Tin(II) bromide - ≥99% , CAS No.10031-24-0

CAS: 10031-24-0 Cat. No.: T302028 Peso molecular: 278.52 Número EC: 233-087-0 PubChem CID: 66224

GRADE & PURITY ≥99%

Synonyms

Stannous bromide | Stannous dibromide | Tin(2+) dibromide

Storage

Protected from light,Room temperature,Argon charged

Shipped In

Normal

Descripción general

Stannous bromide acts a lewis acid. It is used to prepare alkyl tin compounds and in the spectrophotometric determination of iridium. It is involved in regioselective mono-etherfications of vicinal diols with diazo compounds. It acts as a catalyst to produce resinous lactone high polymers. It serves as a potent reducing agent.

Specifications

Sinónimos

Stannous bromide | Stannous dibromide | Tin(2+) dibromide

Especificaciones y pureza

≥99%

Condiciones de almacenamiento de almacenamiento

Protected from light, Room temperature, Argon charged

Enviado en

Normal

Pureza

≥99%

Nombres e identificadores

• Pubchem Sid: 504754049
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504754049
• Isómeros SMILES: Br[Sn]Br
• PubChem CID: 66224
• Peso molecular: 278.52

Propiedades químicas y físicas

• Solubilidad: Soluble in alcohol, ether, acetone, pyridine and dimethyl sulfoxide
• Sensibilidad: Moisture, air and light sensitive
• Punto de ebullición (°C): 623°C
• Punto de fusión (°C): 215°C
• Peso molecular: 278.520 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 279.737 Da
• Monoisotopic Mass: 277.739 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 3
• Formal Charge: 0
• Complexity: 2.800
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

Referencias

1. Zhenheng Zhang, Shengyi Yang, Muhammad Sulaman, Zhenhua Ge, Jinming Hu, Hui Peng, Libin Tang, Bingsuo Zou, Yurong Jiang.  (2023)  High-stability lead-free tin(II)-perovskites by A-site cation engineering and surface-passivating engineering for high-performance hybrid bulk-heterojunction photodetectors.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2023.170867]

2. Xiao-Bao Li, Chun-Li Hu, Fang Kong, Jiang-Gao Mao.  (2023)  Structure and optical property evolution in PbM(PO4)X (M = Zn, Sn; X = halogen): SHG effect and birefringence.  Inorganic Chemistry Frontiers,  10  (8): (2268-2275).  [PMID:] [10.1039/D3QI00230F]

3. Minjie Zhang, Yanming Lin, Jiayi Li, Xinru Wei, Ying Peng, Zhengkun Wang, Zhenyi Jiang.  (2022)  Interfacial Electronic and Photovoltaic Performance of a Novel Lead-Free Z-Scheme CsSnBr3/MoSe2 Perovskite Heterostructure: A Theoretical and Experimental Study.  Solar RRL,  7  (3): (2200784).  [PMID:] [10.1002/solr.202200784]

4. Dayu Huang, Qiuyun Ouyang, Jinjiang Wu, Youchao Kong, Bo Wang, Hongzhou Lian, Jun Lin.  (2022)  Growth of SnX2 (X = Br, I) Single Crystals with Self-Trapped Exciton Emission.  INORGANIC CHEMISTRY,      [PMID:36337039] [10.1021/acs.inorgchem.2c03058]

5. Binbin Su, Gaomin Song, Maxim S. Molokeev, Zheshuai Lin, Zhiguo Xia.  (2020)  Synthesis, Crystal Structure and Green Luminescence in Zero-Dimensional Tin Halide (C8H14N2)2SnBr6.  INORGANIC CHEMISTRY,      [PMID:32628841] [10.1021/acs.inorgchem.0c01103]

6. Zhenheng Zhang, Shengyi Yang, Zhenhua Ge, Haiyuan Xin, Ying Wang, Yurong Jiang, Bingsuo Zou.  (2024)  Self-Driven Photodetectors Based on Flexible Silicon Nanowires Array Surface-Passivated With Tin-Based Perovskites.  IEEE SENSORS JOURNAL,  24  (14): (21792-21799).  [PMID:] [10.1109/JSEN.2024.3401682]

7. Ruonan Yao, Jiawei Lin, Kunjie Liu, Yuanchang Xu, Boyi Xiao, Jing Zhao, Zhongnan Guo, Quanlin Liu, Wenxia Yuan.  (2024)  Structure and Optical Properties of Sn-Based Halide Perovskites (C10H18N2)SnX4 (X = Cl, Br, I).  ACS Omega,      [PMID:38799330] [10.1021/acsomega.4c01835]

