Palladium(II) Nitrate - Pd 10 wt. % in 10 wt. % nitric acid , CAS No.313222-87-6

CAS: 313222-87-6 Cat. No.: P344956 Peso molecular: 230.43

GRADE & PURITY Pd 10 wt. % in 10 wt. % nitric acid

Synonyms

palladium(2+);dinitrate;hydrate | Palladium(II) nitrate hydrate | Palladium, diaquabis(nitrato-O)- | Nitric acid palladium salt hydrate | Nitric acid, palladium(2+) salt, monohydrate | Palladium nitrate hydrate

Storage

Room temperature

Shipped In

Normal

Descripción general

Palladium(II) nitrate is used as a reactant for doping activated carbon for catalysis. It acts as a catalyst for hydrogenation of 1-heptyne and naphthalene. It serves as an important raw material for the preparation of platinum-palladium carbon alloy nanocatalysts for methanol-tolerant oxygen reduction reaction in fuel cells and in the synthesis of copper palladium alloy thin films. Furthermore, it is used in the synthesis of di-phenyl sulfide-modified palladium-titanium dioxide catalysts for acetylene hydrogenation.

Specifications

Sinónimos

palladium(2+);dinitrate;hydrate | Palladium(II) nitrate hydrate | Palladium, diaquabis(nitrato-O)- | Nitric acid palladium salt hydrate | Nitric acid, palladium(2+) salt, monohydrate | Palladium nitrate hydrate

Especificaciones y pureza

Pd 10 wt. % in 10 wt. % nitric acid

Condiciones de almacenamiento de almacenamiento

Room temperature

Enviado en

Normal

Nombres e identificadores

• Sonrisas canónicas: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.[Pd+2]
• IUPAC Name: palladium(2+);dinitrate;hydrate
• InChIKey: DTZRLFJKQHIVQA-UHFFFAOYSA-N
• INCHI: 1S/2NO3.H2O.Pd/c2*2-1(3)4;;/h;;1H2;/q2*-1;;+2
• Isómeros SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.[Pd+2]
• WGK Alemania: 3
• CAS alternativo: 10102-05-3
• Número ONU: 1477
• Grupo de embalaje: II
• Peso molecular: 230.43
• Reaxy-Rn: 14925029
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=14925029&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Clase Transition metal oxoanionic compounds
      • Subclass Transition metal nitrates

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Clase: Transition metal oxoanionic compounds
• Subclass: Transition metal nitrates
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal nitrates
• Alternative Parents: Inorganic salts Inorganic oxides
• Molecular Framework: Not available
• Substituents: Transition metal nitrate - Inorganic oxide - Inorganic salt
• Descripción: This compound belongs to the class of inorganic compounds known as transition metal nitrates. These are inorganic compounds in which the largest oxoanion is nitrate, and in which the heaviest atom not in an oxoanion is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Miscible with water and dilute nitric acid.
• Peso molecular: 248.450 g/mol
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 247.89 Da
• Monoisotopic Mass: 247.89 Da
• Topological Polar Surface Area: 127.000 Ų
• Heavy Atom Count: 10
• Formal Charge: 0
• Complexity: 18.800
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 4

XLogP3

Referencias

1. Chenchen Shi, Dong Guo, Bowen Liu, Yibei Wang, Yaowei Liu, Gaobin Liu, Biao Wang, Dongchao Qiu, Yuntao Ma, Chunling Lu, Bingbing Niu.  (2023)  Exceptionally stable double perovskite Sr2-xFeTaO6-δ as fuel electrode for solid oxide cells.  JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,      [PMID:] [10.1016/j.jeurceramsoc.2023.09.086]

2. Xingyu Liu, Jingkun Chen, Bowen Han, Renna Li, Le Shi, Zhongbiao Wu, Xiaole Weng.  (2023)  Lean methane combustion over zeolite-supported Pd catalysts: Structure-performance relationship and deactivation mechanism.  Journal of Environmental Sciences,      [PMID:] [10.1016/j.jes.2023.08.025]

3. Yimin Cai, Mengxin Wang, Lihua Yuan, Wen Feng.  (2023)  Complexation and Separation of Palladium with Tridentate 2,6-Bis-triazolyl-pyridine Ligands: Synthesis, Solvent Extraction, Spectroscopy, Crystallography, and DFT Calculations.  INORGANIC CHEMISTRY,      [PMID:37227426] [10.1021/acs.inorgchem.3c01034]

