal of Physical Chemistry C,      [PMID:] [10.1021/acs.jpcc.0c08568]

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10. Jiani Wang, Shupei Zhang, Hong Dai, Hongli Zheng, Zhensheng Hong, Yanyu Lin.  (2019)  Dual-readout immunosensor constructed based on brilliant photoelectrochemical and photothermal effect of polymer dots for sensitive detection of sialic acid.  BIOSENSORS & BIOELECTRONICS,      [PMID:31400731] [10.1016/j.bios.2019.111567]

11. Dong Pan, Pingping Liang, Xiangmin Zhong, Dong Wang, Hui Cao, Wenjun Wang, Wanli He, Zhou Yang, Xiaochen Dong.  (2019)  Self-Assembled Porphyrin-Based Nanoparticles with Enhanced Near-Infrared Absorbance for Fluorescence Imaging and Cancer Photodynamic Therapy.  ACS Applied Bio Materials,      [PMID:35021390] [10.1021/acsabm.8b00530]

12. Shaolei Wang, Kunpeng Song, Chengxin Zhang, Yu Shu, Tao Li, Bien Tan.  (2016)  A novel metalporphyrin-based microporous organic polymer with high CO2 uptake and efficient chemical conversion of CO2 under ambient conditions.  Journal of Materials Chemistry A,  5  (4): (1509-1515).  [PMID:] [10.1039/C6TA08556C]

13. Panpan Zheng, Yiran Xu, Long Li, Yang Shen, Tingting Yang, Ying Song, Xijia Yang.  (2025)  Metal Porphyrin-Terminated Hyperbranched Polyimides for Resistive Switching in Nonvolatile Memory Devices.  CHEMPHYSCHEM,      [PMID:40902258] [10.1002/cphc.202500320]

14. Tianyi Zhang, Yuhui Wu, Ye Tian, Youxiang Wang, Peng Zhang, Qiannuan Shi, Qun Fang, Jianzhang Pan, Qiao Jin, Jian Ji.  (2025)  AI-guided precise design of antimicrobial polymers through high-throughput screening technology on an automated platform.  Bioactive Materials,      [PMID:41502979] [10.1016/j.bioactmat.2025.12.020]

15. Zongning Guo, Xuelin Huang, Zhiqiang Mai, Li Yang, Shaofeng Zheng, Jiaying Liao, Feng Gao, You Zhang, Zhe Jiao.  (2025)  Development of COF-MF-based fluorescent sensor for on-site, and portable detection of uranium in ore samples.  INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY,      [PMID:] [10.1080/03067319.2025.2490609]

16. Jianjun Wang, Xueqing Liu, Dongning Li, Jiao Liu, Zhichun Shi, Yu Zang, Toshiki Aoki.  (2025)  Innovative amino acid-porphyrin decorated hyper-crosslinked polymers for efficient electrosorption of uranium (VI) in aqueous solution.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.135442]