Sodium tetraphenylboron - ≥99.5% , CAS No.143-66-8

CAS: 143-66-8 Cat. No.: S112345 Peso molecular: 342.22 Beilstein Registry Number: 3599783 Número EC: 205-605-5 PubChem CID: 2723787

GRADE & PURITY ≥99.5%

Synonyms

Tetraphenylboron sodium

Storage

Protected from light,Room temperature,Cool

Shipped In

Normal

Descripción general

Application：

· Generates stable, crystalline N-acylammonium salts by ion exchange.[2] Couples with vinyl and aryl triflates to form arylalkenes and biaryls.
· Sodium tetraphenylborate can form hydrophobic salts with amines, ammonium ions, and large alkali metal ions such as cesium or rubidium ions. Hence it is commonly used in gravimetric analysis as a precipitating agent.

Specifications

Sinónimos

Tetraphenylboron sodium

Especificaciones y pureza

≥99.5%

Condiciones de almacenamiento de almacenamiento

Protected from light, Room temperature, Cool

Enviado en

Normal

Pureza

≥99.5%

Nombres e identificadores

• Pubchem Sid: 504760809
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504760809
• Sonrisas canónicas: [B-](C1=CC=CC=C1)(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[Na+]
• IUPAC Name: sodium;tetraphenylboranuide
• InChIKey: HFSRCEJMTLMDLI-UHFFFAOYSA-N
• INCHI: 1S/C24H20B.Na/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1
• Isómeros SMILES: [B-](C1=CC=CC=C1)(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[Na+]
• WGK Alemania: 3
• RTECS: ED3362500
• PubChem CID: 2723787
• Número ONU: 2811
• Peso molecular: 342.22
• Beilstein: 3599783

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Benzene and substituted derivatives
• Alternative Parents: Organic metalloid salts Organoboron compounds Organic sodium salts Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Monocyclic benzene moiety - Organic alkali metal salt - Organic metalloid salt - Hydrocarbon derivative - Organic sodium salt - Organic salt - Organoboron compound - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as benzene and substituted derivatives. These are aromatic compounds containing one monocyclic ring system consisting of benzene.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Soluble in water and ethanol.
• Sensibilidad: Light sensitive.
• Punto de fusión (°C): >300°C
• Peso molecular: 342.200 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 342.156 Da
• Monoisotopic Mass: 342.156 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 26
• Formal Charge: 0
• Complexity: 308.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

1. Ji Wenhui, Liu Huanzhuan, Liu Yadong, Zhang Wei, Zhou Tong, Liu Xinxin, Tao Chao, Dai Jiangxuan, Zha Baoli, Xie Ruijie, Wu Jiansheng, Wu Qiong, Zhang Weina, Li Lin, Huo Fengwei.  (2023)  Large-scale fully printed “Lego Bricks” type wearable sweat sensor for physical activity monitoring.  npj Flexible Electronics,  7  (1): (1-12).  [PMID:] [10.1038/s41528-023-00285-w]

2. Hang Tian, Lichao Wang, Weifeng Yang, Kerui Li, Qinghong Zhang, Yaogang Li, Hongzhi Wang, Chengyi Hou.  (2023)  Hierarchical Fermat Helix-structured Electrochemical Sensing Fibers Enable Sweat Capture and Multi-biomarker Monitoring.  Materials Horizons,      [PMID:37725333] [10.1039/D3MH00989K]

3. Zijian An, QiQi Fu, Jingjiang Lv, Tao Zhou, Yue Wu, Yanli Lu, Guang Liu, Zhenghan Shi, Xin li, Fenni Zhang, Qingjun Liu.  (2023)  Body Heat Powered Wirelessly Wearable System for Real-time Physiological and Biochemical Monitoring.  ADVANCED FUNCTIONAL MATERIALS,  33  (34): (2303361).  [PMID:] [10.1002/adfm.202303361]

4. Manman Zhao, Mingqiang Chen, Yakun Zong, Zhanxiong Li.  (2022)  Modification of fabric via co-grafted with fluorine-free carbene polymer and its hydrophobicity.  POLYMER,      [PMID:] [10.1016/j.polymer.2022.124802]

