Determine the necessary mass, volume, or concentration for preparing a solution.
Reagent grade, 115% H3PO4 basis Reagent Grade for sensitive chromatographic and analytical workflows requiring minimal baseline interference.
Room temperature,Argon charged Ships FedEx DG Service Check lot-specific COA for exact specifications.
SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.
Cited in 79 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.
Polyphosphoric acid (PPA) is widely employed as acylation and alkylation reagent in various reactions. It is a strong mineral acid with excellent dehydrating properties.
Application
Polyphosphoric acid may be used in the synthesis of aromatic sulfones, N -substituted amides and 4-aminobenzophenones. It may also be used in dehydration, Fischer-Indole Synthesis, Beckmann Rearrangement and Schmidt Rearrangement reactions. It can be used as a catalyst in the synthesis of various aromatic ketones. PPA may be used as a catalyst during the synthesis of dimethyl carbonate (DMC) from urea and methanol. It also acts as an absorbent for the ammonia generated in the process. PPA may be used to prepare silica-supported polyphosphoric acid (PPA-SiO 2 ), an easy to handle, reusable heterogenous catalyst.
Other Notes
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| Pubchem Sid | 504772323 |
|---|---|
| Pubchem Sid Url | https://pubchem.ncbi.nlm.nih.gov/substance/504772323 |
| Sonrisas canónicas | OP(=O)(O)O.O1OP2OOP1O2 |
| IUPAC Name | 2,3,5,6,7-pentaoxa-1,4-diphosphabicyclo[2.2.1]heptane;phosphoric acid |
| InChIKey | FVYIVXLIMHNYTD-UHFFFAOYSA-N |
| INCHI | 1S/O5P2.H3O4P/c1-2-7-4-3-6(1)5-7;1-5(2,3)4/h;(H3,1,2,3,4) |
| Isómeros SMILES | OP(=O)(O)O.O1OP2OOP1O2 |
| WGK Alemania | 1 |
| PubChem CID | 73357664 |
| Número ONU | 3264 |
| Grupo de embalaje | I |
Comprehensive hazard, handling, storage, and regulatory compliance document.
Download SDS →Lot-specific quality data. Enter your lot number to retrieve the exact COA.
Look up COA →Full quality attributes and acceptance criteria for this grade.
View spec sheet →Find and download the COA for your product by matching the lot number on the packaging.
| Lot Number | Certificate Type | Fecha | Articulo |
|---|---|---|---|
| Certificate of Analysis | Feb 04, 2026 | P434208 | |
| Certificate of Analysis | Feb 04, 2026 | P434208 | |
| Certificate of Analysis | Feb 10, 2025 | P434208 | |
| Certificate of Analysis | Feb 10, 2025 | P434208 | |
| Certificate of Analysis | Feb 10, 2025 | P434208 | |
| Certificate of Analysis | Feb 10, 2025 | P434208 | |
| Certificate of Analysis | Feb 10, 2025 | P434208 | |
| Certificate of Analysis | Feb 10, 2025 | P434208 | |
| Certificate of Analysis | Feb 10, 2025 | P434208 | |
| Certificate of Analysis | Aug 16, 2024 | P434208 | |
| Certificate of Analysis | Jun 20, 2023 | P434208 |
| 1. Jiayuan Ji, Yuyang Han, Fei Xu, Fuqiang Chu, Yanting Li, Bencai Lin. (2023) Guanidinium/Hydroxyl-Functionalized Polybenzimidazole for High-Temperature Proton Exchange Membrane Fuel Cell Applications. ACS Applied Energy Materials, [PMID:] [10.1021/acsaem.3c02471] |
| 2. Yanwen Guo, Zhenzhen Cai, Fei Yan, Da Lei, Yanan Guo, Shuhai Zhang, Xincun Dou. (2023) Precise Electron-Withdrawing Strength Modulation of ESIPT Probes for Ultrasensitive and Specific Fluorescence Sensing. ANALYTICAL CHEMISTRY, [PMID:37260031] [10.1021/acs.analchem.3c01120] |
| 3. Xiaorui Wang, Shuang Wang, Han Sun, Chenglong Li, Feng Pan, Tongtong Gao, Yu Luo, Xiaojuan Wang, Zhe Wang. (2023) VRFBs based on benzotriazole grafted polybenzimidazole / polymeric ionic liquid with high ion selectivity. ELECTROCHIMICA ACTA, [PMID:] [10.1016/j.electacta.2023.142619] |
| 4. Junming Dai, Yu Zhang, Chunli Gong, Yinhua Wan, Yongbing Zhuang. (2023) Soluble polybenzimidazoles incorporating Tröger’s base for high-temperature proton exchange membrane fuel cells. CHEMICAL ENGINEERING JOURNAL, [PMID:] [10.1016/j.cej.2023.143151] |
| 5. Yutong Zhao, Bo Lv, Wei Song, Jinkai Hao, Junfang Zhang, Zhigang Shao. (2023) Influence of the PBI structure on PBI/CsH5(PO4)2 membrane performance for HT-PEMFC application. JOURNAL OF MEMBRANE SCIENCE, [PMID:] [10.1016/j.memsci.2023.121531] |
