Tri(o-tolyl)phosphine - ≥99% , CAS No.6163-58-2

CAS: 6163-58-2 Cat. No.: T396888 Peso molecular: 304.37 Beilstein Registry Number: 661212 Número EC: 228-193-9 PubChem CID: 80271

GRADE & PURITY ≥99%

Synonyms

FT-0636009 | Thionaphthoquinone | tritolylphosphine | tri-tolylphosphine | TRIS(2-TOLUENE)PHOSPHINE | tri(orthotolyl)phosphine | tri(ortho-tolyl)phosphine | Tri-o-tolylphosphine | tri-o-tolyl-phosphine | trio-tolylphosphine | AC-22726 | MFCD00015001 | P(o

Storage

Protected from light,Room temperature,Argon charged

Shipped In

Normal

Descripción general

Application

Tri(o-tolyl)phosphine is used in a ruthenium-catalyzed direct amination of alcohols. It is also used in Suzuki reaction. Further, it is used in the preparation of tri-ortho-phosphinselenide by reacting with selenium as a reagent. In addition to this, it acts as a ligand in coordination chemistry.

Specifications

Sinónimos

FT-0636009 | Thionaphthoquinone | tritolylphosphine | tri-tolylphosphine | TRIS(2-TOLUENE)PHOSPHINE | tri(orthotolyl)phosphine | tri(ortho-tolyl)phosphine | Tri-o-tolylphosphine | tri-o-tolyl-phosphine | trio-tolylphosphine | AC-22726 | MFCD00015001 | P(o

Especificaciones y pureza

≥99%

Información jurídica

Phosphine Ligand Kit component.

Condiciones de almacenamiento de almacenamiento

Protected from light, Room temperature, Argon charged

Enviado en

Normal

Pureza

≥99%

Nombres e identificadores

• Pubchem Sid: 488185834
• Sonrisas canónicas: CC1=CC=CC=C1P(C2=CC=CC=C2C)C3=CC=CC=C3C
• IUPAC Name: tris(2-methylphenyl)phosphane
• InChIKey: COIOYMYWGDAQPM-UHFFFAOYSA-N
• INCHI: 1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3
• Isómeros SMILES: CC1=CC=CC=C1P(C2=CC=CC=C2C)C3=CC=CC=C3C
• WGK Alemania: 3
• PubChem CID: 80271
• Peso molecular: 304.37
• Beilstein: 661212
• Reaxy-Rn: 661212

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Toluenes Organic phosphines and derivatives Organopnictogen compounds Hydrocarbon derivatives
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Triphenylphosphine - Toluene - Phenylphosphine - Phosphine - Organopnictogen compound - Hydrocarbon derivative - Organophosphorus compound - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Soluble in alcohol. Slightly soluble in cold water. Insoluble in water.
• Sensibilidad: light sensitive,air sensitive
• Punto de fusión (°C): 124-126°C
• Peso molecular: 304.400 g/mol
• XLogP3: 5.700
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 304.138 Da
• Monoisotopic Mass: 304.138 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 22
• Formal Charge: 0
• Complexity: 286.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Huixia Zhang, Zhaomin Wang, Yong Liu, Ping Xie.  (2022)  Exploring the direct effects of microcystin-LR on DNA via using cross-technical means.  ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY,      [PMID:36068764] [10.1016/j.ecoenv.2022.113841]

2. Aijing Wang, Minggang Tian, Yujing Zuo, Zhiming Gou.  (2022)  Carbazole-siloxane based polymers for the selective detection of 4-nitrophenol and Fe3+.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,      [PMID:] [10.1016/j.jphotochem.2022.113961]

3. Xiaomei Zhang, Zhiming Gou, Yujing Zuo, Weiying Lin.  (2021)  Pyrene-based polymer fluorescent materials for the detection of 2,4,6-trinitrophenol and cell imaging.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,      [PMID:] [10.1016/j.jphotochem.2021.113183]

4. Tong Hu, Liangliang Han, Manjun Xiao, Xichang Bao, Ting Wang, Mingliang Sun, Renqiang Yang.  (2014)  Enhancement of photovoltaic performance by increasing conjugation of the acceptor unit in benzodithiophene and quinoxaline copolymers.  Journal of Materials Chemistry C,  2  (38): (8047-8053).  [PMID:] [10.1039/C4TC01440E]

5. Ya Chu, Fei Zhao, Fanpeng Meng, Weiqiang Zhang, Jinsheng Zhao, Xiujuan Zhong.  (2024)  Donor-acceptor type conjugated porous polymers based on benzotrithiophen and triazine derivatives: Effect of linkage unit on photocatalytic water splitting.  INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,      [PMID:] [10.1016/j.ijhydene.2024.03.260]

6. Haoran Liu, Chenghao Wang, Lishuai Zong, Lingmei Jiang, Guangsheng Zhang, Zichun Ding, Zexian Jia, Changhong Xiao, Chao Li, Jinyan Wang, Xigao Jian.  (2024)  Solvent-free Acrylate/BCB drop-on-demand (DOD) inkjet dielectric ink for 3D printing.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.156411]

7. Leilei Zhang, Haoheng Bai, Weiqi Sun, Luqi Wang, Minyan Duan, Qianying Liu, Chao Zhou, Xueyang Fang, Tao Zhang.  (2026)  NIR-II Photoacoustic-Cavitation Boosted Metabolic Reprogramming Regulation Toward the Localized TNBC Growth Inhibition.  ACS Applied Materials & Interfaces,      [PMID:] [10.1021/acsami.6c02884]