Methanesulfonato{N-[2-(di-1-adamantylphosphino)phenyl]morpholine}(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct - ≥98% , CAS No.2230788-66-4

CAS: 2230788-66-4 Cat. No.: M396289 Peso molecular: 847.39 PubChem CID: 124203159

GRADE & PURITY ≥98%

Storage

Room temperature

Descripción general

Technical Notes:

1. Palladium catalyst for ammonia arylation.

2. Palladium catalyst for multicomponent one-pot synthesis of indoles.

3. Palladium catalyst for primary aliphatic amination of aryl mesylates.

4. Palladium catalyst for ketone mono-α-arylation of aryl mesylates.

Tech. Note (1) Ref. (1)

Tech. Note (2) Ref. (2)

Tech. Note (3) Ref. (3)

Tech. Note (4) Ref. (3)

References:

1. Angew. Int. Ed., 2010, 49, 4071.

2. Angew. Int. Ed., 2013, 52, 7242.

3. Adv. Synth. Catal., 2015, 357, 100.

Specifications

Especificaciones y pureza

≥98%

Condiciones de almacenamiento de almacenamiento

Room temperature

Pureza

≥98%

Nombres e identificadores

• Sonrisas canónicas: CNC1=CC=CC=C1C2=CC=CC=[C-]2.CS(=O)(=O)O.C1COCCN1C2=CC=CC=C2P(C34CC5CC(C3)CC(C5)C4)C67CC8CC(C6)CC(C8)C7.[Pd]
• IUPAC Name: bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane;methanesulfonic acid;N-methyl-2-phenylaniline;palladium
• InChIKey: VGVZQTYHQRVKCK-UHFFFAOYSA-N
• INCHI: 1S/C30H42NOP.C13H12N.CH4O3S.Pd/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h1-4,21-26H,5-20H2;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;-1
• PubChem CID: 124203159
• Peso molecular: 847.39