TPPS (=Tetraphenylporphyrin Tetrasulfonic Acid ) [Ultra-high sensitive spectrophotometric reagent for transition metals] - ≥85%(HPLC) , CAS No.35218-75-8

CAS: 35218-75-8 Cat. No.: T162693 Peso molecular: 934.98 Número EC: 634-857-2 PubChem CID: 135398549

GRADE & PURITY ≥85%(HPLC)

Synonyms

HY-W075353 | 4-[(1Z,4Z,9Z,15Z)-10,15,20-tris(4-sulfophenyl)-21,23-dihydroporphyrin-5-yl]benzenesulfonic acid | 4-(N-tert-butyloxycarbonylaminomethyl)piperidine | WR 247188 | AKOS005494142 | F0777-0572 | 4,4',4'',4'''-(21H,23H-Porphine-5,10,15,20-tetrayl)t

Storage

Room temperature

Shipped In

Normal

Descripción general

4,4′,4′′,4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonic acid) [tetrasodium salt hydrate, TPPS] has been used in preparing Co–Al LDH/Fe(III)-TPPS film modified electrode; for demonstrating reversible redox peak attribution to Co(III)/Co(II), with iron(III) porphyrin; making it mediator for electron transfer.

Specifications

Sinónimos

HY-W075353 | 4-[(1Z, 4Z, 9Z, 15Z)-10, 15, 20-tris(4-sulfophenyl)-21, 23-dihydroporphyrin-5-yl]benzenesulfonic acid | 4-(N-tert-butyloxycarbonylaminomethyl)piperidine | WR 247188 | AKOS005494142 | F0777-0572 | 4, 4', 4'', 4'''-(21H, 23H-Porphine-5, 10, 15, 20-tetrayl)t

Especificaciones y pureza

≥85%(HPLC)

Condiciones de almacenamiento de almacenamiento

Room temperature

Enviado en

Normal

Pureza

≥85%(HPLC)

Nombres e identificadores

• Pubchem Sid: 504773230
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504773230
• Sonrisas canónicas: C1=CC(=CC=C1C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC=C(C=C7)S(=O)(=O)O)C8=CC=C(C=C8)S(=O)(=O)O)C=C4)C9=CC=C(C=C9)S(=O)(=O)O)N3)S(=O)(=O)O
• IUPAC Name: 4-[10,15,20-tris(4-sulfophenyl)-21,23-dihydroporphyrin-5-yl]benzenesulfonic acid
• InChIKey: PBHVCRIXMXQXPD-UHFFFAOYSA-N
• INCHI: 1S/C44H30N4O12S4/c49-61(50,51)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)62(52,53)54)37-21-23-39(47-37)44(28-7-15-32(16-8-28)64(58,59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)63(55,56)57/h1-24,45,48H,(H,49,50,51)(H,52,53,54)(H,55,56,57)(H,58,59,60)
• Isómeros SMILES: C1=CC(=CC=C1C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC=C(C=C7)S(=O)(=O)O)C8=CC=C(C=C8)S(=O)(=O)O)C=C4)C9=CC=C(C=C9)S(=O)(=O)O)N3)S(=O)(=O)O
• RTECS: DB7339000
• PubChem CID: 135398549
• Peso molecular: 934.98

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organoheterocyclic compounds
    • Clase Tetrapyrroles and derivatives
      • Subclass Porphyrins

