Purity reference material of isocarbophos pesticide - ≥99.4%, U=0.4%(k=2) , CAS No.24353-61-5

CAS: 24353-61-5 Cat. No.: P283861 Peso molecular: 289.29 Número EC: 246-192-1 PubChem CID: 90479

GRADE & PURITY ≥99.4%, U=0.4%(k=2)

Synonyms

DL-5-Hydroxylysine (hydrochloride) | O-Methyl O-[2-(isopropoxycarbonyl)phenyl] phosphoramidothioate | Isocarbofos 1000 microg/mL in Acetone | CHEBI:38704 | AI3-27659 | DTXCID5022063 | O-Methylphosphoramidothioate, O-ester with isopropyl salicylate | Pesti

Storage

Store at 2-8°C,Protected from light,Desiccated

Shipped In

Wet ice,FedEx DG Service

Descripción general

The sample should be balanced to room temperature before use. After opening, the seal should be restored as soon as possible and stored under the specified conditions. This reference material is a kind of toxic and harmful substance. When using it, pay attention to protection and avoid inhalation or contact with skin.

Specifications

Sinónimos

DL-5-Hydroxylysine (hydrochloride) | O-Methyl O-[2-(isopropoxycarbonyl)phenyl] phosphoramidothioate | Isocarbofos 1000 microg/mL in Acetone | CHEBI:38704 | AI3-27659 | DTXCID5022063 | O-Methylphosphoramidothioate, O-ester with isopropyl salicylate | Pesti

Especificaciones y pureza

≥99.4%, U=0.4%(k=2)

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Protected from light, Desiccated

Enviado en

Wet ice, FedEx DG Service

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥99.4%

Nombres e identificadores

• Sonrisas canónicas: CC(C)OC(=O)C1=CC=CC=C1OP(=S)(N)OC
• IUPAC Name: propan-2-yl 2-[amino(methoxy)phosphinothioyl]oxybenzoate
• InChIKey: YFVOXLJXJBQDEF-UHFFFAOYSA-N
• INCHI: 1S/C11H16NO4PS/c1-8(2)15-11(13)9-6-4-5-7-10(9)16-17(12,18)14-3/h4-8H,1-3H3,(H2,12,18)
• Isómeros SMILES: CC(C)OC(=O)C1=CC=CC=C1OP(=S)(N)OC
• PubChem CID: 90479
• Número ONU: 3464
• Peso molecular: 289.29

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Benzoic acids and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Benzoic acids and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Benzoic acid esters
• Alternative Parents: Phenoxy compounds Benzoyl derivatives Thiophosphoric acid esters Carboxylic acid esters Monocarboxylic acids and derivatives Organooxygen compounds Organic oxides Organic nitrogen compounds Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Benzoate ester - Phenoxy compound - Benzoyl - Organic thiophosphoric acid or derivatives - Thiophosphoric acid ester - Carboxylic acid ester - Monocarboxylic acid or derivatives - Carboxylic acid derivative - Organic nitrogen compound - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organooxygen compound - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as benzoic acid esters. These are ester derivatives of benzoic acid.
• External Descriptors: salicylates - organic phosphonate - phosphonic ester - organothiophosphate insecticide

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Light sensitive.
• Peso molecular: 289.290 g/mol
• XLogP3: 2.400
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 289.054 Da
• Monoisotopic Mass: 289.054 Da
• Topological Polar Surface Area: 103.000 Ų
• Heavy Atom Count: 18
• Formal Charge: 0
• Complexity: 337.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 1
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Yufeng Zhang, Lingli Jiang, Yang Chen, Qianjun Zhang, Chao Kang, Dongmei Chen.  (2023)  Detection of chlorpyrifos residue in apple and rice samples based on aptamer sensor: Improving quantitative accuracy with partial least squares model.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2023.109352]

2. Ying Wang, Li Yin, Guangxu Qu, Chung-Hang Leung, Lei Han, Lihua Lu.  (2023)  Highly Active Single-Atom Nanozymes with High-Loading Iridium for Sensitive Detection of Pesticides.  ANALYTICAL CHEMISTRY,      [PMID:37530640] [10.1021/acs.analchem.3c01569]

3. Feng Luo, Yue Tang, Jia Zheng, Zhengmin Xie, Junjun Wang, Jianli Zhou, Yuangen Wu.  (2023)  Smartphone-assisted colorimetric aptasensor for rapid detection of carbendazim residue in agriculture products based on the oxidase-mimicking activity of octahedral Ag2O nanoparticles.  TALANTA,      [PMID:37385190] [10.1016/j.talanta.2023.124845]

