Determine the necessary mass, volume, or concentration for preparing a solution.
30% in hydrochloric acid for sensitive chromatographic and analytical workflows requiring minimal baseline interference.
Room temperature Ships Check lot-specific COA for exact specifications.
SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.
Cited in 57 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.
Description
Building block for a new series of mixed zirconium phosphonates which may have uses in catalysis, ion exchange or photophysics.
| Sonrisas canónicas | O=[Zr].Cl.Cl |
|---|---|
| IUPAC Name | oxozirconium;dihydrochloride |
| InChIKey | CMOAHYOGLLEOGO-UHFFFAOYSA-N |
| INCHI | 1S/2ClH.O.Zr/h2*1H;; |
| Isómeros SMILES | O=[Zr].Cl.Cl |
| PubChem CID | 24373 |
| Número ONU | 1759 |
| Grupo de embalaje | I |
| Peso molecular | 178.13 |
Comprehensive hazard, handling, storage, and regulatory compliance document.
Download SDS →Lot-specific quality data. Enter your lot number to retrieve the exact COA.
Look up COA →Full quality attributes and acceptance criteria for this grade.
View spec sheet →Taxonomy Tree
| Kingdom | Inorganic compounds |
|---|---|
| Superclass | Mixed metal/non-metal compounds |
| Clase | Transition metal salts |
| Subclass | Transition metal chlorides |
| Intermediate Tree Nodes | Not available |
| Direct Parent | Transition metal chlorides |
| Alternative Parents | Inorganic salts Inorganic oxides Inorganic hydrides |
| Molecular Framework | Not available |
| Substituents | Transition metal chloride - Inorganic hydride - Inorganic oxide - Inorganic salt |
| Descripción | This compound belongs to the class of inorganic compounds known as transition metal chlorides. These are inorganic compounds in which the largest halogen atom is Chlorine, and the heaviest metal atom is a transition metal. |
| External Descriptors | Not available |
| Punto de fusión (°C) | −15 °C |
|---|---|
| Peso molecular | 180.140 g/mol |
| XLogP3 | |
| Hydrogen Bond Donor Count | 2 |
| Hydrogen Bond Acceptor Count | 1 |
| Rotatable Bond Count | 0 |
| Exact Mass | 177.853 Da |
| Monoisotopic Mass | 177.853 Da |
| Topological Polar Surface Area | 17.100 Ų |
| Heavy Atom Count | 4 |
| Formal Charge | 0 |
| Complexity | 6.000 |
| Isotope Atom Count | 0 |
| Defined Atom Stereocenter Count | 0 |
| Undefined Atom Stereocenter Count | 0 |
| Defined Bond Stereocenter Count | 0 |
| Undefined Bond Stereocenter Count | 0 |
| The total count of all stereochemical bonds | 0 |
| Covalently-Bonded Unit Count | 3 |
| 1. Juanjuan Zheng, Jiahao Liu, Jinzheng Zhang, Yisha Jiang, Shiwei Xu, Yueyue Feng, Liying Huang, Guofeng Wang, Fen Wu, Nannan Liu. (2023) Dual-current signal high-sensitivity detection of telomerase using signal amplified DNA functionalized metal-organic frameworks in glass nanopipettes. SENSORS AND ACTUATORS B-CHEMICAL, [PMID:] [10.1016/j.snb.2023.134950] |
