(Trimetilsilil)diazometano - 2.0 M en hexanos , CAS No.18107-18-1

CAS: 18107-18-1 Cat. No.: T140538 Peso molecular: 114.22 Beilstein Registry Number: 1902903 Número EC: 605-915-4 PubChem CID: 167693
Disponible para pedir
GRADE & PURITY 2.0 M in hexanes
Synonyms
QI98HQO8C4 | TMSD | AT38821 | trimetilsilil diazometano | trimetilsilano | diazometiltrimetilsilano | EN300-74206 | Trimetilsilil diazometano | (Diazometil)trimetilsilano | (diazometil)-trimetilsilano | Q1990988 | trimetilsilldia
Storage
Conservar a 2-8°C,cargado con argón
Shipped In
Hielo húmedo
 ·  off list, applied to all prices below.
Size
Estado
Price
Qty
5ml
T140538-5ml
8-12 wks(?) Production requires sourcing of materials. We appreciate your patience and understanding.
39,90US$
25ml
T140538-25ml
1
139,90US$
100ml
T140538-100ml
1
389,90US$
500ml
T140538-500ml
1
1.399,90US$
Enter a quantity for the sizes you want to add.
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Why this grade

2.0 M en hexanos for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

🌡

Storage & shipping

Conservar a 2-8°C,cargado con argón Ships Hielo húmedo Check lot-specific COA for exact specifications.

📋

Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

📚

Literature proof

Cited in 17 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Descripción general

Reactivo para la preparación de: &bull Análogos macrolactámicos del producto natural macrólido (-)-A26771B con estabilidad metabólica y actividad antibacteriana mejoradas &bull Análogos de la aigialomicina D como inhibidores de la proteína quinasa para el tratamiento del cáncer &bull Derivados de α-aminoácidos no naturales que contienen gem-bisfosfonatos mediante reacción de adición de Michael &bull Disacáridos y tetrasacáridos de hialuronano 4-metilumbeliferil recubiertos como sustratos potenciales de hialuronidasa &bull Stictamidas A-C como inhibidores de la metalopéptidasa de matriz 12 (MMP12) con actividad antitumoral invasiva &bull Inhibidores de la enzima convertidora de endotelina (ECE) WS 75624A y WS 75624B mediante un enfoque de metátesis cruzada &bull Derivados de ent-kaureno como agentes antiinflamatorios &bull Análogos de desmosdumotina C como potentes agentes antitumorales que actúan a través de la activación del punto de control de ensamblaje del huso &bull Imidazolo[2,1-b]benzotiazol como posibles inhibidores de p53

Specifications

Sinónimos
QI98HQO8C4 | TMSD | AT38821 | trimetilsilil diazometano | trimetilsilano | diazometiltrimetilsilano | EN300-74206 | Trimetilsilil diazometano | (Diazometil)trimetilsilano | (diazometil)-trimetilsilano | Q1990988 | trimetilsilldia
Especificaciones y pureza
2.0 M en hexanos
Condiciones de almacenamiento de almacenamiento
Conservar a 2-8°C, cargado con argón
Enviado en
Hielo húmedo
Nombres e identificadores
Sonrisas canónicasC[Si](C)(C)C=[N+]=[N-]
IUPAC Namediazomethyl(trimethyl)silane
InChIKeyONDSBJMLAHVLMI-UHFFFAOYSA-N
INCHI1S/C4H10N2Si/c1-7(2,3)4-6-5/h4H,1-3H3
Isómeros SMILES C[Si](C)(C)C=[N+]=[N-]
WGK Alemania 3
PubChem CID 167693
Peso molecular 114.22
Beilstein 1902903

