(R)-(+)-2-difenilfosfino-2'-metoxi-1,1'-binaftilo - ≥96% , CAS No.145964-33-6

CAS: 145964-33-6 Cat. No.: D489387 Peso molecular: 468.54 Número EC: 813-339-1

GRADE & PURITY ≥96%

Synonyms

(R)-(2 inverted exclamation mark -Methoxy-[1,1 inverted exclamation mark -binaphthalen]-2-yl)diphenylphosphine | AKOS016005658 | AKOS015895300 | J-008175 | MFCD00269686 | SC11349 | (R)- 2- diphenylphosphino, 2'-hydroxyl-1,1'-binaphthyl | (r)-(+)-2-(diphen

Storage

Argon charged,Room temperature

Shipped In

Normal

Descripción general

Ligando utilizado en la hidrosilación asimétrica catalizada por paladio de olefinas, la reducción catalizada por paladio de ésteres alílicos, las reacciones de adición asimétrica catalizadas por rodio y las reacciones de aminación asimétrica catalizadas por complejos de cobre(I).

el (R)-MOP se utiliza como catalizador en la preparación de alquilideneboronatos y oxindoles de tetrahidrobenzofuranona quirales. También se utiliza como catalizador en la síntesis total de Oseltamivir Fosfato；un inhibidor oralmente activo de la neuraminidasa del virus de la gripe y un fármaco antiviral.

Specifications

Sinónimos

(R)-(2 inverted exclamation mark -Methoxy-[1, 1 inverted exclamation mark -binaphthalen]-2-yl)diphenylphosphine | AKOS016005658 | AKOS015895300 | J-008175 | MFCD00269686 | SC11349 | (R)- 2- diphenylphosphino, 2'-hydroxyl-1, 1'-binaphthyl | (r)-(+)-2-(diphen

Especificaciones y pureza

≥96%

Condiciones de almacenamiento de almacenamiento

Argon charged, Room temperature

Enviado en

Normal

Pureza

≥96%

Nombres e identificadores

• Pubchem Sid: 488194747
• Sonrisas canónicas: COC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)P(C5=CC=CC=C5)C6=CC=CC=C6
• IUPAC Name: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane
• InChIKey: KRWTWSSMURUMDE-UHFFFAOYSA-N
• INCHI: 1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3
• Isómeros SMILES: COC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)P(C5=CC=CC=C5)C6=CC=CC=C6
• WGK Alemania: 3
• Peso molecular: 468.54
• Reaxy-Rn: 4889178
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=4889178&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Naphthalenes Anisoles Alkyl aryl ethers Organic phosphines and derivatives Hydrocarbon derivatives
• Molecular Framework: Aromatic homopolycyclic compounds
• Substituents: Triphenylphosphine - Naphthalene - Phenol ether - Anisole - Phenylphosphine - Alkyl aryl ether - Phosphine - Ether - Organic oxygen compound - Hydrocarbon derivative - Organophosphorus compound - Organooxygen compound - Aromatic homopolycyclic compound
• Descripción: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Soluble in toluene
• Sensibilidad: Air & Moisture Sensitive
• Rotación específica [α]: 94° (C=0.3,CHCl3)
• Punto de fusión (°C): 193°C
• Peso molecular: 468.500 g/mol
• XLogP3: 8.700
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 468.164 Da
• Monoisotopic Mass: 468.164 Da
• Topological Polar Surface Area: 9.200 Ų
• Heavy Atom Count: 35
• Formal Charge: 0
• Complexity: 633.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1