Phosphomolybdic acid hydrate - Mo：45% - 63% , CAS No.51429-74-4

CAS: 51429-74-4 Cat. No.: P305387 Peso molecular: 1825.25 (anhydrous basis) Número EC: 610-660-7

GRADE & PURITY Mo：45% - 63%

Synonyms

Phosphoric acid, anhydride with molybdic acid | Phosphomolybdic acid [MI] | Phosphomolybdic acid hydrate, moist crystals | PHOSPHOMOLYBDICACIDHYDRATE | Phosphomolybdic acid hydrate, SAJ special grade | Molybdenumphosphorus hydroxide oxide | Phosphomolybdi

Storage

Room temperature,Argon charged,Desiccated,Cool

Shipped In

Normal

Descripción general

Phosphomolybdic acid (PMA) hydrate is primarily used in spectrophotometric determination of phosphate ions. PMA is a component in the 3-color histology stain called Masson’s trichrome; employed in the differentiation step, Phosphomolybdic acid is one of the solutions fixed tissues are immersed in prior to subsequent staining. Phosphomolybdic acid is also used as reagent for simple and rapid colorimetric determination of phenothiazine derivatives. PMA oxidizes the phenothiazine derivative to a cationic free radical, forming a coloured salt. A preliminary extraction is necessary if certain reductants (sulphite or ascorbic acid) are present as stabilizers, as they will reduce the reagent to phosphomolybdenum blue.

A reagent used for spectrophotometric determination of phosphate ions.Employed in preparation of a hybrid organic-inorganic, electroactive material with potential application as a cation-insertion electrode in batteries.

Phosphomolybdic acid hydrate may be used in the synthesis of molybdenum disulfide (MoS2)-reduced graphene oxide (RGO) composites with potential application as electrodes for sodium ion battery. It may also be used as a catalyst precursor in the presence of hydrogen peroxide as oxidant for the dibenzothiophenes oxidation in diesel fuels.

A precursor to hybrid organic-inorganic based molecular batteries with applications as cation-insertion electrodes.

Specifications

Sinónimos

Phosphoric acid, anhydride with molybdic acid | Phosphomolybdic acid [MI] | Phosphomolybdic acid hydrate, moist crystals | PHOSPHOMOLYBDICACIDHYDRATE | Phosphomolybdic acid hydrate, SAJ special grade | Molybdenumphosphorus hydroxide oxide | Phosphomolybdi

Especificaciones y pureza

Mo：45% - 63%

Condiciones de almacenamiento de almacenamiento

Room temperature, Argon charged, Desiccated, Cool

Enviado en

Normal

Nombres e identificadores

• Pubchem Sid: 504768125
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504768125
• Sonrisas canónicas: O.OP(=O)(O)O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O
• IUPAC Name: phosphoric acid;trioxomolybdenum;hydrate
• InChIKey: PDDXOPNEMCREGN-UHFFFAOYSA-N
• INCHI: 1S/12Mo.H3O4P.H2O.36O/c;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;(H3,1,2,3,4);1H2
• Isómeros SMILES: O.OP(=O)(O)O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O
• WGK Alemania: 3
• Número ONU: 3088
• Grupo de embalaje: III
• Peso molecular: 1825.25 (anhydrous basis)

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Mixed metal/non-metal compounds
    • Clase Transition metal oxoanionic compounds
      • Subclass Transition metal phosphates

• Kingdom: Inorganic compounds
• Superclass: Mixed metal/non-metal compounds
• Clase: Transition metal oxoanionic compounds
• Subclass: Transition metal phosphates
• Intermediate Tree Nodes: Not available
• Direct Parent: Transition metal phosphates
• Alternative Parents: Inorganic salts Inorganic oxides
• Molecular Framework: Not available
• Substituents: Transition metal phosphate - Inorganic oxide - Inorganic salt
• Descripción: This compound belongs to the class of inorganic compounds known as transition metal phosphates. These are inorganic compounds in which the largest oxoanion is phosphate, and in which the heaviest atom not in an oxoanion is a transition metal.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Soluble in water, ethanol, and ether.
• Sensibilidad: Hygroscopic
• Punto de fusión (°C): 90℃
• Peso molecular: 1843.400 g/mol
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 41
• Rotatable Bond Count: 0
• Exact Mass: 1841.67 Da
• Monoisotopic Mass: 1866.67 Da
• Topological Polar Surface Area: 693.000 Ų
• Heavy Atom Count: 54
• Formal Charge: 0
• Complexity: 112.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 14

XLogP3

Referencias

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