4. Lin Dong, Jordi Morales-Vidal, Lili Mu, Licheng Li, Núria López, Javier Pérez-Ramírez, Zupeng Chen.  (2023)  Selective hydrogenolysis of 5-hydroxymethylfurfural to 5-methylfurfural over Au/TiO2.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2023.122893]

5. Shuangde Li, Tao Wang, Mu Zhou, Shaohua Chai, Linfeng Nie, Zhenjiang Wu, Ning Han, Yunfa Chen.  (2022)  PtPd/molecular sieve as dual-functional monolithic adsorbent/catalyst for effective removal of trace toluene at low-temperature and their electric-heating performance.  JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,      [PMID:] [10.1016/j.jiec.2022.07.044]

6. Li Zhenyu, Li Jiefei, Zheng Zexuan, Jiang Kunhong, Zheng Tianrun, Wang Dongmin, Wei Hang, Shi Zhiming, Li Xiaotian, Chu Haibin.  (2022)  Roles of hydroxyl and oxygen vacancy of CeO2·xH2O in Pd-catalyzed ethanol electro-oxidation.  Science China-Chemistry,  65  (5): (877-884).  [PMID:] [10.1007/s11426-021-1220-2]

7. Ruixue Yangcheng, Jiansu Ran, Zhaohui Liu, Yuntong Cui, Jianjian Wang.  (2022)  Phosphoric acid-modified commercial kieselguhr supported palladium nanoparticles as efficient catalysts for low-temperature hydrodeoxygenation of lignin derivatives in water.  GREEN CHEMISTRY,  24  (4): (1570-1577).  [PMID:] [10.1039/D1GC04243B]

8. Guanfeng Tian, Youqing Wu, Shiyong Wu, Sheng Huang, Jinsheng Gao.  (2021)  CO2 hydrogenation to methanol over Pd/MnO/In2O3 catalyst.  Journal of Environmental Chemical Engineering,      [PMID:] [10.1016/j.jece.2021.106965]

9. Revanasiddappa Manjunatha, Li Dong, Zibo Zhai, Jianyi Wang, Qianru Fu, Wei Yan, Jiujun Zhang.  (2020)  Pd nanocluster-decorated CoFe composite supported on nitrogen carbon nanotubes as a high-performance trifunctional electrocatalyst.  Green Energy & Environment,      [PMID:] [10.1016/j.gee.2020.12.005]

10. Feifei Luo, Song Hong, Bo Chen, Ying Yin, Guirong Tang, Fenglin Hu, Huizhan Zhang, Chengshu Wang.  (2020)  Unveiling of Swainsonine Biosynthesis via a Multibranched Pathway in Fungi.  ACS Chemical Biology,      [PMID:32786262] [10.1021/acschembio.0c00466]

11. Ning Xiang, Xiaojin Han, Yarong Bai, Qiaoyan Li, Jianfeng Zheng, Yulin Li, Yaqin Hou, Zhanggen Huang.  (2020)  Size effect of γ-Al2O3 supports on the catalytic performance of Pd/γ-Al2O3 catalysts for HCHO oxidation.  Molecular Catalysis,      [PMID:] [10.1016/j.mcat.2020.111112]

12. Jing Sun, Zhenyu Jiang, Ke Wang, Faqi Li, Zhanlong Song, Wenlong Wang, Xiqiang Zhao, Yanpeng Mao.  (2019)  Experimental Study on Microwave–SiC-Assisted Catalytic Hydrogenation of Phenol.  ENERGY & FUELS,      [PMID:] [10.1021/acs.energyfuels.9b02595]

13. Li Hu, Zhao Wenfeng, Saravanamurugan Shunmugavel, Dai Wenshuai, He Jian, Meier Sebastian, Yang Song, Riisager Anders.  (2018)  Control of selectivity in hydrosilane-promoted heterogeneous palladium-catalysed reduction of furfural and aromatic carboxides.  Communications Chemistry,  1  (1): (1-11).  [PMID:] [10.1038/s42004-018-0033-z]

