Sodium trimethylsilanolate - ≥95% , CAS No.18027-10-6

CAS: 18027-10-6 Cat. No.: S467157 Peso molecular: 112.18 Número EC: 241-939-8 PubChem CID: 23672319

GRADE & PURITY ≥95%

Synonyms

MFCD00013926 | SCHEMBL380132 | Trimethylsilanol sodium salt | Silanol, 1,1,1-trimethyl-, sodium salt (1:1) | AKOS015909317 | Sodium trimethylsilanolate, 95% | trimethylsilyloxy sodium | sodium trimethylsilanolat | FT-0637638 | NaOTMS | s15125 | SODIUMTRIM

Storage

Room temperature,Argon charged

Shipped In

Normal

Descripción general

Sodium trimethylsilanolate is a versatile and very powerful reagent for the conversion of esters to carboxylic acids and the hydrolysis of nitriles to primary amides. It can be used as a starting material for the synthesis of metal silanolates via the salt metathesis and as a catalyst for the silylation of silanols with hydrosilanes.

Application：

Sodium trimethylsilanolate is used as a catalyst in the:
Synthesis of the rhodium silonate complex.
Silylation of methylphenylsilane with tert-butyldimethylsilanol to synthesize trisiloxanes.  

Specifications

Sinónimos

MFCD00013926 | SCHEMBL380132 | Trimethylsilanol sodium salt | Silanol, 1, 1, 1-trimethyl-, sodium salt (1:1) | AKOS015909317 | Sodium trimethylsilanolate, 95% | trimethylsilyloxy sodium | sodium trimethylsilanolat | FT-0637638 | NaOTMS | s15125 | SODIUMTRIM

Especificaciones y pureza

≥95%

Condiciones de almacenamiento de almacenamiento

Room temperature, Argon charged

Enviado en

Normal

Pureza

≥95%

Nombres e identificadores

• Sonrisas canónicas: C[Si](C)(C)[O-].[Na+]
• IUPAC Name: sodium;trimethyl(oxido)silane
• InChIKey: HSNUIYJWTSJUMS-UHFFFAOYSA-N
• INCHI: 1S/C3H9OSi.Na/c1-5(2,3)4;/h1-3H3;/q-1;+1
• Isómeros SMILES: C[Si](C)(C)[O-].[Na+]
• WGK Alemania: 3
• PubChem CID: 23672319
• Peso molecular: 112.18

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Clase Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Clase: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes
• Direct Parent: Trialkylheterosilanes
• Alternative Parents: Organic metalloid salts Organic zwitterions Organic sodium salts Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylheterosilane - Organic alkali metal salt - Organic metalloid salt - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organic sodium salt - Organic salt - Organic zwitterion - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Moisture sensitive
• Punto de inflamación (°F): 230.0 °F
• Punto de inflamación (°C): 110 °C
• Punto de fusión (°C): 230 °C
• Peso molecular: 112.180 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 112.032 Da
• Monoisotopic Mass: 112.032 Da
• Topological Polar Surface Area: 23.100 Ų
• Heavy Atom Count: 6
• Formal Charge: 0
• Complexity: 32.299
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

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