5. Junxing Hao, Zeqiang Zhu, Chengguo Hu, Zhihong Liu.  (2022)  Photosensitive-Stamp-Inspired Scalable Fabrication Strategy of Wearable Sensing Arrays for Noninvasive Real-Time Sweat Analysis.  ANALYTICAL CHEMISTRY,      [PMID:35238536] [10.1021/acs.analchem.2c00593]

6. Huimin Duan, Lijie Yin, Tao Chen, Dongming Qi, Dongyue Zhang.  (2022)  A “metal ions-induced poisoning behavior of biomolecules” inspired polymeric probe for Cu2+ selective detection on basis of coil to helix conformation transition.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2022.111070]

7. Shuzhen Dou, Zhongshun Wang, Qiye Chen, Nan Lu.  (2022)  One-step fabrication of high-density Si nanotips as SALDI-MS substrate for highly sensitive detection.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2022.131578]

8. Peng Wei, Xiaogang Li, Zhimin He, Xueping Sun, Qirui Liang, Zhengying Wang, Chun Fang, Qing Li, Hui Yang, Jiantao Han, Yunhui Huang.  (2021)  Porous N, B co-doped carbon nanotubes as efficient metal-free electrocatalysts for ORR and Zn-air batteries.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2021.130134]

9. Liu Mingyang, Du Xuejun, Xu Ke, Yan Binwei, Fan Zaibi, Gao Zideng, Ren Xueqin.  (2021)  A cationic quantum dot-based ratiometric fluorescent probe to visually detect berberine hydrochloride in human blood serums.  Journal of Analytical Science and Technology,  12  (1): (1-9).  [PMID:] [10.1186/s40543-021-00261-x]

10. Chuanmin Ding, Zhiting Gao, Junwen Wang, Lichao Ma, Ju Shangguan, Qinbo Yuan, Ming Zhao, Kan Zhang.  (2020)  The coralline cobalt oxides compound of multiple valence states deriving from flower-like layered double hydroxide for efficient hydrogen generation from hydrolysis of NaBH4.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2020.10.141]

11. Lin Xinzhang, Cong Hengjiang, Sun Keju, Fu Xuemei, Kang Wanchao, Wang Xiuli, Jin Shengye, Wu Ren’an, Liu Chao, Huang Jiahui.  (2020)  One-step rapid synthesis, crystal structure and 3.3 microseconds long excited-state lifetime of Pd1Ag28 nanocluster.  Nano Research,  13  (2): (366-372).  [PMID:] [10.1007/s12274-020-2615-1]

12. Yue Zhang, Yifeng E, Yi Wang, Donghui Li, Yuting Liu.  (2019)  Preparation of graphene oxide and its application for improving the properties of an electrochemical sensor for the determination of bambuterol hydrochloride in real samples.  Analytical Methods,  12  (3): (288-296).  [PMID:] [10.1039/C9AY02286D]

13. Liu Yuting, Zhang Jing, Li Donghui.  (2019)  Preparation of cadmium sulfide nanoparticles and their application for improving the properties of the electrochemical sensor for the determination of enrofloxacin in real samples.  CHIRALITY,  31  (3): (174-184).  [PMID:30653718] [10.1002/chir.23045]

14. Chen Fan, Jiale Yang, You Liang, Hongqiang Dong, Wenbing Zhang, Gang Tang, Yongsong Cao.  (2018)  Effective tuning guanidinium ionic liquid as greener solvent for fast and sensitive determination of auxin herbicides.  MICROCHEMICAL JOURNAL,      [PMID:] [10.1016/j.microc.2018.08.054]

15. Yunxue Gao, Shuni Li, Quanguo Zhai, Yucheng Jiang, Mancheng Hu.  (2017)  Phase Diagrams and Physicochemical Properties for the Ternary System (CsCl + NaCl + H2O) at T = (298.15, 308.15, and 318.15) K.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/acs.jced.7b00023]