• Kingdom: Organic compounds
• Superclass: Organoheterocyclic compounds
• Clase: Tetrapyrroles and derivatives
• Subclass: Porphyrins
• Intermediate Tree Nodes: Not available
• Direct Parent: Porphyrins
• Alternative Parents: Benzenesulfonic acids and derivatives Benzenesulfonyl compounds 1-sulfo,2-unsubstituted aromatic compounds Sulfonyls Pyrroles Organosulfonic acids Heteroaromatic compounds Azacyclic compounds Organonitrogen compounds Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aromatic heteropolycyclic compounds
• Substituents: Porphyrin - Benzenesulfonate - Arylsulfonic acid or derivatives - Benzenesulfonyl group - 1-sulfo,2-unsubstituted aromatic compound - Monocyclic benzene moiety - Benzenoid - Pyrrole - Organic sulfonic acid or derivatives - Organosulfonic acid or derivatives - Organosulfonic acid - Sulfonyl - Heteroaromatic compound - Azacycle - Organic nitrogen compound - Organic oxygen compound - Organonitrogen compound - Organosulfur compound - Hydrocarbon derivative - Organic oxide - Aromatic heteropolycyclic compound
• Descripción: This compound belongs to the class of organic compounds known as porphyrins. These are compounds containing a fundamental skeleton of four pyrrole nuclei united through the alpha-positions by four methine groups to form a macrocyclic structure.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Peso molecular: 935.000 g/mol
• XLogP3: 5.400
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 8
• Exact Mass: 934.074 Da
• Monoisotopic Mass: 934.074 Da
• Topological Polar Surface Area: 308.000 Ų
• Heavy Atom Count: 64
• Formal Charge: 0
• Complexity: 1770.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Pengfei Bian, Na Li, Guohua Li, Senlin Zhang, Xiujuan Liu, Jianmin Gu, Bo Liu, Tifeng Jiao.  (2022)  Interfacial aggregation behavior of novel carbazole-based composite Langmuir-Blodgett films for photoelectric conversion and catalytic performance.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2022.130460]

2. Hongzhi Lu, Shoufang Xu.  (2021)  CDs–MnO2–TPPS Ternary System for Ratiometric Fluorescence Detection of Ascorbic Acid and Alkaline Phosphatase.  ACS Omega,      [PMID:34235328] [10.1021/acsomega.1c01828]

3. Wenhui Li, Hua Dong, Kejing Niu, Huan-Yu Wang, Wenqian Cheng, Hualong Song, An-Kang Ying, Xiaobing Zhai, Kefeng Li, Huijuan Yu, Dong-Sheng Guo, Yuefei Wang.  (2024)  Analyzing urinary hippuric acid as a metabolic health biomarker through a supramolecular architecture.  TALANTA,      [PMID:38972275] [10.1016/j.talanta.2024.126480]

4. Bin Xiao, Junhao Xiao, Sisi Liu, Xiaoying Xiao, Shengping Dai, Yan Sui, Jinming Wu, Huixian Ye.  (2024)  Peroxynitrite scavenger FeTPPS binds with hCT to effectively inhibit its amyloid aggregation.  DALTON TRANSACTIONS,      [PMID:39355983] [10.1039/D4DT02214A]

5. Xingdi Zhao, Xinyu Li, Pengfei Bian, Qingrui Zhang, Yuqing Qiao, Mingli Wang, Tifeng Jiao.  (2025)  SERS and Chiral Properties of Cinnamic Acid Derivative Langmuir-Blodgett Films Complexed with Dyes.  Coatings,  15  (8): (890).  [PMID:] [10.3390/coatings15080890]

6. Yudong Xue, Jia Tian, Zhiyong Liu, Jianbo Chen, Mengsi Wu, Yongjia Shen, Weian Zhang.  (2019)  A Redox Stimulation-Activated Amphiphile for Enhanced Photodynamic Therapy.  BIOMACROMOLECULES,      [PMID:31244019] [10.1021/acs.biomac.9b00581]

7. Chengkun Bai, Bingdi Wang, Zhengshun Jiang, Chunying Lv, Zhenning Liu, Shiyu Wang, Song Liang, Hongying Zang.  (2024)  Bioinspired electron carrier mediated transmembrane photocatalytic hydrogen evolution in silica colloidosomes.  Inorganic Chemistry Frontiers,      [PMID:] [10.1039/D4QI02015D]

8. Tianshun Ding, Shi Feng, Hao Li, Zelong Zhang, Shengyang Tao.  (2026)  Interfacial Chirality Transfer Induced by Vortices inside Microdroplets.  Small Methods,      [PMID:] [10.1002/smtd.70643]