| 2. Cong Wu, Chun Zhang, Xianyi Yan, Qian Liang, Kang Zhao, Yufei Tang. (2023) Preparation and antibacterial properties of BCZT-Ag piezoelectric coating on titanium surface for orthopedic implants. CERAMICS INTERNATIONAL, [PMID:] [10.1016/j.ceramint.2023.10.261] |
| 3. Huan-Yu Chen, Xing-Biao Liu, Qi-Xin Guan, Can-Jun Zou, Ping-Ping Fang. (2023) Detection of Oxytetracycline on NH2–UiO-66(Zr)@Au NPs with High Sensitivity and Selectivity by SERS. Journal of Physical Chemistry C, [PMID:] [10.1021/acs.jpcc.3c05339] |
| 4. Bing Yin, Fangyu Fan, Xujiang Hua, Dongmei Qi, Kailu Han, Youqing Hou, Dongshuai Hou. (2023) Reinforced anticorrosive composite coating with mesh-brick structures and excellent air permeability on concrete. Journal of Building Engineering, [PMID:] [10.1016/j.jobe.2023.107378] |
| 5. Cong Wu, Chun Zhang, Xianyi Yan, Junhua Cheng, Lei Chen, Yufei Tang, Kang Zhao. (2023) Preparation and biological properties of BCZT/TiO2 electrokinetic conversion coating on titanium surface in vitro for dental implants. SURFACE & COATINGS TECHNOLOGY, [PMID:] [10.1016/j.surfcoat.2023.129746] |
| 6. Hong Zhu, Yan Huang, Simi Li, Lingkui Zhao, Junfeng Zhang. (2023) Enhanced CO2 adsorption of PEHA/sepiolite adsorbent by zirconium accelerator in post-combustion. SEPARATION AND PURIFICATION TECHNOLOGY, [PMID:] [10.1016/j.seppur.2023.124395] |
| 7. Xinxin Xia, Hongyang Yu, Pindian Qin, Mingyu Dai, Lixue Jia, Yi Deng, Cuiqin Li, Feng Li. (2023) Organodiphosphonate Zr-MOF: A highly efficient catalyst for Meerwein–Ponndorf–Verley reduction of furfural. Asia-Pacific Journal of Chemical Engineering, 18 (5): (e2937). [PMID:] [10.1002/apj.2937] |
| 8. Xiwen Li, Zuan Yang, Peiran Meng, Shipeng Jiang, Mingyang Sun, Xiaoyu Zhang, Yue Sun. (2023) Ultrasensitive electrochemical detection of phospholipase C via dual signal amplification based on MVL ATRP and silver nanoparticles. MICROCHEMICAL JOURNAL, [PMID:] [10.1016/j.microc.2023.108847] |
| 9. Xiwen Li, Peiran Meng, Mingyang Sun, Yue Chen, Zhiyi Song, Xinyao Wang, Na Li, Yue Sun. (2023) An ultrasensitive electrochemical sensor for phospholipase C via signal amplification based on breathing ATRP and its application. ANALYST, 148 (10): (2352-2361). [PMID:37098798] [10.1039/D3AN00234A] |
| 10. Guozhi Fan, Yi Chen, Yuchan Lu, Qunpeng Cheng, Bo Chai, Guangsen Song. (2023) Co-production of 5-hydroxymethyl furfural and furfural from holocellulose over UiO-66-derived acid-base catalysts. CHEMICAL ENGINEERING SCIENCE, [PMID:] [10.1016/j.ces.2023.118768] |
| 11. Cheng Ying, Zhang Wei, Shi Biqing, Li Siqi, Dong Bing, Quan Yulian, Ji Xianbin. (2023) Improved the hydrogen sorption properties of MgH2 by CeMnZr solid solution. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 40 (1): (104-111). [PMID:] [10.1007/s11814-022-1287-9] |
| 12. Bing Yin, Xujiang Hua, Fangyu Fan, Dongmei Qi, Kailu Han, Youqing Hou, Dongshuai Hou. (2022) A functional and robust super-hydrophobic PCC coating based on the induced assembly of modified zirconium phosphate. JOURNAL OF APPLIED POLYMER SCIENCE, 140 (6): (e53427). [PMID:] [10.1002/app.53427] |