14. Hu Li, Wenfeng Zhao, Zhen Fang.  (2017)  Hydrophobic Pd nanocatalysts for one-pot and high-yield production of liquid furanic biofuels at low temperatures.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2017.05.039]

15. Jinxu Xi, Qineng Xia, Yi Shao, Daqian Ding, Panpan Yang, Xiaohui Liu, Guanzhong Lu, Yanqin Wang.  (2015)  Production of hexane from sorbitol in aqueous medium over Pt/NbOPO4 catalyst.  APPLIED CATALYSIS B-ENVIRONMENTAL,      [PMID:] [10.1016/j.apcatb.2015.08.052]

16. Meiling Chen, Xingyu Liu, Xiaole Weng, Renna Li, Zhongbiao Wu.  (2024)  Tailoring Pd/M@CoAlO core-shell catalyst morphology for efficient methane oxidation.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2024.129547]

17. Puxiang Yan, Haiyong Wang, Yuhe Liao, Chenguang Wang.  (2023)  Synthesis of renewable diesel and jet fuels from bio-based furanics via hydroxyalkylation/alkylation (HAA) over SO42-/TiO2 and hydrodeoxygenation (HDO) reactions.  FUEL,      [PMID:] [10.1016/j.fuel.2023.127685]

18. Xiaoqing Liu, Yuxuan Shang, Zhong-Ren Chen.  (2021)  Vinyl Groups Containing Tetraphenylethylene Derivatives as Fluorescent Probes Specific for Palladium and the Quenching Mechanism†.  CHINESE JOURNAL OF CHEMISTRY,  39  (6): (1599-1605).  [PMID:] [10.1002/cjoc.202000746]

19. Wenjie Xue, Hongxia Liu, Baohua Mao, Honglei Liu, Minghuang Qiu, Chengguang Yang, Xinqing Chen, Yuhan Sun.  (2020)  Reversible hydrogenation and dehydrogenation of N-ethylcarbazole over bimetallic Pd-Rh catalyst for hydrogen storage.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2020.127781]

20. Zhongwei Wang, Hu Li, Wenfeng Zhao, Song Yang.  (2018)  Low-temperature and solvent-free production of biomass-derived diesel-range C17 precursor via one-pot cascade acylation–alkylation over Sn4+-montmorillonite.  JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,      [PMID:] [10.1016/j.jiec.2018.05.047]

21. Sendaner Adelieti, Si-Qi Wu, Xian-Hao Wu, Rong Guo, Jian-Shan Chen, Zhi-Fang Diao, Zi-Yi Miao, Zhen-Hong Han, Ye-Yan Qin, Yuan-Gen Yao.  (2025)  Effect of Gel Alkalinity on the Catalytic Properties of PdCu/NaY Zeolites for Methyl Nitrite Carbonylation to Dimethyl Carbonate.  HELVETICA CHIMICA ACTA,      [PMID:] [10.1002/hlca.202500015]

22. Tao Li, Wan Wang, Jiawei Chen, Yue Wang, Xiangbin Cai, Lini Yang, Xin Liu, Jiangyong Diao, Zarrin Es'haghi, Lixin Xia, Li Jin, Guoqing Wang, Hongyang Liu.  (2026)  Atomically dispersed bimetallic Pd-Fe clusters for boosting catalytic antibacterial performance with O2.  JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,      [PMID:] [10.1016/j.jmst.2025.12.048]

23. Mengjie Xu, Min Hao, Jing Yu, Junfeng Du, Shuai Zhang, Haibin Chu, Yaping Du.  (2026)  Hydrogen Spillover-Enabled Pd/CeO2 Interface Catalysis for Highly Efficient Electrochemical Nitrate-to-Ammonia Conversion.  SmartMat,  7  (2): (e70073).  [PMID:] [10.1002/smm2.70073]

24. Mimi Wu, Junzhong Xie, Guangyou Huo, Xiaolin Yu, Xueqin Yang, Yi Xing, Wei Su, Yang Zheng, Yuechang Wei, Maofa Ge, Ding Ma.  (2026)  Nanoconfinement of Pd Ensembles in Ceria’s Bridging Hydroxyl Nests for Enhanced C–H Bond Activation.  Journal of the American Chemical Society,      [PMID:] [10.1021/jacs.6c01057]