| 6. Jinxi Zhang, Duowang Yang, Guoqiang Sun, Yiwen Li, Yue Qi, Xiaoyan Ma. (2023) Roles of recycled oils, polyphosphoric acid and sulfur on chemo-rheological and morphological properties of high-viscosity modified asphalt. CONSTRUCTION AND BUILDING MATERIALS, [PMID:] [10.1016/j.conbuildmat.2023.130724] |
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| 8. Ge Chao, Hongying Tang, Qing Ju, Nanwen Li, Kang Geng. (2022) Fluorinated polybenzimidazole as binders for high-temperature proton exchange membrane fuel cells. JOURNAL OF POWER SOURCES, [PMID:] [10.1016/j.jpowsour.2022.232473] |
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| 15. Hongying Tang, David Aili, Kang Geng, Jian Gao, Qingfeng Li, Nanwen Li. (2021) On the stability of imidazolium and benzimidazolium salts in phosphoric acid based fuel cell electrolytes. JOURNAL OF POWER SOURCES, [PMID:] [10.1016/j.jpowsour.2021.230642] |
| 16. Zongmin Ma, Zishuo Yan, Xia Yin, Yang Si, Jianyong Yu, Bin Ding. (2021) Antibacterial and antiviral nanofibrous membranes with renewable oxidative function for high-efficiency and super-throughput water disinfection. COMPOSITES COMMUNICATIONS, [PMID:] [10.1016/j.coco.2021.100875] |
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| 18. Dan Zhao, Zhixia Zhang, Xuemei Liu, Rui Zhang, Xincai Xiao. (2020) Rapid and low-temperature synthesis of N, P co-doped yellow emitting carbon dots and their applications as antibacterial agent and detection probe to Sudan Red I. Materials Science & Engineering C-Materials for Biological Applications, [PMID:33321593] [10.1016/j.msec.2020.111468] |
| 19. Junqiao Jiang, Erli Qu, Min Xiao, Dongmei Han, Shuanjin Wang, Yuezhong Meng. (2020) 3D Network Structural Poly (Aryl Ether Ketone)-Polybenzimidazole Polymer for High-Temperature Proton Exchange Membrane Fuel Cells. ADVANCES IN POLYMER TECHNOLOGY, [PMID:] [10.1155/2020/4563860] |
| 20. Chongxiong Duan, Haochuan Luo, Jingling Li, Cuiyin Liu. (2020) A novel strategy to construct polybenzimidazole linked crosslinking networks for polymer electrolyte fuel cell applications. POLYMER, [PMID:] [10.1016/j.polymer.2020.122555] |
| 21. Jiao Yang, Chen Guofei, Zhou Haijun, Zhang Feng, Chen Xiaoqi, Li Yantao, Xiao Xueshan, Fang Xingzhong. (2019) Synthesis and properties of processable poly(benzimidazole-imide)s based on 2-(3-aminophenyl)-5-aminobenzimidazole. JOURNAL OF POLYMER RESEARCH, 26 (12): (1-12). [PMID:] [10.1007/s10965-019-1930-2] |
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| 23. Guohua Sun, Bingxue Liu, Hongqing Niu, Fuyao Hao, Nanjun Chen, Mengying Zhang, Guofeng Tian, Shengli Qi, Dezhen Wu. (2019) In situ welding: Superb strength, good wettability and fire resistance tri-layer separator with shutdown function for high-safety lithium ion battery. JOURNAL OF MEMBRANE SCIENCE, [PMID:] [10.1016/j.memsci.2019.117509] |
| 24. Chenxiao Lin, Jixia Wang, Guohong Shen, Junfei Duan, Dong Xie, Faliang Cheng, Yan Zhang, Shiguo Zhang. (2019) Construction of crosslinked polybenz imidazole-based anion exchange membranes with ether-bond-free backbone. JOURNAL OF MEMBRANE SCIENCE, [PMID:] [10.1016/j.memsci.2019.117303] |
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| 27. Xiangxu Cui, Tingting Li, Jiashuang Li, Yukun An, Libao An, Xinmu Zhang, Zhiming Zhang. (2018) A highly selective and reversible turn-off fluorescent chemosensor for Cu2+ based on electrospun nanofibrous membrane modified with pyrenecarboxaldehyde. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, [PMID:30243105] [10.1016/j.saa.2018.09.021] |
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| 30. Xiao Yang, Lian Duan, Xiaoqi Ran. (2018) Photocatalytic degradation of organic dyes by a donor–acceptor type conjugated polymer: poly(thiophene-1,3,4-oxadiazole) and its photocatalytic mechanism. POLYMER INTERNATIONAL, 67 (9): (1282-1290). [PMID:] [10.1002/pi.5652] |
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| 67. Zhiliang Ma, Chao Xie, YueZhou Wei, Xiangbiao Yin, Caiwu Luo, Shunyan Ning, Qiang Wu, Tianjiao Jiang. (2025) High-efficiency separation of Pd from high-level liquid waste by a novel silica-based sorbent modified with polybenzimidazole. SEPARATION AND PURIFICATION TECHNOLOGY, [PMID:] [10.1016/j.seppur.2025.133401] |
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