Methanesulfonato(diadamantyl-n-butylphosphino)-2'-amino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane - ≥95% , CAS No.1651823-59-4

CAS: 1651823-59-4 Cat. No.: M396475 Peso molecular: 728.27 Número EC: 815-115-9

GRADE & PURITY ≥95%

Synonyms

Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3

Storage

Room temperature,Argon charged

Shipped In

Normal

Descripción general

This is a Buchwald third generation precatalyst that can be used in:

1.Direct ortho-arylation of pyridinecarboxylic acids.

2.Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.

3.Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.

4.Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.

Specifications

Sinónimos

Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1, 1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1, 1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3

Especificaciones y pureza

≥95%

Condiciones de almacenamiento de almacenamiento

Room temperature, Argon charged

Enviado en

Normal

Pureza

≥95%

Nombres e identificadores

• Sonrisas canónicas: CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
• InChIKey: REYVZCOGMIXVNX-DVBMAMJVSA-M
• INCHI: 1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-
• WGK Alemania: 3
• Peso molecular: 728.27