8. Zhipeng Lv, Huiping Gao, Yayong Hu, Yunpeng Fan, Gencai Pan, Huafang Zhang, Wenwu You, Zhenlong Zhang, Yanli Mao.  (2024)  Ultraviolet–Visible-Near-Infrared Broadband Photodetector Enabled by Cs2AgBiBr6: Sn/Conjugated Polymer Heterojunction.  ACS Applied Materials & Interfaces,      [PMID:39276066] [10.1021/acsami.4c09281]

9. Jing-Ning Lv, Jie Zhang, Yu-Meng Liu, Shao-Ya Zhang, Xiang-Yuan Deng, Man Xu, Xiao-Wu Lei, Zhi-Wei Chen, Cheng-Yang Yue.  (2024)  Zero-dimensional hybrid tin halides with stable broadband light emissions.  DALTON TRANSACTIONS,  53  (10): (4698-4704).  [PMID:38362640] [10.1039/D3DT03937D]

10. Zhao Yubin, Li Meng, Matras-Postolek Katarzyna, Yang Ping.  (2020)  Crystal structure and luminescence of Cs-Pb-Sn-Br nanocrystals.  JOURNAL OF NANOPARTICLE RESEARCH,  22  (9): (1-11).  [PMID:] [10.1007/s11051-020-05020-4]

11. Bin Yu, Songxue Bai, Zhenglin Jia, Haitao Tang, Yong Liu, Hailin Liu, Qianqian Lin.  (2024)  Flexible and Transparent Phosphonium-Based Metal Halide Glass Scintillators for High-Resolution X-ray Imaging.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.4c01334]

12. Haotian Gu, Tenglong Sun, Yining Feng, Muzhi Cai, Jintian Tang, Shiqing Xu.  (2025)  Impact of phospho-oxygen derivatives on crystallinity and optoelectronic properties of CsSnBr3 LED.  OPTICAL MATERIALS,      [PMID:] [10.1016/j.optmat.2025.116781]

13. Zewen Lin, Zhenxu Lin, Haixia Wu, Rui Huang, Jie Song, Kaitao Chen, Li Xia, Yi Zhang, Huihong Lin, Hongliang Li, Dejian Hou, Yanqing Guo, Paul K. Chu.  (2025)  Plasma-Enhanced Grain Growth and Non-Radiative Recombination Mitigation in CsSnBr3 Perovskite Films for High-Performance, Lead-Free Photodetectors.  Small,      [PMID:39757505] [10.1002/smll.202411086]

14. Yunfei Bai, Panwang Zhou, Xinyu Yang, Hongyuan Zhao, Ziying Wen, Qichao Meng, Haibo Sun, Chao Li, William W. Yu, Feng Liu.  (2025)  Emissive or Nonemissive? Molecular Insight into Luminescence Properties of Tin(II) Metal Halides.  ACS Applied Materials & Interfaces,      [PMID:40335458] [10.1021/acsami.5c05396]

15. Yifeng Xing, Jialin Yin, Yifei Qiao, Jie Zhao, Haiyang He, Danyang Zhao, Wanlu Zhang, Shiliang Mei, Ruiqian Guo.  (2025)  Gram-Scale Synthesis and Optical Properties of Self-Trapped-Exciton-Emitting Two-Dimensional Tin Halide Perovskites.  Nanomaterials,  15  (11): (818).  [PMID:40497866] [10.3390/nano15110818]

16. Xin An, Xiaoqi Guo, Shuhan Zhu, Bingbing Fan, Jinpeng Zhu, Gang Shao, Hongliang Xu, Hailong Wang, Hongxia Lu.  (2025)  High-entropy lead-free perovskite nanoparticles as efficient photocatalysis with a wide visible-light absorption band.  JOURNAL OF ALLOYS AND COMPOUNDS,      [PMID:] [10.1016/j.jallcom.2025.181680]

17. Zhaoyong Jiao, Zhiheng Shang, Minghuan Cui, Shuwen Zheng, Pan Song, Haiying Wang, Jicai Zhang, Jian Song, Shuhong Ma, Guangrui Jia, Zhongpo Zhou, Chaochao Qin.  (2025)  Ultrafast energy transfer between all-inorganic tin-based perovskite nanocrystals and RhB chromophore.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2025.121383]

18. Jiaxing Qi, Zixiao Qin, Yangchun Mo, Yani Xue, Xiaopeng Wei, Jilin Wang, Fei Long.  (2026)  Synthesis, structure, optoelectronic properties and stability of the lead-free tin-based organic-inorganic hybrid material.  POLYHEDRON,      [PMID:] [10.1016/j.poly.2026.118117]

19. Pubao Peng, Yang Geng, Jiajun Nan, Song Li, Dewei Zhang, Qing Lin, Yaru Gong, Guodong Tang.  (2026)  High Thermoelectric Performance Achieved by Manipulating the Band Structure and Lattice Dislocations in n-Type Ge/Pb/Br Codoped Polycrystalline SnSe.  Carbon Energy,      [PMID:] [10.1002/cey2.70217]