RuCl[(R,R)-TsDPEN](mesitylene) - ≥90%(HPLC) , CAS No.174813-82-2

CAS: 174813-82-2 Cat. No.: R138379 Peso molecular: 622.18 Número EC: 806-980-3 PubChem CID: 91972075

GRADE & PURITY ≥90%(HPLC)

Synonyms

R0127 | [(1R,2R)-2-Amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;ruthenium(2+);1,3,5-trimethylbenzene;chloride | Chloro(mesitylene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II) | [(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-t

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

Ligands and Complexes for Asymmetric Reactions

RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:

· (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).

· Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.

Specifications

Sinónimos

R0127 | [(1R, 2R)-2-Amino-1, 2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;ruthenium(2+);1, 3, 5-trimethylbenzene;chloride | Chloro(mesitylene)[(R, R)-N-(p-toluenesulfonyl)-1, 2-diphenylethylenediamine]ruthenium(II) | [(R, R)-N-(2-Amino-1, 2-diphenylethyl)-p-t

Especificaciones y pureza

≥90%(HPLC)

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥90%(HPLC)

Nombres e identificadores

• Sonrisas canónicas: CC1=CC=C(C=C1)S(=O)(=O)[N-]C(C2=CC=CC=C2)C(C3=CC=CC=C3)N.CC1=CC(=CC(=C1)C)C.[Cl-].[Ru+2]
• IUPAC Name: [(1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;ruthenium(2+);1,3,5-trimethylbenzene;chloride
• InChIKey: XBNBOGZUDCYNOJ-AGEKDOICSA-M
• INCHI: 1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
• Isómeros SMILES: CC1=CC=C(C=C1)S(=O)(=O)[N-][C@H](C2=CC=CC=C2)[C@@H](C3=CC=CC=C3)N.CC1=CC(=CC(=C1)C)C.[Cl-].[Ru+2]
• WGK Alemania: 3
• PubChem CID: 91972075
• Peso molecular: 622.18

Propiedades químicas y físicas

• Sensibilidad: Air sensitive;heat sensitive;Moisture sensitive
• Punto de fusión (°C): 241-249 °C