Tetramethylammonium chloride(TMACI) - ≥98%(T) , CAS No.75-57-0

CAS: 75-57-0 Cat. No.: T110540 Peso molecular: 109.6 Beilstein Registry Number: 3911201 Número EC: 200-880-8

GRADE & PURITY ≥98%(T)

Synonyms

AKOS015833138 | BCP24457 | EINECS 200-880-8 | SCHEMBL35736 | USAF AN-8 | AI3-19012 | Amberlite(R) IRA-900 chloride form, chloride form, strongly basic, 20-50 mesh | EN300-219151 | AMBERLITE IRA-900 | HSDB 7987 | FT-0659748 | STR05669 | CAS-75-57-0 | DTXCI

Storage

Argon charged,Desiccated,Room temperature

Shipped In

Normal

Descripción general

Tetramethylammonium chloride (TMAC) is structurally similar to alkyltrimethylammonium salts. Oxidation of TMAC yields formaldehyde and trimethlamine. It is considered as poor phase-transfer catalyst for most reactions as it is insoluble in organic media. However, it is highly suitable as phase-transfer catalyst for fluorination of chlorobenzaldehydes along with alkali metal fluorides which yield 1,2,2,2-tetrafluoroethyldifluoromethyl ether.
Tetramethylammonium chloride along with N-hydroxyphthalimide and xanthone may be used as an efficient chloride catalytic system for the aerobic oxidation of hydrocarbons to form the corresponding oxygenated compounds. It may also be used as a phase transfer catalyst for the synthesis of aryl fluorides via selective chloride/fluoride exchange reaction of activated aryl chlorides with potassium fluoride in solid-liquid phase.

Specifications

Sinónimos

AKOS015833138 | BCP24457 | EINECS 200-880-8 | SCHEMBL35736 | USAF AN-8 | AI3-19012 | Amberlite(R) IRA-900 chloride form, chloride form, strongly basic, 20-50 mesh | EN300-219151 | AMBERLITE IRA-900 | HSDB 7987 | FT-0659748 | STR05669 | CAS-75-57-0 | DTXCI

Especificaciones y pureza

≥98%(T)

Condiciones de almacenamiento de almacenamiento

Argon charged, Desiccated, Room temperature

Enviado en

Normal

Pureza

≥98%(T)

Nombres e identificadores

• Pubchem Sid: 504751078
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504751078
• Sonrisas canónicas: C[N+](C)(C)C.[Cl-]
• IUPAC Name: tetramethylazanium;chloride
• InChIKey: OKIZCWYLBDKLSU-UHFFFAOYSA-M
• INCHI: 1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
• Isómeros SMILES: C[N+](C)(C)C.[Cl-]
• WGK Alemania: 1
• Peso molecular: 109.6
• Beilstein: 3911201
• Reaxy-Rn: 3911201
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3911201&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic nitrogen compounds
    • Clase Organonitrogen compounds
      • Subclass Quaternary ammonium salts

• Kingdom: Organic compounds
• Superclass: Organic nitrogen compounds
• Clase: Organonitrogen compounds
• Subclass: Quaternary ammonium salts
• Intermediate Tree Nodes: Not available
• Direct Parent: Tetraalkylammonium salts
• Alternative Parents: Organopnictogen compounds Organic chloride salts Hydrocarbon derivatives Amines
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Tetraalkylammonium salt - Organopnictogen compound - Hydrocarbon derivative - Organic chloride salt - Organic salt - Amine - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as tetraalkylammonium salts. These are organonitrogen compounds containing a quaternary ammonium substituted with four alkyl chains.
• External Descriptors: organic molecular entity

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Objetivos asociados (humanos)

SLC22A1 Tchem Solute carrier family 22 member 1 (646 Activities)

Discover Target: SLC22A1

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

SLC22A2 Tchem Solute carrier family 22 member 2 (261 Activities)

Discover Target: SLC22A2

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Objetivos asociados (no humanos)

Slc5a7 Choline transporter (45 Activities)

Discover Target: Slc5a7

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Slc22a5 Solute carrier family 22 member 5 (44 Activities)

Discover Target: Slc22a5

Activity Type	Relation	Activity value	Units	Action Type	Journal	PubMed Id	doi	Assay Aladdin ID

Mecanismos de acción

Propiedades químicas y físicas

• Solubilidad: Soluble in water. Insoluble in ether, and benzene
• Sensibilidad: Hygroscopic
• Punto de fusión (°C): > 300 °C
• Peso molecular: 109.600 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 109.066 Da
• Monoisotopic Mass: 109.066 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 6
• Formal Charge: 0
• Complexity: 19.100
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3

Referencias

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