tert-Butyllithium solution - 1.7 M in pentane , CAS No.594-19-4

CAS: 594-19-4 Cat. No.: T433023 Peso molecular: 64.06 Beilstein Registry Number: 3587204 Número EC: 209-831-5

GRADE & PURITY 1.7 M in pentane

Synonyms

tertbutyllithium | tert-Butyllithium | t-Butyllitium | ter-Butyllithium | t-butyllithiurn | tBuLi | t-BuLi | t-butyllithium | t-butyl-lithium | tert-butyllitium | t-butyllithum | t-butyl | Tert butyllithium | lithium | 2-methylpropane

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice,FedEx DG Service

Descripción general

tert -Butyllithium solution ( tert -BuLi) is an organolithium compound, used as a strong base in organic chemistry. It facilitates lithium-halogen exchange reaction and also can be employed in the deprotonation of C-H compounds and amines.

Application

tert -Butyllithium solution can be used as a strong base in the synthesis of: Alkyllithium derivatives form alkyl iodides and diiodoalkanes by halogen-lithium exchange reaction. Inorganic polymer [(LiMo 3 Se 3 )n] from [(InMo 3 Se 3 )n] by reductive intercalation method. Adducts of cinnamic acid (1,3- and 1,4-adducts) by reacting with C-C double of cinnamic acid.

Specifications

Sinónimos

tertbutyllithium | tert-Butyllithium | t-Butyllitium | ter-Butyllithium | t-butyllithiurn | tBuLi | t-BuLi | t-butyllithium | t-butyl-lithium | tert-butyllitium | t-butyllithum | t-butyl | Tert butyllithium | lithium | 2-methylpropane

Especificaciones y pureza

1.7 M in pentane

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice, FedEx DG Service

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Nombres e identificadores

• Sonrisas canónicas: [Li+].C[C-](C)C
• IUPAC Name: lithium;2-methylpropane
• InChIKey: UBJFKNSINUCEAL-UHFFFAOYSA-N
• INCHI: 1S/C4H9.Li/c1-4(2)3;/h1-3H3;/q-1;+1
• Isómeros SMILES: [Li+].C[C-](C)C
• WGK Alemania: 2
• Peso molecular: 64.06
• Beilstein: 3587204
• Reaxy-Rn: 3587204
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3587204&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic salts
    • Clase Organic metal salts
      • Subclass Organic alkali metal salts

• Kingdom: Organic compounds
• Superclass: Organic salts
• Clase: Organic metal salts
• Subclass: Organic alkali metal salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic lithium salts
• Alternative Parents: Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic lithium salt - Hydrocarbon derivative - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as organic lithium salts. These are organic compounds containing a lithium ion.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: CO2 sensitive；Moisture sensitive
• Peso molecular: 64.099 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 64.0864 Da
• Monoisotopic Mass: 64.0864 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 8.400
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

1. Haoyun Deng, Zhixiong Yang, Mengzhen Zhou, Encai Ou, Yanbing Lu, Qiulan Zhou, Kun Liu, Weijian Xu.  (2024)  Anionic polymerization of (Z)-1,3-pentadiene using Ba/Al/Li trimetallic initiators to synthesize crystalline high trans-1,4-polypentadiene.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.127841]

2. Ning Yan, Lei Ding, Tong Wu, Sihang Zhang, Feng Yang, Ya Cao, Ming Xiang.  (2021)  Shutdown-Functionalized Poly Ethylene-Vinyl Alcohol Sulfonate Lithium and Poly (Vinyl Alcohol) Composite Lithium-Ion Battery Separator.  JOURNAL OF THE ELECTROCHEMICAL SOCIETY,  168  (11): (110510).  [PMID:] [10.1149/1945-7111/ac330c]