Phenylphosphonic Dichloride - ≥98% , CAS No.824-72-6

CAS: 824-72-6 Cat. No.: P160250 Peso molecular: 194.98 Beilstein Registry Number: 16804 Número EC: 212-534-3

GRADE & PURITY ≥98%

Synonyms

Phenylphosphonyl dichloride | C6H5Cl2OP | AKOS000120063 | P0334 | NSC 66477 | PhPOCl2 | BENZENE PHOSPHORUS OXYDICHLORIDE | Benzenephosphonodichloridic acid | DTXSID5044732 | p,p-Dichlorophenylphosphine oxide | Phenylphosphonic dichloride, 97% | InChI=1/C6

Storage

Room temperature,Argon charged

Shipped In

FedEx DG Service

Specifications

Sinónimos

Phenylphosphonyl dichloride | C6H5Cl2OP | AKOS000120063 | P0334 | NSC 66477 | PhPOCl2 | BENZENE PHOSPHORUS OXYDICHLORIDE | Benzenephosphonodichloridic acid | DTXSID5044732 | p, p-Dichlorophenylphosphine oxide | Phenylphosphonic dichloride, 97% | InChI=1/C6

Especificaciones y pureza

≥98%

Condiciones de almacenamiento de almacenamiento

Room temperature, Argon charged

Enviado en

FedEx DG Service

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥98%

Nombres e identificadores

• Sonrisas canónicas: C1=CC=C(C=C1)P(=O)(Cl)Cl
• IUPAC Name: dichlorophosphorylbenzene
• InChIKey: IBDMRHDXAQZJAP-UHFFFAOYSA-N
• INCHI: 1S/C6H5Cl2OP/c7-10(8,9)6-4-2-1-3-5-6/h1-5H
• Isómeros SMILES: C1=CC=C(C=C1)P(=O)(Cl)Cl
• Número ONU: 1760
• Grupo de embalaje: I
• Peso molecular: 194.98
• Beilstein: 16804
• Reaxy-Rn: 1072240

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Benzene and substituted derivatives
• Alternative Parents: Organic phosphonic acids and derivatives Organopnictogen compounds Organophosphorus compounds Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Monocyclic benzene moiety - Organophosphonic acid derivative - Organic oxygen compound - Organopnictogen compound - Organic oxide - Hydrocarbon derivative - Organophosphorus compound - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as benzene and substituted derivatives. These are aromatic compounds containing one monocyclic ring system consisting of benzene.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Miscible with benzene, chloroform, dimethyl sulfoxide and carbon tetrachloride.
• Sensibilidad: Moisture sensitive.
• Índice de refracción: 1.559
• Punto de inflamación (°F): 399.2 °F
• Punto de inflamación (°C): 204 °C
• Punto de ebullición (°C): 258 °C
• Punto de fusión (°C): 3°C
• Peso molecular: 194.980 g/mol
• XLogP3: 3.100
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 193.946 Da
• Monoisotopic Mass: 193.946 Da
• Topological Polar Surface Area: 17.100 Ų
• Heavy Atom Count: 10
• Formal Charge: 0
• Complexity: 148.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Zexi Zhao, Zhiyong Zhang, Caiying Sun, Miaojun Xu, Bin Li.  (2023)  A novel macromolecular phosphorus-nitrogen containing flame retardant for polycarbonate.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2023.110648]

2. Fukai Chu, Wei Wang, Yifan Zhou, Zhoumei Xu, Bin Zou, Xin Jiang, Yandong Hu, Weizhao Hu.  (2023)  Fully bio-based and intrinsically flame retardant unsaturated polyester cross-linked with isosorbide-based diluents.  CHEMOSPHERE,      [PMID:37820874] [10.1016/j.chemosphere.2023.140371]

3. Liangyuan Qi, Liang Chen, Wei Cai, Chuanshen Wang, Bangyu Wang, Yuan Hu, Weiyi Xing.  (2023)  Intelligent polyester fabric with fire safety for personal temperature management.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2023.146272]

4. Dan Meng, Hailiang Wang, Yuchun Li, Jian Liu, Jun Sun, Xiaoyu Gu, Haiqiao Wang, Sheng Zhang.  (2023)  Constructing lignin based nanoparticles towards flame retardant thermoplastic polyurethane composites with improved mechanical and oxidation resistant properties.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:37648133] [10.1016/j.ijbiomac.2023.126570]

5. Yanpeng Wu, Tonghui Yang, Yongchang Cheng, Tao Huang, Bin Yu, Qilin Wu, Meifang Zhu, Hao Yu.  (2023)  Synthesis phosphorus–sulfur reactive flame retardant for polyamide 66 with high flame retardant efficiency and low smoke.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2023.110378]