4. Xiangqiang Zhan, Yue Tang, Yuanyuan Liu, Han Tao, Yuangen Wu.  (2022)  A novel colorimetric strategy for rapid detection of dimethoate residue in vegetables based on enhancing oxidase-mimicking catalytic activity of cube-shape Ag2O particles.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2022.131720]

5. Jian Zhang, Xiaobo Fang, Jayne Wu, Zhiwen Hu, Yu Jiang, Haochen Qi, Lei Zheng, Xiaofeng Xuan.  (2019)  An interdigitated microelectrode based aptasensor for real-time and ultratrace detection of four organophosphorus pesticides.  BIOSENSORS & BIOELECTRONICS,      [PMID:31767346] [10.1016/j.bios.2019.111879]

6. Luo Danqiu, Chen Huayun, Zhou Pei, Tao Han, Wu Yuangen.  (2019)  Oligonucleotides and pesticide regulated peroxidase catalytic activity of hemin for colorimetric detection of isocarbophos in vegetables by naked eyes.  ANALYTICAL AND BIOANALYTICAL CHEMISTRY,  411  (29): (7857-7868).  [PMID:31705220] [10.1007/s00216-019-02185-3]

7. Lei Tan, Manli Guo, Jiean Tan, Yuanyuan Geng, Shuyi Huang, Youwen Tang, Chaochin Su, ChunChe Lin, Yong Liang.  (2019)  Development of high-luminescence perovskite quantum dots coated with molecularly imprinted polymers for pesticide detection by slowly hydrolysing the organosilicon monomers in situ.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2019.04.079]

8. Huan Li, Hongyu Chen, Mingxia Li, Qiujun Lu, Youyu Zhang, Shouzhuo Yao.  (2019)  Template protection of gold nanoclusters for the detection of organophosphorus pesticides.  NEW JOURNAL OF CHEMISTRY,  43  (14): (5423-5428).  [PMID:] [10.1039/C9NJ01007F]

9. Kang Yan, Li Long, Chen Wanchao, Zhang Feiyu, Du Yiping, Wu Ting.  (2018)  Rapid In Situ SERS Analysis of Pesticide Residues on Plant Surfaces Based on Micelle Extraction of Targets and Stabilization of Ag Nanoparticle Aggregates.  Food Analytical Methods,  11  (11): (3161-3169).  [PMID:] [10.1007/s12161-018-1290-2]

10. Huayun Chen, Yuangen Wu, Wenping Yang, Shenshan Zhan, Shuyi Qiu, Pei Zhou.  (2016)  Ultrasensitive and selective detection of isocarbophos pesticide based on target and random ssDNA triggered aggregation of hemin in polar organic solutions.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2016.12.014]

11. Qi Shu, Limin Wang, Hui Ouyang, Wenwen Wang, Fengquan Liu, Zhifeng Fu.  (2016)  Multiplexed immunochromatographic test strip for time-resolved chemiluminescent detection of pesticide residues using a bifunctional antibody.  BIOSENSORS & BIOELECTRONICS,      [PMID:27664410] [10.1016/j.bios.2016.09.057]

12. Hui Ouyang, Limin Wang, Shijia Yang, Wenwen Wang, Lin Wang, Fengquan Liu, Zhifeng Fu.  (2015)  Chemiluminescence Reaction Kinetics-Resolved Multianalyte Immunoassay Strategy Using a Bispecific Monoclonal Antibody as the Unique Recognition Reagent.  ANALYTICAL CHEMISTRY,      [PMID:25622025] [10.1021/ac5045093]

13. Linghui Huang, Yue Tang, Jianxun Han, Xiaojuan Niu, Xin Lin, Yuangen Wu.  (2024)  A stable colorimetric biosensor for highly selective detection of malathion residue in food based on aptamer-regulated laccase-mimic activity.  FOOD CHEMISTRY,      [PMID:38428076] [10.1016/j.foodchem.2024.138842]

14. Yue Tang, Xiangqiang Zhan, Jia Zheng, Zhengmin Xie, Shuangju Zhu, Yuangen Wu.  (2023)  Facile colorimetric smartphone-based biosensor for rapid detection of organophosphorus pesticides residues in environment using the aptamer-enhanced oxidase activity of octahedral Ag2O particles.  ANALYTICA CHIMICA ACTA,      [PMID:37230725] [10.1016/j.aca.2023.341325]