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganometallic compounds
ClaseOrganometalloid compounds
SubclassOrganosilicon compounds
Intermediate Tree Nodes Alkylsilanes
Direct ParentTrialkylsilanes
Alternative Parents Diazo compounds  Organic metalloid salts  Organopnictogen compounds  Organonitrogen compounds  Hydrocarbon derivatives  
Molecular FrameworkAliphatic acyclic compounds
Substituents Trialkylsilane - Diazo compound - Organic metalloid salt - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organic salt - Organonitrogen compound - Aliphatic acyclic compound
DescripciónThis compound belongs to the class of organic compounds known as trialkylsilanes. These are organosilicon compounds containing exactly one alkyl chain attached to the silicon atom.
External Descriptors Not available
Estructura 3D
Modelo de Estructura Química Interactiva





Certificados (CoA, COO, BSE/TSE y tabla de análisis)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

42 results found

Lot NumberCertificate TypeFechaArticulo
F2509597Certificate of AnalysisMar 29, 2025 T140538
F2509648Certificate of AnalysisMar 29, 2025 T140538
F2509650Certificate of AnalysisMar 29, 2025 T140538
C2624180Certificate of AnalysisJan 11, 2025 T140538
C2624181Certificate of AnalysisJan 11, 2025 T140538
C2624182Certificate of AnalysisJan 11, 2025 T140538
B2520416Certificate of AnalysisJan 11, 2025 T140538
B2520333Certificate of AnalysisJan 11, 2025 T140538
B2520334Certificate of AnalysisJan 11, 2025 T140538
B2520415Certificate of AnalysisJan 11, 2025 T140538
K2415594Certificate of AnalysisNov 01, 2024 T140538
K2415590Certificate of AnalysisNov 01, 2024 T140538
K2415592Certificate of AnalysisNov 01, 2024 T140538
H2402457Certificate of AnalysisJul 18, 2024 T140538
H2402458Certificate of AnalysisJul 18, 2024 T140538
H2402581Certificate of AnalysisJul 18, 2024 T140538
K2407137Certificate of AnalysisJul 18, 2024 T140538
F2429148Certificate of AnalysisApr 11, 2024 T140538
C2426372Certificate of AnalysisMar 08, 2024 T140538
C2426371Certificate of AnalysisMar 08, 2024 T140538
A2410386Certificate of AnalysisDec 28, 2023 T140538
A2410387Certificate of AnalysisDec 28, 2023 T140538
A2410388Certificate of AnalysisDec 28, 2023 T140538
A2410389Certificate of AnalysisDec 28, 2023 T140538
A2410390Certificate of AnalysisDec 28, 2023 T140538
A2410391Certificate of AnalysisDec 28, 2023 T140538
C2327311Certificate of AnalysisMar 10, 2023 T140538
C2327310Certificate of AnalysisMar 10, 2023 T140538
C2327309Certificate of AnalysisMar 10, 2023 T140538
J2330056Certificate of AnalysisMar 10, 2023 T140538
C2327312Certificate of AnalysisMar 10, 2023 T140538
H2328053Certificate of AnalysisMar 10, 2023 T140538
G2214591Certificate of AnalysisJul 04, 2022 T140538
A2309425Certificate of AnalysisJul 04, 2022 T140538
G2214592Certificate of AnalysisJul 04, 2022 T140538
G2214590Certificate of AnalysisJul 04, 2022 T140538
G2214589Certificate of AnalysisJul 04, 2022 T140538
A2309424Certificate of AnalysisJul 04, 2022 T140538
C2202607Certificate of AnalysisFeb 17, 2022 T140538
C2202610Certificate of AnalysisFeb 17, 2022 T140538
C2202629Certificate of AnalysisFeb 17, 2022 T140538
C2202637Certificate of AnalysisFeb 17, 2022 T140538