6. Yi-Ran Li, Ying-Ming Li, Wen-Juan Hu, Dan-Ping Zhu, Jose Hobson, Antonio Vázquez-López, De-Yi Wang.  (2023)  The designation of highly efficient intrinsic fame-retarding epoxy materials via the regulation of the phosphorus and nitrogen content for the curing agents.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2023.131078]

7. Di Zhang, Weihong Cao, Zhenghong Guo, Hongqiang Yan, Zhengping Fang, Peng Chen, Juan Li.  (2022)  Structure and properties of a flame retardant ternary vitrimer regulated by cyclic and long-chain dicarboxylic acids.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2022.110234]

8. Lin-Xuan Han, Ze-Yong Zhao, Cong Deng, Yu-Zhong Wang.  (2022)  Piperazine/Alkene-Containing Phosphoramide Oligomer for the Intumescent Flame Retardation of EPDM Rubber.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2022.109990]

9. Shikang Huo, Yang He, Zhenyuan Hu, Wei Bao, Weijie Chen, Yaying Wang, Danli Zeng, Hansong Cheng, Yunfeng Zhang.  (2022)  New insights into designation of single-ion conducting gel polymer electrolyte for high-performance lithium metal batteries.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2022.120287]

10. Yang Xianwen, Liu Xiaohui, Yang Xuan, Zhang Qiuyan, Zheng Yunbo, Ren Yuanlin, Cheng Bowen.  (2022)  A phosphorous/nitrogen-containing flame retardant with UV-curing for polyester/cotton fabrics.  CELLULOSE,  29  (2): (1263-1281).  [PMID:] [10.1007/s10570-021-04346-z]

11. Yue Xu, Yong Qiu, Chentao Yan, Lubin Liu, Miaojun Xu, Baoti Xu, Bin Li.  (2021)  A novel and multifunctional flame retardant nucleating agent towards superior fire safety and crystallization properties for biodegradable poly (lactic acid).  ADVANCED POWDER TECHNOLOGY,      [PMID:] [10.1016/j.apt.2021.09.026]

12. Jianwen Cheng, Huajun Duan, Shuang Yang, Jun Wang, Qianqian Zhang, Guoping Ding, Yefa Hu, Siqi Huo.  (2020)  A P/N-containing flame retardant constructed by phosphaphenanthrene, phosphonate, and triazole and its flame retardant mechanism in reducing fire hazards of epoxy resin.  JOURNAL OF APPLIED POLYMER SCIENCE,  137  (37): (49090).  [PMID:] [10.1002/app.49090]

13. Hao Wang, Heng Qi, Zekun Zhang, Kun Wang, Hongqiang Wang, Yu Tong.  (2024)  Phosphonic Chloride Assisted Fabrication of Highly Emissive Mixed Halide Perovskite Films in Ambient Air for Blue Light-Emitting Diodes.  ACS Applied Materials & Interfaces,      [PMID:38795117] [10.1021/acsami.3c19394]

14. Xiaohui Liu, Haojie Wang, Birong Zeng, Xindan Yi, Weiang Luo, Guorong Chen, Yiting Xu, Conghui Yuan, Lizong Dai.  (2024)  Phosphorus-containing curing agents with dynamic bonds endowing epoxy resins with flame retardancy and remolding capability.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2024.111260]

15. Yanlu Sun, Shuo Fan, Xiulin Li, Xubin Wang, Dequn Wu, Xueli Wang, Jianyong Yu, Ruchao Yuan, Faxue Li.  (2025)  Phosphorus-containing transition metal complexes endowing polyamide 6 and its filaments with flame retardancy, low heat-release, anti-dripping and UV-blocking properties.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2025.111233]

16. Jingsheng Wang, Jun Wang, Shuang Yang, Guoping Ding, Renxin Xu, Wei Liu, Jiuxiao Sun, Kaiwen Chen, Liu Duan, Jiaqi Wang, Hao Wang, Siqi Huo.  (2025)  Phosphorus-derived imidazolium salts with varied oxidation states: Tailoring latency, mechanical properties, and flame retardancy in single-component epoxy resins.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2025.111325]

17. Tongshuai Tian, Xi Shu, Tianyi Han, Li Liu.  (2025)  Biobased Phosphorus-Nitrile Flame Retardant from Vanillin for Thermoplastic Poly(ester ether) Elastomers: Enhanced Fire Safety and Antidripping Performance.  ACS Applied Polymer Materials,      [PMID:] [10.1021/acsapm.5c01756]

