Phenox O-PC™ A0202 - New Iridium, ≥97% , CAS No.1987900-95-7

CAS: 1987900-95-7 Cat. No.: P485533 Peso molecular: 613.74 PubChem CID: 129057445

GRADE & PURITY New Iridium, ≥97%

Synonyms

3,7-Di([1,1′-biphenyl]-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine, PhenO_1Naph_Biph, Miyake organophotoredox catalyst, 3,7-Di(4-biphenyl) 1-naphthalene-10-phenoxazine

Storage

Room temperature

Descripción general

Description

This phenoxazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst901112) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with theMiyakeResearch Group.

Specifications

Sinónimos

3, 7-Di([1, 1′-biphenyl]-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine, PhenO_1Naph_Biph, Miyake organophotoredox catalyst, 3, 7-Di(4-biphenyl) 1-naphthalene-10-phenoxazine

Especificaciones y pureza

New Iridium, ≥97%

Información jurídica

专利申请PCT/US2016/058245。与New Iridium Inc.合作出售。如需大于25克的订单，请通过[email protected]与New Iridium联系，或访问https://www.newiridium.com。Phenox O-PC is a trademark of New Iridium LLC

Condiciones de almacenamiento de almacenamiento

Room temperature

Nombres e identificadores

• Sonrisas canónicas: C1=CC=C(C=C1)C2=CC=C(C=C2)C3=CC4=C(C=C3)N(C5=C(O4)C=C(C=C5)C6=CC=C(C=C6)C7=CC=CC=C7)C8=CC=CC9=CC=CC=C98
• IUPAC Name: 10-naphthalen-1-yl-3,7-bis(4-phenylphenyl)phenoxazine
• InChIKey: IGGSSEOAGCUGDJ-UHFFFAOYSA-N
• INCHI: 1S/C46H31NO/c1-3-10-32(11-4-1)34-18-22-36(23-19-34)39-26-28-43-45(30-39)48-46-31-40(37-24-20-35(21-25-37)33-12-5-2-6-13-33)27-29-44(46)47(43)42-17-9-15-38-14-7-8-16-41(38)42/h1-31H
• PubChem CID: 129057445
• Peso molecular: 613.74

Propiedades químicas y físicas

• Punto de inflamación (°F): Not applicable
• Punto de inflamación (°C): Not applicable
• Punto de fusión (°C): 171℃