Methacrolein - ≥80%(GC), contains 1% HQ as stabilizer , CAS No.78-85-3

CAS: 78-85-3 Cat. No.: M133597 Peso molecular: 70.09 Beilstein Registry Number: 1(3)2981 Número EC: 201-150-1

GRADE & PURITY ≥80%(GC), contains 1% HQ as stabilizer

Synonyms

EN300-19749 | Methakrylaldehyd | CH2=C(CH3)CHO | Methacrolein-13C | InChI=1/C4H6O/c1-4(2)3-5/h3H,1H2,2H | 2-Methyl-2-propenal | 2-Methylacrolein | MFCD00006974 | 2-Propenal, 2-methyl- | Methacrolein (Stabilized with 1per cent Hydroquinone) | UNII-9HRB2489

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice,FedEx DG Service

Descripción general

Methacrolein on oxidation over heteropoly acid catalysts (mainly 12-molybdophosphoric acid) at 300°C yields methacrylic acid. It is the major product of isoprene oxidation.
Methacrolein was used to study the effect of parts per billion levels of limonene oxidation products and the terpene oxidation product, methacrolein on human eye blink frequency. It was also used in determination of rate constants and the products of the reactions between atomic chlorine and acrolein, methacrolein and methyl vinyl ketone.

Specifications

Sinónimos

EN300-19749 | Methakrylaldehyd | CH2=C(CH3)CHO | Methacrolein-13C | InChI=1/C4H6O/c1-4(2)3-5/h3H, 1H2, 2H | 2-Methyl-2-propenal | 2-Methylacrolein | MFCD00006974 | 2-Propenal, 2-methyl- | Methacrolein (Stabilized with 1per cent Hydroquinone) | UNII-9HRB2489

Especificaciones y pureza

≥80%(GC), contains 1% HQ as stabilizer

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice, FedEx DG Service

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥80%(GC)

Nombres e identificadores

• Sonrisas canónicas: CC(=C)C=O
• IUPAC Name: 2-methylprop-2-enal
• InChIKey: STNJBCKSHOAVAJ-UHFFFAOYSA-N
• INCHI: 1S/C4H6O/c1-4(2)3-5/h3H,1H2,2H3
• Isómeros SMILES: CC(=C)C=O
• RTECS: OZ2625000
• Número ONU: 2396
• Grupo de embalaje: II
• Peso molecular: 70.09
• Beilstein: 1(3)2981
• Reaxy-Rn: 1209258
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1209258&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Clase Organooxygen compounds
      • Subclass Carbonyl compounds
        • Level5 Alpha,beta-unsaturated carbonyl compounds
          • Level6 Alpha,beta-unsaturated aldehydes
            • Level7 Enals

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Clase: Organooxygen compounds
• Subclass: Carbonyl compounds
• Intermediate Tree Nodes: Alpha,beta-unsaturated carbonyl compounds - Alpha,beta-unsaturated aldehydes
• Direct Parent: Enals
• Alternative Parents: Short-chain aldehydes Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Enal - Organic oxide - Hydrocarbon derivative - Short-chain aldehyde - Aldehyde - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as enals. These are an alpha,beta-unsaturated aldehyde of general formula RC=C-CH=O in which the aldehydic C=O function is conjugated to a C=C triple bond at the alpha,beta position.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Mecanismos de acción

Propiedades químicas y físicas

• Solubilidad: Soluble in water; Degree of Solubility in water: 60 g/l 20 °C; Miscible with Ether,Ethanol
• Sensibilidad: heat,light and air sensitive
• Índice de refracción: 1.41
• Punto de inflamación (°F): 5.0 °F
• Punto de inflamación (°C): -15°C(lit.)
• Punto de ebullición (°C): 68°C
• Punto de fusión (°C): -81°C(lit.)
• Peso molecular: 70.090 g/mol
• XLogP3: 0.700
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 70.0419 Da
• Monoisotopic Mass: 70.0419 Da
• Topological Polar Surface Area: 17.100 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 54.700
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Tianhao Zhang, Yuhang Bian, Luming Wang, Hui Zhao, Gang Wang, Chunshan Li.  (2023)  Continuous Synthesis of Methacrolein over Sulfonic Acid Resin Catalysts: Unraveling the Effect of Acid Strength and Solvent Permittivity.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,      [PMID:] [10.1021/acs.iecr.3c01550]

