Tri-tert-butylphosphine solution - 1.0 M in 2-methyltetrahydrofuran , CAS No.13716-12-6

CAS: 13716-12-6 Cat. No.: T431998 Peso molecular: 202.32 Beilstein Registry Number: 1738613 Número EC: 237-266-4 PubChem CID: 83681

GRADE & PURITY 1.0 M in 2-methyltetrahydrofuran

Synonyms

doi:10.14272/BWHDROKFUHTORW-UHFFFAOYSA-N.1 | EINECS 237-266-4 | tri tert-butylphosphane | Tri-tert-butylphosphine, 90%, technical grade | InChI=1/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H | monochloro-1,4-dimethoxybenzene | SCHEMBL28566 | tri-tert.buty

Storage

Room temperature

Descripción general

Application

Valuable ligand for several coupling reactions. This product is offered as a solution in 2-methyltetrahydrofuran for more convenient handling.

Specifications

Sinónimos

doi:10.14272/BWHDROKFUHTORW-UHFFFAOYSA-N.1 | EINECS 237-266-4 | tri tert-butylphosphane | Tri-tert-butylphosphine, 90%, technical grade | InChI=1/C12H27P/c1-10(2, 3)13(11(4, 5)6)12(7, 8)9/h1-9H | monochloro-1, 4-dimethoxybenzene | SCHEMBL28566 | tri-tert.buty

Especificaciones y pureza

1.0 M in 2-methyltetrahydrofuran

Condiciones de almacenamiento de almacenamiento

Room temperature

Nombres e identificadores

• Sonrisas canónicas: CC(C)(C)P(C(C)(C)C)C(C)(C)C
• IUPAC Name: tritert-butylphosphane
• InChIKey: BWHDROKFUHTORW-UHFFFAOYSA-N
• INCHI: 1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3
• Isómeros SMILES: CC(C)(C)P(C(C)(C)C)C(C)(C)C
• WGK Alemania: 3
• PubChem CID: 83681
• Número ONU: 2845
• Peso molecular: 202.32
• Beilstein: 1738613

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organophosphorus compounds
    • Clase Organic phosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Organophosphorus compounds
• Clase: Organic phosphines and derivatives
• Subclass: Not available
• Intermediate Tree Nodes: Not available
• Direct Parent: Organic phosphines and derivatives
• Alternative Parents: Organopnictogen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Phosphine - Organopnictogen compound - Hydrocarbon derivative - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as organic phosphines and derivatives. These are organic compounds containing a phosphine derivative, with the general formula B1P(R2)R3 (R1-R3=alkyl, aryl).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Punto de inflamación (°F): 39.2 °F
• Punto de inflamación (°C): -17 °C
• Punto de ebullición (°C): 102-103°C
• Punto de fusión (°C): 30-35°C
• Peso molecular: 202.320 g/mol
• XLogP3: 2.900
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 202.185 Da
• Monoisotopic Mass: 202.185 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 13
• Formal Charge: 0
• Complexity: 128.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Jie Xie, Xiaobing Wang, Yonghui Wang, Jiawei Li, Chun Cao, Ming Jin.  (2023)  Effect of substituents on the performance of N-carbazolyl double benzylidene ketones in visible/NIR light one/two-photon polymerization.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2023.112636]

2. Xianqi Zhu, Lin Li, Jin Tang, Chunyu Yang, Hao Yu, Kunpeng Liu, Ziyan Zheng, Xinggui Gu, Qingsong Yu, Fu-Jian Xu, Zhihua Gan.  (2021)  Cascade-responsive nano-assembly for efficient photothermal-chemo synergistic inhibition of tumor metastasis by targeting cancer stem cells.  BIOMATERIALS,      [PMID:34890970] [10.1016/j.biomaterials.2021.121305]

3. Shuailing Huang, Yinglong Wu, Fang Zeng, Junjie Chen, Shuizhu Wu.  (2018)  A turn-on fluorescence probe based on aggregation-induced emission for leucine aminopeptidase in living cells and tumor tissue.  ANALYTICA CHIMICA ACTA,      [PMID:30119736] [10.1016/j.aca.2018.05.032]

4. Ruming Jiang, Meiying Liu, Hongye Huang, Long Huang, Qiang Huang, Yuanqing Wen, Qian-yong Cao, Jianwen Tian, Xiaoyong Zhang, Yen Wei.  (2017)  A novel self-catalyzed photoATRP strategy for preparation of fluorescent hydroxyapatite nanoparticles and their biological imaging.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2017.11.039]

5. Shuailing Huang, Yinglong Wu, Fang Zeng, Lihe Sun, Shuizhu Wu.  (2016)  Handy ratiometric detection of gaseous nerve agents with AIE-fluorophore-based solid test strips.  Journal of Materials Chemistry C,  4  (42): (10105-10110).  [PMID:] [10.1039/C6TC03116A]

6. Lihuan Xu, Qiang Fei, Lin Yao, Chang Su.  (2024)  Triphenylamine-containing dihydrophenazine copolymers with adjustable multi-electron redox characteristics and their application as cathodes in lithium-organic batteries.  Journal of Materials Chemistry A,  12  (22): (13320-13327).  [PMID:] [10.1039/D4TA00778F]