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Propiedades químicas y físicas
SolubilidadImmiscible with water. Miscible with organic solvents.
SensibilidadHeat & Moisture & Light Sensitive.
Punto de inflamación (°F)-9.4 °F
Punto de inflamación (°C)-23 °C
Punto de ebullición (°C)96°C
Peso molecular114.220 g/mol
XLogP3
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count1
Rotatable Bond Count1
Exact Mass114.061 Da
Monoisotopic Mass114.061 Da
Topological Polar Surface Area2.000 Ų
Heavy Atom Count7
Formal Charge0
Complexity96.700
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count0
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count1
The total count of all stereochemical bonds1
Covalently-Bonded Unit Count1
Preguntas frecuentes y artículos
Citations of This Product
Referencias
1. Zhang Yu, Zheng Jianzhi, Li Xijuan, Wu Ying, Zhang Ke.  (2023)  Stoichiometric Imbalance-promoted Step-growth Polymerization Based on Self-accelerating Three-component Reaction.  CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,  39  (5): (822-828).  [PMID:] [10.1007/s40242-023-3173-3]
2. Chujun Liu, Yawen Guo, Bo Wang, Lan Chen, Kaizhou Xie, Chenggen Yang.  (2021)  Establishment and Validation of a GC–MS/MS Method for the Quantification of Penicillin G Residues in Poultry Eggs.  Foods,  10  (11): (2735).  [PMID:34829016] [10.3390/foods10112735]
3. Xiaoling Long, Huilin Xu, Dongyue Zhang, Jianshu Li.  (2020)  Bioinspired by both mussel foot protein and bone sialoprotein: universal adhesive coatings for the promotion of mineralization and osteogenic differentiation.  Polymer Chemistry,  11  (31): (4995-5004).  [PMID:] [10.1039/D0PY00774A]
4. Tu Lichan, Su Ping, Zhang Zhongren, Gao Linhui, Wang Jiadian, Hu Tianyuan, Zhou Jiawei, Zhang Yifeng, Zhao Yujun, Liu Yuan, Song Yadi, Tong Yuru, Lu Yun, Yang Jian, Xu Cao, Jia Meirong, Peters Reuben J., Huang Luqi, Gao Wei.  (2020)  Genome of Tripterygium wilfordii and identification of cytochrome P450 involved in triptolide biosynthesis.  Nature Communications,  11  (1): (1-12).  [PMID:32080175] [10.1038/s41467-020-14776-1]
5. Mengtao Zhang, Wei Guo, Juntong Wei, Jianghong Shi, Jiawei Zhang, Hui Ge, Huanyu Tao, Xiaowei Liu, Qing Hu, Zongwei Cai.  (2019)  Determination of newly synthesized dihydroxylated polybrominated diphenyl ethers in sea fish by gas chromatography-tandem mass spectrometry.  CHEMOSPHERE,      [PMID:31563719] [10.1016/j.chemosphere.2019.124878]
6. Lu Chunxia, Tang Zonggui, Gao XiaoXu, Ma Xiaomei, Liu Changbin.  (2018)  Computer-aided design of magnetic dummy molecularly imprinted polymers for solid-phase extraction of ten phthalates from food prior to their determination by GC-MS/MS.  MICROCHIMICA ACTA,  185  (8): (1-11).  [PMID:30003399] [10.1007/s00604-018-2892-5]
7. Fang Wei, Xiang Wang, Hui-fang Ma, Xin Lv, Xu-yan Dong, Hong Chen.  (2018)  Rapid profiling and quantification of phospholipid molecular species in human plasma based on chemical derivatization coupled with electrospray ionization tandem mass spectrometry.  ANALYTICA CHIMICA ACTA,      [PMID:29776536] [10.1016/j.aca.2018.04.012]