2. Hui Guo, Yuchao Li, Cuncun Zuo, Yanxia Zheng, Xinpeng Guo, Jinguo Hao, Haofei Huang, Ming Wang, Tingting Ge.  (2022)  Kinetics, mechanism, and simulation of hydrogen transfer reaction of α, β-unsaturated aldehydes to allylic alcohols.  AICHE JOURNAL,  68  (7): (e17683).  [PMID:] [10.1002/aic.17683]

3. Wenda Hu, Yan Wan, Lili Zhu, Xiaojie Cheng, Shaolong Wan, Jingdong Lin, Yong Wang.  (2017)  A Strategy for the Simultaneous Synthesis of Methallyl Alcohol and Diethyl Acetal with Sn-β.  ChemSusChem,  10  (23): (4715-4724).  [PMID:28926196] [10.1002/cssc.201701435]

4. Chen Li, Hong Zhang, Siyao Gu, Wenlong Lu, Xinyu Chen, Liuliu Zhong, Hui Wan, Lei Wang, Guofeng Guan.  (2025)  Hydrogen bonding effects assisted organic ammonium polyoxometalate salts catalysis for the selective oxidation of methacrolein and mechanism study.  APPLIED CATALYSIS A-GENERAL,      [PMID:] [10.1016/j.apcata.2025.120220]

5. Tianhao Zhang, Hanwen Yan, Chong Zhang, Yiqian Yang, Jie Li, Guoliang Zhang, Junping Zhang, Gang Wang, Chunshan Li.  (2025)  Proton shuttle mediated by ionic liquid promotes aldol condensation.  JOURNAL OF CATALYSIS,      [PMID:] [10.1016/j.jcat.2025.116001]

6. Wei Xu, Xue Zou, Yueting Ding, Qi Zhang, Yulan Song, Jin Zhang, Min Yang, Zhou Liu, Qiang Zhou, Dianlong Ge, Qiangling Zhang, Wencheng Song, Chaoqun Huang, Chengyin Shen, Yannan Chu.  (2024)  Qualitative and quantitative rapid detection of VOCs differentially released by VAP-associated bacteria using PTR-MS and FGC-PTR-MS.  ANALYST,      [PMID:38197456] [10.1039/D3AN02011H]

7. Qianchun Zhang, Yuxian Zhao, Zhaoru Ban, Li Jiang, Shan Tang.  (2024)  Synthesis of Mesoporous SiO2 Nanomicrospheres for the Efficient Cataluminescence Sensing of Isobutyraldehyde.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.4c02931]

8. Zhang Tianhao, Tian Yuan, Zhang Chong, Yan Tingting, Yan Hanwen, Zhang Guoliang, Li Jie, Li Zengxi, Wang Gang, Li Chunshan, Zhang Suojiang.  (2025)  Electronically tailored metal-ion-chelation strategy promotes ionic liquid catalysis at near-ambient condition.  Nature Communications,  16  (1): (1-12).  [PMID:41022719] [10.1038/s41467-025-63630-9]

9. Shipeng Jiang, Siyu Han, Xinyi Wang, Yueran Ma, Yue Chen, Mingyang Sun, Peiran Meng, Shaokai Du, Yue Sun.  (2025)  Smartphone-based paper LPS sensor: achieving picomolar ultra-sensitive detection.  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D5NJ01756D]

10. Chen Li, Hong Zhang, Siyao Gu, Wenlong Lu, Xinyu Chen, Liuliu Zhong, Mingjun Zheng, Hui Wan, Lei Wang, Guofeng Guan.  (2025)  The study of structure-property relationships of heteropolyacids regulated by cesium sources in selective oxidation with methacrolein.  CHEMICAL ENGINEERING RESEARCH & DESIGN,      [PMID:] [10.1016/j.cherd.2025.04.044]

11. Yifei Zhang, Zhenyu Fan, Daming Fan, Mingfu Wang, Yueliang Zhao.  (2025)  The Structure–Activity Relationship of Flavonoids in Inhibiting Aldehyde Emissions from Heated Soybean Oil.  ACS Food Science & Technology,      [PMID:] [10.1021/acsfoodscitech.5c00195]

12. Pengjun Wang, Yang Rui, Tianli Hui, Tao Zheng, Rui Zhang, Xianghai Meng, Xiangping Zhang, Zhichang Liu, Haiyan Liu.  (2026)  Hydrogen-bonding and confinement-enabled one-step immobilization of functional ionic liquids in hierarchical silica for efficient methacrolein synthesis.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2026.166170]