Tebbe reagent solution - 0.5M in toluene , CAS No.67719-69-1

CAS: 67719-69-1 Cat. No.: T466030 Peso molecular: 284.58 Número EC: 628-935-5

GRADE & PURITY 0.5M in toluene

Synonyms

Bis(cyclopentadienyl)-μ-chloro­(dimethylaluminum)-μ-methylenetitanium

Storage

Room temperature

Descripción general

Tebbe reagent is a Lewis acid stabilized organometallic compound, which is used to transform carbonyl groups into β-substituted methylenes. It also reacts with a wide range of carbonyl compounds, including esters, amides, and lactones to yield corresponding olefins.Tebbe reagent can be used:For the conversion of carbonyl groups of chlorophyll derivatives into the corresponding exo-methylene (or vinylidene) groups.In the synthesis of β-C-glycosides from 3-OH glycol esters.As a versatile methylenation reagent for the conversion of ketones and aldehydes to olefins. It offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers.To olefinate aldehydes.To methylenate a chiral polyhydroxyketone with high diasteroselctivity.

Specifications

Sinónimos

Bis(cyclopentadienyl)-μ-chloro­(dimethylaluminum)-μ-methylenetitanium

Especificaciones y pureza

0.5M in toluene

Condiciones de almacenamiento de almacenamiento

Room temperature

Nombres e identificadores

• Sonrisas canónicas: [CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.C[Al](C)C[Ti]Cl
• InChIKey: QEJAQNUJXFLWSP-UHFFFAOYSA-M
• INCHI: 1S/2C5H5.2CH3.CH2.Al.ClH.Ti/c2*1-2-4-5-3-1;;;;;;/h2*1-5H;2*1H3;1H2;;1H;/q;;;;;;;+1/p-1
• Número ONU: 2924
• Peso molecular: 284.58

Propiedades químicas y físicas

• Punto de inflamación (°F): 39.2 °F - closed cup
• Punto de inflamación (°C): 4 °C - closed cup