| 13. Weng Changmei, Li Guanhua, Zhang Dongdong, Duan Zhaoxia, Chen Kuijun, Zhang Jieyuan, Li Tao, Wang Jianmin. (2022) Nanoscale Porphyrin Metal-Organic Frameworks Deliver siRNA for Alleviating Early Pulmonary Fibrosis in Acute Lung Injury. Frontiers in Bioengineering and Biotechnology, [PMID:35923570] [10.3389/fbioe.2022.939312] |
| 14. Meng Zhao, Yujie Ban, Weishen Yang. (2022) Assembly of ionic liquid molecule layers on metal–organic framework-808 for CO2 capture. CHEMICAL ENGINEERING JOURNAL, [PMID:] [10.1016/j.cej.2022.135650] |
| 15. Su Yang, Xiaoxuan Guo, Xiaomei Pan, Liuyu Gu, Xueping Liu, Lijing Gao, Guomin Xiao. (2021) Synthesis of Brominated Alkanes via Heterogeneous Catalytic Distillation over Al2O3/SO42−/ZrO2. Catalysts, 11 (12): (1464). [PMID:] [10.3390/catal11121464] |
| 16. Ying Cheng, Shuhua Zhou, Biqing Shi, Bing Dong, Xianbin Ji, Siqi Li, Wei Zhang. (2021) A novel Ce0.8Fe0.1Zr0.1O2 solid solution with high catalytic activity for hydrogen storage in MgH2. RSC Advances, 11 (60): (37677-37683). [PMID:35498102] [10.1039/D1RA06951A] |
| 17. Longfei Zhang, Luhong Zhang, Yongli Sun, Bin Jiang. (2021) Porous ZrO2 encapsulated perovskite composite oxide for organic pollutants removal: Enhanced catalytic efficiency and suppressed metal leaching. JOURNAL OF COLLOID AND INTERFACE SCIENCE, [PMID:33848748] [10.1016/j.jcis.2021.03.171] |
| 18. Huikai Shao, Liang Lai, Dongsheng Xu, Jacques Crommen, Qiqin Wang, Zhengjin Jiang. (2021) Development of zirconium modified adenosine triphosphate functionalized monolith for specific enrichment of N-glycans. JOURNAL OF CHROMATOGRAPHY A, [PMID:33823387] [10.1016/j.chroma.2021.462090] |
| 19. Bin Han, Xinwen Ou, Zuqi Zhong, Shujie Liang, Xu Yan, Hong Deng, Zhang Lin. (2020) Photoconversion of anthropogenic CO2 into tunable syngas over industrial wastes derived metal-organic frameworks. APPLIED CATALYSIS B-ENVIRONMENTAL, [PMID:] [10.1016/j.apcatb.2020.119594] |
| 20. Tianxiang Li, Songbo Chen, Songhan Wan, Shuwei Cai, Xianru He. (2020) The effect of functional zirconium phosphate on aging resistance of nitrile butadiene rubber composites. POLYMER COMPOSITES, 41 (5): (1867-1877). [PMID:] [10.1002/pc.25504] |
| 21. Qiwen Wang, Haipei Si, Lihui Zhang, Ling Li, Xiaohong Wang, Shengtian Wang. (2020) A fast and facile electrochemical method for the simultaneous detection of epinephrine, uric acid and folic acid based on ZrO2/ZnO nanocomposites as sensing material. ANALYTICA CHIMICA ACTA, [PMID:32106959] [10.1016/j.aca.2020.01.012] |
| 22. Xiaojing Lv, Lixia Zha, Liang Qian, Xinjia Xu, Qian Bi, Zhiyi Xu, Dominic S. Wright, Cheng Zhang. (2019) Controllable fabrication of perylene bisimide self-assembled film and patterned all-solid-state electrochromic device. CHEMICAL ENGINEERING JOURNAL, [PMID:] [10.1016/j.cej.2019.123939] |
| 23. Lixue Gai, Qingda An, Zuoyi Xiao, Shangru Zhai, Haisong Wang, Weijie Cai, Zhongcheng Li. (2019) Rational construction of Co NPs embedded N-doped carbon layer/ZrSBA-15 composites with hierarchical succulent-like nanostructures for enhanced microwave absorption. MICROPOROUS AND MESOPOROUS MATERIALS, [PMID:] [10.1016/j.micromeso.2019.109880] |
