Triethylborane solution - 1.0M in hexanes , CAS No.97-94-9

CAS: 97-94-9 Cat. No.: T466127 Peso molecular: 97.99 Beilstein Registry Number: 1731462 Número EC: 202-620-9

GRADE & PURITY 1.0M in hexanes

Synonyms

Boron triethyl | Triethylborane | triethyl-borane | InChI=1/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H | FT-0655589 | Borane, triethyl- | EN300-35961 | triethyl borane | triethylboran | Triethylborine | 4-04-00-04359 (Beilstein Handbook Reference) | BEt3 | Et3B |

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice,FedEx DG Service

Descripción general

Description

Triethylborane can be used:As a radical initiator and terminator of free-radical reactions in aqueous media.(1)To synthesize polymers such as poly(2-substituted-1-propenylene)s by reacting with 2-substituted allylic arsonium ylides.(2)Catalyst for:Allylation of aldehydesDecarboxylative C-C bond cleavage reactionsRhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenationsRegioselective hydroxyalkylation of unsaturated oxime ethersReactant for radical reductions of alkyl bromides withN-heterocyclic carbene boranesReactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential

Specifications

Sinónimos

Boron triethyl | Triethylborane | triethyl-borane | InChI=1/C6H15B/c1-4-7(5-2)6-3/h4-6H2, 1-3H | FT-0655589 | Borane, triethyl- | EN300-35961 | triethyl borane | triethylboran | Triethylborine | 4-04-00-04359 (Beilstein Handbook Reference) | BEt3 | Et3B |

Especificaciones y pureza

1.0M in hexanes

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice, FedEx DG Service

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Nombres e identificadores

• Isómeros SMILES: B(CC)(CC)CC
• WGK Alemania: 3
• RTECS: ED2100000
• Número ONU: 2845
• Peso molecular: 97.99
• Beilstein: 1731462
• Reaxy-Rn: 1731462

Propiedades químicas y físicas

• Sensibilidad: Moisture sensitive，Air sensitive；
• Punto de inflamación (°F): -32.8 °F
• Punto de inflamación (°C): -36 °C
• Punto de ebullición (°C): 95°C
• Punto de fusión (°C): -92°C
• Peso molecular: 98.000 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 98.1267 Da
• Monoisotopic Mass: 98.1267 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 7
• Formal Charge: 0
• Complexity: 25.700
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

Referencias

1. Qing Huang, Wen-Zhen Wang, Shuang Liu, Xin-Gang Jia, Li Xia, Fang-Ling Qin, Qian Wang, Yun Liu, Hong-Jiu Li.  (2023)  Green fabrication of carbon dioxide-based polycarbonates with durable antimicrobial properties and UV resistance.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2023.147107]

2. Xin Huang, Krill Alferov, Tingting Zhao, Jingyao Yin, Shuanjin Wang, Dongmei Han, Sheng Huang, Zhiheng Huang, Min Xiao, Yuezhong Meng.  (2023)  Facile and direct synthesis of oligocarbonate diols from carbon dioxide and their application as sustainable feedstock for polyurethane.  Journal of CO2 Utilization,      [PMID:] [10.1016/j.jcou.2023.102571]

3. Lijun Wang, Fang Wang, Qiang Zhou, Yanfei Wang, Haixiang Song, Haiyang Yang.  (2022)  Metal-free Lewis pairs catalysed synthesis of fluorescently labelled polyester-based amphiphilic polymers for biological imaging.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2022.111033]

4. Boru Zhang, Heng Li, Huitong Luo, Junpeng Zhao.  (2020)  Ring-opening alternating copolymerization of epichlorohydrin and cyclic anhydrides using single- and two-component metal-free catalysts.  EUROPEAN POLYMER JOURNAL,      [PMID:] [10.1016/j.eurpolymj.2020.109820]

5. Xin Huang, Tingting Zhao, Shuanjin Wang, Dongmei Han, Sheng Huang, Hui Guo, Min Xiao, Yuezhong Meng.  (2024)  Self-Healable, Transparent, Biodegradable, and Shape Memorable Polyurethanes Derived from Carbon Dioxide-Based Diols.  MOLECULES,  29  (18): (4364).  [PMID:39339359] [10.3390/molecules29184364]

6. Jinsong Wang, Huining Xiao, Haijiao Xie, Yang Huang, Farzad Seidi.  (2025)  Tailoring disulfide-embedded lignin-based hydrophobic self-healing coatings for metal protection.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:40280525] [10.1016/j.ijbiomac.2025.143448]

7. Ming Niu, Zhenghua Zhang, Rourou Wang, Yaxin Zhou, Jing Zhou, Lumei Pu, Weibing Xu.  (2025)  Antibacterial efficacy and pharmacokinetics of a poly(mPEG-b-PCEA)–trimethoprim conjugate.  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D5NJ01599E]

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9. Mingsheng Liu, Lian He, Shuanjin Wang, Dongmei Han, Sheng Huang, Min Xiao, Yuezhong Meng.  (2026)  Structural Instability Origins in Polythiocarbonates: O/S Exchange Phenomenon and Stability Hierarchy.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.5c02472]