16. Yunxue Gao, Shuni Li, Quanguo Zhai, Yucheng Jiang, Mancheng Hu.  (2016)  Stable (solid + liquid) phase equilibrium for the ternary system (NaCl + RbCl + H2O) at T = (288.15, 298.15 and 308.15) K.  JOURNAL OF CHEMICAL THERMODYNAMICS,      [PMID:] [10.1016/j.jct.2016.12.007]

17. Yao Lin, Yuan Yang, Yuxuan Li, Lu Yang, Xiandeng Hou, Xinbin Feng, Chengbin Zheng.  (2016)  Ultrasensitive Speciation Analysis of Mercury in Rice by Headspace Solid Phase Microextraction Using Porous Carbons and Gas Chromatography-Dielectric Barrier Discharge Optical Emission Spectrometry.  ENVIRONMENTAL SCIENCE & TECHNOLOGY,      [PMID:26828416] [10.1021/acs.est.5b04328]

18. Ma Xueli, Wang Chunfeng, Ren Hao, Chen Yujuan, Zhuo Kelei.  (2015)  Response of a new multi-walled carbon nanotubes modified carbon paste electrode to 1-hexyl-3-methylimidazolium cation in aqueous solution.  IONICS,  21  (9): (2503-2510).  [PMID:] [10.1007/s11581-015-1413-3]

19. Kelei Zhuo, Hao Ren, Yujing Wei, Yujuan Chen, Jingjing Ma.  (2014)  Activity Coefficients of [Cnmim]Br (n = 3 to 8) Ionic Liquids in Aqueous Fructose Solution at T = 298.15 K.  JOURNAL OF CHEMICAL AND ENGINEERING DATA,      [PMID:] [10.1021/je4005195]

20. Minghui He, Xun Huang, Yugang Huang, Zhaohua Zeng, Jianwen Yang.  (2012)  Photoinduced redox initiation for fast polymerization of acrylaytes based on latent superbase and peroxides.  POLYMER,      [PMID:] [10.1016/j.polymer.2012.05.031]

21. Xuyi Li, Chen Huang, Rui Xue, Jia-Ping Tong, Yuehan Cheng, Bao-Li An, Jiaqiang Xu, Yue-Ling Bai.  (2024)  A Viologen Derivative Transition from Photosilence to Sensitive Photochromism through Ion Exchange.  CRYSTAL GROWTH & DESIGN,      [PMID:] [10.1021/acs.cgd.4c00192]

22. Xiaoqing Yang, Jinshan Zhao, JunFeng Zeng, Bihua Chen, Liang Tang, Jun Zhang, Akif Zeb, Zhiyong Li, Shiguo Zhang, Yan Zhang.  (2025)  Design of halogen-free hyper-crosslinked porous ionic polymers for efficient CO2 capture and conversion.  GREEN CHEMISTRY,      [PMID:] [10.1039/D4GC05351F]

23. Yan Zhang, Yining Sun, Jingxuan Han, Ming Zhang, Fangjie Li, Dongye Yang.  (2025)  High-sensitivity flexible electrochemical sensor for real-time multi-analyte sweat analysis.  TALANTA,      [PMID:39879800] [10.1016/j.talanta.2025.127644]

24. Yuanzhen Wang, Yiding Jiao, Jiacheng Wang, Hanting Zhang, Tingting Ye, Jiang Lu, Er He, Luhe Li, Jie Song, Chenyu Bai, Xusong Li, Yiran Li, Fangyan Li, Fengqi Li, Jingrui Jian, Shuo Yang, Xinxin Hou, Qianming Li, Shupeng Zhao, Ruiyang Tan, Ye Zhang.  (2025)  Metalgel Fiber with Excellent Electrical and Mechanical Properties.  ACS Applied Materials & Interfaces,      [PMID:39854174] [10.1021/acsami.4c19418]

25. Ziyi Mi, Youyuan Xia, Huo Dong, Yuhang Shen, Ziyou Feng, Yawen Hong, Haoyu Zhu, Binfeng Yin, Zhengping Ji, Qin Xu, Xiaoya Hu, Yun Shu.  (2024)  Microfluidic Wearable Electrochemical Sensor Based on MOF-Derived Hexagonal Rod-Shaped Porous Carbon for Sweat Metabolite and Electrolyte Analysis.  ANALYTICAL CHEMISTRY,      [PMID:39392225] [10.1021/acs.analchem.4c02950]

