(S)-(+)-2,2''-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl - ≥97% , CAS No.919338-66-2

CAS: 919338-66-2 Cat. No.: S281938 Peso molecular: 1091.52 PubChem CID: 46910330

GRADE & PURITY ≥97%

Synonyms

(S)-(+)-2,2''-Bis[di(3,5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl | (S)-3,5-iPr-4-NMe2-MeOBIPHEP | SL-A107-2：(S)​-​(6,​6'-​Dimethoxybiphenyl-​2,​2'-​diyl)​bis{bis[3,​5-​diisopropyl-​4-​(dimethylamino)​phenyl]​phosphine}

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

Atropisomeric MeOBIPHEP ligands

Specifications

Sinónimos

(S)-(+)-2, 2''-Bis[di(3, 5-di-i-propyl-4-dimethylaminophenyl)phosphino]-6, 6''-dimethoxy-1, 1''-biphenyl | (S)-3, 5-iPr-4-NMe2-MeOBIPHEP | SL-A107-2：(S)​-​(6, ​6'-​Dimethoxybiphenyl-​2, ​2'-​diyl)​bis{bis[3, ​5-​diisopropyl-​4-​(dimethylamino)​phenyl]​phosphine}

Especificaciones y pureza

≥97%

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥97%

Nombres e identificadores

• Sonrisas canónicas: CC(C)C1=CC(=CC(=C1N(C)C)C(C)C)P(C2=CC=CC(=C2C3=C(C=CC=C3P(C4=CC(=C(C(=C4)C(C)C)N(C)C)C(C)C)C5=CC(=C(C(=C5)C(C)C)N(C)C)C(C)C)OC)OC)C6=CC(=C(C(=C6)C(C)C)N(C)C)C(C)C
• IUPAC Name: 4-[[2-[2-bis[4-(dimethylamino)-3,5-di(propan-2-yl)phenyl]phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-[4-(dimethylamino)-3,5-di(propan-2-yl)phenyl]phosphanyl]-N,N-dimethyl-2,6-di(propan-2-yl)aniline
• InChIKey: SBQGDYGNDIQAIT-UHFFFAOYSA-N
• INCHI: 1S/C70H100N4O2P2/c1-41(2)53-33-49(34-54(42(3)4)67(53)71(17)18)77(50-35-55(43(5)6)68(72(19)20)56(36-50)44(7)8)63-31-27-29-61(75-25)65(63)66-62(76-26)30-28-32-64(66)78(51-37-57(45(9)10)69(73(21)22)58(38-51)46(11)12)52-39-59(47(13)14)70(74(23)24)60(40-52)48(15)16/h27-48H,1-26H3
• Isómeros SMILES: CC(C)C1=CC(=CC(=C1N(C)C)C(C)C)P(C2=CC=CC(=C2C3=C(C=CC=C3P(C4=CC(=C(C(=C4)C(C)C)N(C)C)C(C)C)C5=CC(=C(C(=C5)C(C)C)N(C)C)C(C)C)OC)OC)C6=CC(=C(C(=C6)C(C)C)N(C)C)C(C)C
• WGK Alemania: 3
• PubChem CID: 46910330
• Peso molecular: 1091.52

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Biphenyls and derivatives Phenylpropanes Cumenes Phenoxy compounds Methoxybenzenes Dialkylarylamines Anisoles Aniline and substituted anilines Alkyl aryl ethers Organic phosphines and derivatives Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Triphenylphosphine - Biphenyl - Cumene - Phenylpropane - Anisole - Phenoxy compound - Phenol ether - Dialkylarylamine - Aniline or substituted anilines - Methoxybenzene - Phenylphosphine - Alkyl aryl ether - Phosphine - Tertiary amine - Ether - Organophosphorus compound - Organooxygen compound - Organonitrogen compound - Organic oxygen compound - Hydrocarbon derivative - Organic nitrogen compound - Amine - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Air sensitive ；Light sensitive
• Peso molecular: 1091.500 g/mol
• XLogP3: 18.400
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 21
• Exact Mass: 1090.73 Da
• Monoisotopic Mass: 1090.73 Da
• Topological Polar Surface Area: 31.400 Ų
• Heavy Atom Count: 78
• Formal Charge: 0
• Complexity: 1460.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1