Tetrahydrofuran-d8 - ≥99.5 atom% D , CAS No.1693-74-9

CAS: 1693-74-9 Cat. No.: T102271 Peso molecular: 80.16 Beilstein Registry Number: 111854 Número EC: 216-898-4 PubChem CID: 80290

GRADE & PURITY ≥99.5 atom% D

Synonyms

Deuterated tetrahydrofuran

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

Tetrahydrofuran-d8 (THF-d8), a deuterated derivative of tetrahydrofuran, is a standard purity solvent suitable for routine NMR analyses (conducted at ambient temperatures where quality is less critical). It participates as a solvent in an intermolecular proton exchange reaction between methanol and acetic acid. Kinetics of this reaction has been studied by ′H NMR line shape analysis. Infrared spectral studies of THF and THF-d8 have been investigated in the range of 10 and 300cm-1.

Specifications

Sinónimos

Deuterated tetrahydrofuran

Especificaciones y pureza

≥99.5 atom% D

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

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Pureza

≥99.5 atom% D

Nombres e identificadores

• Sonrisas canónicas: [2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]
• IUPAC Name: 2,2,3,3,4,4,5,5-octadeuteriooxolane
• InChIKey: WYURNTSHIVDZCO-SVYQBANQSA-N
• INCHI: 1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2
• Isómeros SMILES: [2H]C1(C(C(OC1([2H])[2H])([2H])[2H])([2H])[2H])[2H]
• WGK Alemania: 1
• CAS alternativo: 109-99-9
• PubChem CID: 80290
• Número ONU: 2056
• Peso molecular: 80.16
• Beilstein: 111854

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Clase Tetrahydrofurans

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Clase: Tetrahydrofurans
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Tetrahydrofurans
• Alternative Parents: Oxacyclic compounds Dialkyl ethers Hydrocarbon derivatives
• Molecular Framework: Aliphatic heteromonocyclic compounds
• Substituents: Tetrahydrofuran - Oxacycle - Ether - Dialkyl ether - Organic oxygen compound - Hydrocarbon derivative - Organooxygen compound - Aliphatic heteromonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as tetrahydrofurans. These are heterocyclic compounds containing a saturated, aliphatic, five-membered ring where a carbon is replaced by an oxygen.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Miscible with water.
• Sensibilidad: Moisture sensitive.
• Índice de refracción: 1.403
• Punto de inflamación (°F): 0.5 °F
• Punto de inflamación (°C): -17°C
• Punto de ebullición (°C): 65-66°C
• Punto de fusión (°C): -106°C
• Peso molecular: 80.150 g/mol
• XLogP3: 0.500
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 80.1077 Da
• Monoisotopic Mass: 80.1077 Da
• Topological Polar Surface Area: 9.200 Ų
• Heavy Atom Count: 5
• Formal Charge: 0
• Complexity: 22.800
• Isotope Atom Count: 8
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Zhang Zhe, Peng Haoran, Yang Dongchen, Zhang Guoqing, Zhang Jinlin, Ju Feng.  (2022)  Polyvinyl chloride degradation by a bacterium isolated from the gut of insect larvae.  Nature Communications,  13  (1): (1-14).  [PMID:36097154] [10.1038/s41467-022-32903-y]

2. Kang Chen, Liuzhang Ouyang, Hao Zhong, Jiangwen Liu, Hui Wang, Huaiyu Shao, Yao Zhang, Min Zhu.  (2019)  Converting H+ from coordinated water into H− enables super facile synthesis of LiBH4.  GREEN CHEMISTRY,  21  (16): (4380-4387).  [PMID:] [10.1039/C9GC01897B]

3. Peng Zhao, Xiaojing Cui, Chizhou Wang, Xiaojie Shao, Hongyan Li, Ning Zhang, Xianglin Hou, Tiansheng Deng.  (2024)  Amphiphilic molecules affording efficient aqueous degradation of unsaturated polyester resin.  POLYMER DEGRADATION AND STABILITY,      [PMID:] [10.1016/j.polymdegradstab.2024.110774]

4. Zhicheng Zhu, Chongming Liu, Rui Li, Kaibo Pan, Da Yue, Yutong Zhou, Kai Zhang, Bai Yang.  (2024)  High Refractive Index Carbonized Polymer Dots Acting as Light Scattering Units in Nanocomposites for Full-Screen Light Guide Plate.  ADVANCED FUNCTIONAL MATERIALS,      [PMID:] [10.1002/adfm.202312774]

5. Fang Liu, Yuan-yuan Lin, Chuan-jia Jiao, Zhao-hua Xu, Dong-hua Xu, Shi-fang Luan.  (2024)  Shear thickening behaviour of polyborosiloxane.  POLYMER,      [PMID:] [10.1016/j.polymer.2024.127377]

6. Wan Ting Dai, Zhen Hua Xie, Yu Bin Ke, Yang You, Ze Ping Zhang, Min Zhi Rong, Ming Qiu Zhang.  (2025)  Microstructural Convergence of Subnetworks in Reversibly Interlocked Polymer Networks Revealed by Small-Angle Neutron Scattering.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.5c00413]

7. Nianyue Zhang, Shuilong Kang, Meng Zhang, Sifan You, Xiang Hu, Guangyuan Feng, Kunal S. Mali, Steven De Feyter, Oleksandr Ivasenko, Lifeng Chi, Yuan Fang.  (2025)  Toward Unified Mechanism of Bias-Dependent Switching in Reactive Self-Assembly Systems.  ACS Nano,      [PMID:40607774] [10.1021/acsnano.5c03607]