26. Jie Fu, Jiawang Wang, Yihong Ding, Shouzhe Deng, Cherie S. Tan, Shuang Li.  (2025)  Wearable physicochemical-sensing system integrated with diaper for pheochromocytoma monitoring.  SENSORS AND ACTUATORS B-CHEMICAL,      [PMID:] [10.1016/j.snb.2025.137520]

27. Jie Fu, Yanwen Wang, Yihong Ding, Jiawang Wang, Shouzhe Deng, Zhuoya Jiang, Cherie S. Tan, Shuang Li.  (2025)  Wearable ring sensor for monitoring biomarkers of atherosclerosis in sweat.  TALANTA,      [PMID:39827480] [10.1016/j.talanta.2025.127608]

28. Yizhu Liu, Yexi Jin, Detao Yuan, Hao Shen, Yu Lu, Guangyao Chen, Liwei Xue, Tuo Zhang, Zongheng Shi, Jing Zhang, Liguo Chen.  (2025)  A wearable sweat detection system with biomimetic steady-flow microfluidic structure for multi-biomarker analysis.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.167915]

29. Mingpeng Yang, Nan Sun, Xiaochen Lai, Yanjie Li, Xingqiang Zhao, Jiamin Wu, Wangping Zhou.  (2023)  Screen-Printed Wearable Sweat Sensor for Cost-Effective Assessment of Human Hydration Status through Potassium and Sodium Ion Detection.  Micromachines,  14  (8): (1497).  [PMID:37630034] [10.3390/mi14081497]

30. Ying Qin, Jilong Mo, Yanhua Liu, Song Zhang, Jinlong Wang, Qiu Fu, Shuangfei Wang, Shuangxi Nie.  (2022)  Stretchable Triboelectric Self-Powered Sweat Sensor Fabricated from Self-Healing Nanocellulose Hydrogels.  ADVANCED FUNCTIONAL MATERIALS,  32  (27): (2201846).  [PMID:] [10.1002/adfm.202201846]

31. Yanqin Song, Muhammad Ismail, Qi Shan, Jianing Zhao, Yanping Zhu, Leiming Zhang, Yuan Du, Longbing Ling.  (2021)  ROS-mediated liposomal dexamethasone: a new FA-targeted nanoformulation to combat rheumatoid arthritis via inhibiting iRhom2/TNF-α/BAFF pathways.  Nanoscale,  13  (47): (20170-20185).  [PMID:34846489] [10.1039/D1NR05518F]

32. Zhe Xing, Qiang Liu, Bo Lin, Shuang Li, Yuxin Liu, Guanyang Zhang, Wenjie Yu, Zhenhua Wu, Hongju Mao.  (2025)  A multi-channel wearable sensing patch based on gate-all-around field-effect transistors.  LAB ON A CHIP,      [PMID:40433808] [10.1039/D5LC00162E]

33. Huimin Wang, Guangxin Wang, Ruoxi Liu, Jin Yong Lee, Shufeng Liu, Yingqi Tang, Jing Yu.  (2025)  Electrochemiluminescent Enantiodiscrimination on Chiral Engineered l-His-ZIF8.  LANGMUIR,      [PMID:41217085] [10.1021/acs.langmuir.5c03908]

34. Wenyu Shen, Yang Li, Shaoyang Gao, Yuhe Tian, Ziyun Zhang, Junbo Xu, Duo Wang, Chao Yang.  (2025)  Mechanism of abnormal Mg2+ extraction in sodium tetraphenylborate - tributyl phosphate system for Li+/Mg2+ separation.  AICHE JOURNAL,      [PMID:] [10.1002/aic.70124]

35. Qian Cheng, Yue Wang, Yongxiang Wang, Panfeng Gao, Jun-Tao Li, Jiangxue Long, Haiyan Fu.  (2026)  Preferentially selective lithium recovery from spent lithium-ion battery leachates using NaBPh4/TBP synergistic extraction.  HYDROMETALLURGY,      [PMID:] [10.1016/j.hydromet.2026.106753]