8. Su Ping, Guan Hongyu, Zhang Yifeng, Wang Xing, Gao Linhui, Zhao Yujun, Hu Tianyuan, Zhou Jiawei, Ma Baowei, Tu Lichan, Tong Yuru, Huang Luqi, Gao Wei.  (2017)  Probing the Single Key Amino Acid Responsible for the Novel Catalytic Function of ent-Kaurene Oxidase Supported by NADPH-Cytochrome P450 Reductases in Tripterygium wilfordii.  Frontiers in Plant Science,      [PMID:29081786] [10.3389/fpls.2017.01756]
9. Yan Qiongxian, Tang Shaoxun, Han Xuefeng, Bamikole Musibau Adungbe, Zhou Chuanshe, Kang Jinhe, Wang Min, Tan Zhiliang.  (2016)  Effects of Chain Length and Saturability of Fatty Acids on Phospholipids and Proteins in Plasma Membranes of Bovine Mammary Gland.  JOURNAL OF MEMBRANE BIOLOGY,  249  (6): (743-756).  [PMID:27469350] [10.1007/s00232-016-9919-9]
10. Cao Weijia, Ma Weichao, Zhang Bowen, Wang Xin, Chen Kequan, Li Yan, Ouyang Pingkai.  (2016)  Improved pinocembrin production in Escherichia coli by engineering fatty acid synthesis.  JOURNAL OF INDUSTRIAL MICROBIOLOGY & BIOTECHNOLOGY,  43  (4): (557-566).  [PMID:26733394] [10.1007/s10295-015-1725-3]
11. Su Ping, Tong Yuru, Cheng Qiqing, Hu Yating, Zhang Meng, Yang Jian, Teng Zhongqiu, Gao Wei, Huang Luqi.  (2016)  Functional characterization of ent-copalyl diphosphate synthase, kaurene synthase and kaurene oxidase in the Salvia miltiorrhiza gibberellin biosynthetic pathway.  Scientific Reports,  (1): (1-8).  [PMID:26971881] [10.1038/srep23057]
12. Hui-Qin Pan, Rui Feng, Yan-Nan Tan, Xiao-Ya Qin, Yi-Min Cao, Xiu-Hong Mao, Qing Hu, Heng Zhou.  (2024)  Determination of Puberulic Acid in Monascus-Fermented Red Yeast Rice by LC-MS/MS Combined with Precolumn Derivatization.  Toxins,  17  (1): (11).  [PMID:39852964] [10.3390/toxins17010011]
13. Wenyu Cui, Jin Liu, Lin Zhu, Mandlaa, Ziyu Sun, Zhongjun Chen.  (2024)  Studies on acid resistance mechanism of Saccharomyces cerevisiae HJ-U17 during fruit fermentation with high acidity.  LWT-FOOD SCIENCE AND TECHNOLOGY,      [PMID:] [10.1016/j.lwt.2024.117243]
14. Shuai Yang, Lin Zhang, Yibing Sun, Zhichao Yang, Hongchao Li.  (2025)  Nonradical degradation of phosphonates to orthophosphate via surface-activated peroxides on carbon nanotubes.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2025.133242]
15. Peiling Wu, Haofeng Chen, Guojun Yang, Haoyu Qin, Qian Zhang, Yuxin Chen, Dongjiang Lin, Yang Zhang, Shuyong Lin, Shizhen Wang, Jifeng Yuan.  (2025)  Engineering Escherichia coli for the S-selective production of 2-hydroxyisovalerate.  BioDesign Research,      [PMID:] [10.1016/j.bidere.2025.100059]
16. Dan Yang, Yingxiang Dong, Jiahao Zhang, Sijie Yang, Ruijie Lu, Ziqing Liu, Biao Xiong, De-Shan Bin, Jizhuang Wang, Yin Ning, Dan Li.  (2025)  Fusion Assembly of Diblock Copolymer Nanoparticles at Liquid–Solid Interface.  MACROMOLECULES,      [PMID:] [10.1021/acs.macromol.5c02832]
17. Ruijia Wang, Hongda Guo, Tao Zhang, Xiaoxia Chen, Min Ge, Shujun Li, Jian Li, Bing Tian, Bernd Strehmel, Shouxin Liu, Andrey L. Rogach, Tony D. James, Zhijun Chen.  (2026)  Sunlight-Driven Fixation of CO2 to Cyclic Carbonates Using Carbon Dots as a Photothermal Catalyst.  Exploration,      [PMID:41810072] [10.1002/EXP.20250043]
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