PBDB-T-2F - Mn>30000 , CAS No.1802013-83-7

CAS: 1802013-83-7 Cat. No.: P486798
Disponible para pedir
GRADE & PURITY Mn>30000
Synonyms
PCE135 | PM6 | Poly[[4,8-bis[5-(2-ethylhexyl)-4-fluoro-2-thienyl]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl]-2,5-thiophenediyl[5,7-bis(2-ethylhexyl)-4,8-dioxo-4H,8H-benzo[1,2-c:4,5-c′]dithiophene-1,3-diyl]-2,5-thiophenediyl]
Storage
Room temperature
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Size
Estado
Price
Qty
5mg
P486798-5mg
8-12 wks(?) Production requires sourcing of materials. We appreciate your patience and understanding.
114,90US$
25mg
P486798-25mg
4
441,90US$
100mg
P486798-100mg
1

1.257,90US$

1.467,90US$
Guardar 210,00 US$ (14.31%)
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Why this grade

Mn>30000 for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Room temperature Ships Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 0 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Descripción general

High-Efficiency Organic Solar Cells (OPVs)
Polymeric donor material
LUMO=−3.6 eV
HOMO=−5.5 eV
OPV Device Performance:
PBDB-T-2F: ITIC-F (1:1 w/w)
Voc= 0.84V
Jsc= 22.2 mA/cm2
FF= 0.725
PCE=13.5%
PBDB-T-2F (or PM6) is a wide bandgap polymer donor (n-type semiconductor) containing fluorinated thienyl benzodithiophene (BDT-2F) used in high performance polymer solar cells (PSCs). PBDB-T-2F possesses high crystallinity and strong π-π stacking alignment, which are favourable to charge carrier transport and hence suppress recombination in devices. PBDBT-2F based PSCs were reported to have thickness and area insensitive performance and is a promising candidate for large-scale roll-to-roll manufacturing of high-efficiency polymer solar cells.
For example, recently, new study have shown PBDB-T-2F:IT-4F based PSCs yielded an impressive PCE of 13.5% due to the synergistic effect of fluorination on both donor and acceptor, which is among the highest values recorded in the literatures for PSCs to date . The PBDB-T-2F:IT-4F baed PSCs also showed good storage, thermal and illumination stabilities with respect to the efficiency. High efficiency of >11% was maintained for a wide range of film area and thickness. When paired with selenopheno[3,2-b]thiophene-based narrow-bandgap non-fullerene acceptor, an impressive efficiency of 13.3 % was obtained with thickness-insensitive feature.
It has also been previously reported, PBDB-T-2F when paired with narrow band-gap small molecule acceptor 2,2′-((2Z,2′Z)-((4,4,9,9-tetrahexyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b′]dithiophene-2,7-diyl)bis(methanylylidene))bis(3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile (IDIC), the as-cast film (without extra treatments) showed an outstanding power conversion efficiency (PCE) of 11.9%[1], a record value for as-cast polymer solar cells. Moreover, the performance of PBDB-T-2F:IDIC based devices is insensitive to the active layer thickness (≅95-255 nm) and device area (0.20-0.81 cm2), and thus is a promising candidate for future roll-to-roll mass manufacturing and practical application of highly efficient PSCs.
It has also been reported, PBDB-T-2F possesses a strong absorption in the short wavelength region of 300-685 nm with a large bandgap of 1.80 eV, which is complementary to that of ITIC (1.55 eV) and facilitates achieving high short-circuit current (Jsc) in PSCs. Moreover, PBDB-T-2F shows a deep HOMO level of −5.50 eV, a strong crystallinity and a dominant face on packing, which helps to achieve a high open-circuit voltage (Voc) and fill factor (FF) in PSCs.

Specifications

Sinónimos
PCE135 | PM6 | Poly[[4, 8-bis[5-(2-ethylhexyl)-4-fluoro-2-thienyl]benzo[1, 2-b:4, 5-b′]dithiophene-2, 6-diyl]-2, 5-thiophenediyl[5, 7-bis(2-ethylhexyl)-4, 8-dioxo-4H, 8H-benzo[1, 2-c:4, 5-c′]dithiophene-1, 3-diyl]-2, 5-thiophenediyl]
Especificaciones y pureza
Mn>30000
Condiciones de almacenamiento de almacenamiento
Room temperature

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

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✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

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📊 Datasheet

Quick-reference summary of product specifications and applications.

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🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

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Advanced Data

Certificados (CoA, COO, BSE/TSE y tabla de análisis)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

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6 results found

Lot NumberCertificate TypeFechaArticulo
F23271353Certificate of AnalysisApr 02, 2026 P486798
F23271354Certificate of AnalysisApr 02, 2026 P486798
A2627061Certificate of AnalysisMay 10, 2024 P486798
F2418152Certificate of AnalysisMay 10, 2024 P486798
F23271348Certificate of AnalysisJun 19, 2023 P486798
F23271349Certificate of AnalysisJun 19, 2023 P486798
Propiedades químicas y físicas
Solubilidadchloro; benzene: soluble; chloroform: soluble; dichlorobenzene: soluble
Punto de inflamación (°F)Not applicable
Punto de inflamación (°C)Not applicable
Preguntas frecuentes y artículos
Calculadoras de soluciones
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