Methyltrioxorhenium(VII)（MTO） - ≥98% , CAS No.70197-13-6

CAS: 70197-13-6 Cat. No.: M100685 Peso molecular: 249.24 Beilstein Registry Number: 3927932 Número EC: 677-701-9 PubChem CID: 2734010

GRADE & PURITY ≥98%

Synonyms

MTO | AKOS015902546 | methyl trioxorhenium | Rhenium, methyltrioxo-, (T-4)- | SC11060 | Methyltrioxorhenium [MI] | methyl(trioxo)rhenium | PQTLALPZRPFYIT-UHFFFAOYSA-N | methlytrioxorhenium | Rhenium, methyltrioxo-,(T-4)- (9CI) | methyl rhenium trioxide |

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Descripción general

Methyltrioxorhenium(VII) is a potent catalytic oxidant for converting alkenes to epoxides in a variety of solvents as well as an effective antioxidant under various conditions.
A catalytic oxidant and antioxidant.

Product class
M-C, Homogeneous Catalysts, Alkyl Ligands, Precursors for Heterogeneous Catalysts

Reaction type
Oxidation, Metathesis

Chemical properties

Chemical formula

CH3ORe

Empirical formula

CH3ReO3

Molecular weight

249.24

Metal

Re

Theoretical metal content

75

Physical state

crystalline

Color

pale gray

Specifications

Sinónimos

MTO | AKOS015902546 | methyl trioxorhenium | Rhenium, methyltrioxo-, (T-4)- | SC11060 | Methyltrioxorhenium [MI] | methyl(trioxo)rhenium | PQTLALPZRPFYIT-UHFFFAOYSA-N | methlytrioxorhenium | Rhenium, methyltrioxo-, (T-4)- (9CI) | methyl rhenium trioxide |

Especificaciones y pureza

≥98%

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Protected from light, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥98%

Nombres e identificadores

• Sonrisas canónicas: [CH3-].O=[Re](=O)=O
• IUPAC Name: carbanide;trioxorhenium
• InChIKey: VZSXFJPZOCRDPW-UHFFFAOYSA-N
• INCHI: 1S/CH3.3O.Re/h1H3;;;;/q-1
• Isómeros SMILES: [CH3-].O=[Re](=O)=O
• WGK Alemania: 3
• PubChem CID: 2734010
• Peso molecular: 249.24
• Beilstein: 3927932
• Reaxy-Rn: 3927932

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Clase Transition metal organides
      • Subclass Transition metal oxides

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Clase: Transition metal organides
• Subclass: Transition metal oxides
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal oxides
• Alternative Parents: Inorganic salts Inorganic oxides Carbides
• Molecular Framework: Not available
• Substituents: Transition metal oxide - Carbide - Inorganic oxide - Inorganic salt
• Descripción: This compound belongs to the class of inorganic compounds known as transition metal oxides. These are inorganic compounds containing an oxygen atom of an oxidation state of -2, in which the heaviest atom bonded to the oxygen is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Solubility in water: very soluble in H2O
• Sensibilidad: light sensitive ;air sensitive
• Punto de fusión (°C): 111°C
• Peso molecular: 249.240 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 249.964 Da
• Monoisotopic Mass: 249.964 Da
• Topological Polar Surface Area: 51.200 Ų
• Heavy Atom Count: 5
• Formal Charge: -1
• Complexity: 65.500
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

1. Xueni Zhong, Qianqian Lv, Qiyun Yong, Wenping Hu, Dan Li, Shuhui Ji, Liuyue Zhan, Wenbin Chen, Min Li, Jinsheng Lin, Cuirong Sun.  (2022)  Forced degradation studies of elagolix sodium with the implementation of high resolution LC-UV-PDA-MSn (n = 1,2,3…) and NMR structural elucidation.  JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS,      [PMID:36495708] [10.1016/j.jpba.2022.115198]