18. Yuxiang Yi, Hongfei He, Lu Liu, Na Sun, Keqing Zhou, Xiaodong Qian, Congling Shi, Yuan Hu, Bin Yu.  (2025)  Mechanically-robust phosphorus-contained ionogels by UV-curing for fire warning sensor and fire protection.  POLYMER,      [PMID:] [10.1016/j.polymer.2025.129058]

19. Xiao-Hui Shi, Huan Luo, Cheng-Yue Jing, Qing-Yun Liu, De-Yi Wang.  (2025)  Effectively enhancing the fire resistance and mechanical properties of basalt fiber/epoxy composites utilizing a novel piperazine phosphonate flame retardant.  CONSTRUCTION AND BUILDING MATERIALS,      [PMID:] [10.1016/j.conbuildmat.2025.141895]

20. Yujie Chen, Qiu Shi, Jinlei Liu, Haojie Mei, Weiyin Wang, Chuanxi Xiong, Shan Wang, Yilin Tang, Shipeng Zhu.  (2025)  Performance and Mechanisms of P–N Synergistic Oligomeric Flame Retardants with Different Phosphorus Oxidation States in Epoxy Resin.  ChemistrySelect,  10  (21): (e01534).  [PMID:] [10.1002/slct.202501534]

21. Yu Zhu, Liying Guo, Ruiyue Zhang, Qianqian Tian, Hongzhang Cao, Li Wang, Yu Tang, Liangliang Liu.  (2025)  Functionalization of hierarchical porous carbon materials for adsorption of light rare earth ions.  Journal of Materials Chemistry A,      [PMID:] [10.1039/D5TA02473K]

22. Li Dang, Jia Liu, Xinyi Bao, Yongkui Zheng, Zhihui Lv.  (2025)  Interfacial Engineering of Polyvinyl Chloride/Molybdenum Trioxide Doped Magnesium Hydroxide Composite via Chain-Length Tunable Si-P Polyether Modifiers: Synergistic Enhancement of Mechanical Properties and Flame Retardancy.  JOURNAL OF APPLIED POLYMER SCIENCE,  142  (43): (e57676).  [PMID:] [10.1002/app.57676]

23. Qiuting Cai, Xinyang Wang, Yifeng Feng, Guochao Lu, Qingli Cao, Dingshuo Zhang, Yun Gao, Meiyi Zhu, Baodan Zhao, Haiping He, Dawei Di, Zhizhen Ye, Xingliang Dai.  (2025)  Unravel the impacts of deep-level defects on auger recombination in nanocrystals for realizing low-threshold blue amplified spontaneous emission.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.169849]

24. Dejun Wen, Yang Li, Lei Du, Zhiming Jiang.  (2025)  A novel strategy for fabricating highly-efficient flame-retardant polyester fabrics utilizing dual phosphorus oxidation states.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2025.111740]

25. Ying Wang, Jianhao Zhu, Changhao Sun, Yili Duan, Jihang Wang, Zhihui Liu, Xilei Chen, Menghe Zhu, Pingan Song, Lei Liu.  (2025)  Fire-retardant superhydrophobic graphene-modified foam for oil/water separation.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.170752]

26. Yu Huang, Guoping Zhu, Zhennan Wang, Yadong Wang, Zongmin Zhu.  (2025)  The ultra-low addition of P/Si/N-containing flame retardant towards simultaneous enhancement of flame retardancy, mechanics and degradability of PLA.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.171625]

27. Yi-fan Zha, Yang Gou, Zhi-xuan Zhang, Zhi-yuan Lan, De-xiang Sun, Yong Wang.  (2025)  A novel polyphosphoramide additive breaks the flame retardancy, mechanical properties, and heat resistance trilemma in polylactic acid.  POLYMER,      [PMID:] [10.1016/j.polymer.2025.129529]

28. Han Feng, Yijing Chen, Hao Zeng, Chunhong Zhang, Guanxi Li, Yuning Gong, Lu Wang, Lei Shang.  (2026)  A rigid-flexible integrated isocyanate simultaneous flame retardant and toughened, reinforced epoxy resin.  JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,      [PMID:] [10.1016/j.jiec.2026.01.037]

29. Jinpeng Liu, Hongmei Mu, Junchao Huang, Yuhua Wang.  (2026)  Flame-Retardant Synergism through Chemical Intercalation for Rigid Polyurethane Foam by Using Intrinsic/inorganic Combination.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.5c03245]

30. Ronghao Wang, Shoushun Dong, Shuqi Li, Haoyang Zhang, Yuchuan Li, Xiangmei Li.  (2026)  Preparation of High Fire Safety Polyamide 66 Using Polyphosphazene to Promote Char Formation of Diethyl Aluminum Phosphinate.  JOURNAL OF POLYMER SCIENCE,      [PMID:] [10.1002/pola.70098]