| 24. Jiang Feng, Sun Haoyang, Chen Lei, Lei Fan, Sun Dazhi. (2019) Dispersion-tribological property relationship in mineral oils containing 2D layered α-zirconium phosphate nanoplatelets. Friction, 8 (4): (695-707). [PMID:] [10.1007/s40544-019-0294-2] |
| 25. Taotao Qiang, Qi Zhang, Liang Chen. (2019) A clean and economical processing system to improve the fluffiness of down fibers based on alkalized Zr(SO4)2. Journal of Cleaner Production, [PMID:] [10.1016/j.jclepro.2019.117625] |
| 26. Jian He, Hu Li, Yufei Xu, Song Yang. (2019) Dual acidic mesoporous KIT silicates enable one-pot production of γ-valerolactone from biomass derivatives via cascade reactions. RENEWABLE ENERGY, [PMID:] [10.1016/j.renene.2019.06.105] |
| 27. Zhang Xiaosheng, Xu Hong, Dong Jinxiang. (2019) Tribological Properties of Magnesium Ion-exchanged α-Zirconium Phosphate as a Solid Lubricant Additive in Lithium Grease. JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 34 (1): (47-54). [PMID:] [10.1007/s11595-019-2013-2] |
| 28. Dongmei Han, Yiqing Luo, Qing Ju, Xujing Xiao, Min Xiao, Naiyu Xiao, Shou Chen, Xiaohua Peng, Shuanjin Wang, Yuezhong Meng. (2018) Nano-Brick Wall Architectures Account for Super Oxygen Barrier PET Film by Quadlayer Assembly of Polyelectrolytes and α-ZrP Nanoplatelets. Polymers, 10 (10): (1082). [PMID:30961007] [10.3390/polym10101082] |
| 29. Dalei Sun, Kaihong Xie, Yanxiong Fang, Xianghua Yang. (2018) One-Pot Synthesis of N,N′-dialkylureas via Carbonylation of Amines with CO2 Applying Y0.08Zr0.92O1.96 Mixed Oxide (YSZ-8) as a Heterogeneous Catalyst. Catalysts, 8 (5): (188). [PMID:] [10.3390/catal8050188] |
| 30. Wang Ning, Chen Xueyan, Lu Kezhen, Zhang Xingxiang, Xiaofei Ma. (2017) The fabrication of the elastic zirconium-based carbon nanofibrous mats with three-dimensional macrostructures. MATERIALS LETTERS, [PMID:] [10.1016/j.matlet.2017.07.125] |
| 31. Ying Duan, Jun Zhang, Dongmi Li, Dongsheng Deng, Lu-Fang Ma, Yanliang Yang. (2017) Direct conversion of carbohydrates to diol by the combination of niobic acid and a hydrophobic ruthenium catalyst. RSC Advances, 7 (42): (26487-26493). [PMID:] [10.1039/C7RA03939E] |
| 32. Feng Zhao, Qi Jianqi, Huang Zhangyi, Xie Xiumin, Wei Nian, Lu Tiecheng. (2017) Optimization of the Amount and Molecular Weight of Dispersing Agent PEG During the Co-Precipitation Preparation of Nano-Crystalline C-YSZ Powder. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 17 (4): (2613-2619). [PMID:29664247] [10.1166/jnn.2017.12690] |
| 33. Lei Chen, Dazhi Sun, Jin Li, Guangdao Zhu. (2017) Exfoliation of layered zirconium phosphate nanoplatelets by melt compounding. MATERIALS & DESIGN, [PMID:] [10.1016/j.matdes.2017.03.026] |
| 34. Guo Xingzhong, Ding Li, Ren Jing, Yang Hui. (2017) Preparation of macroporous Li2ZrO3 monoliths via an epoxide-mediated sol–gel process accompanied by phase separation. JOURNAL OF POROUS MATERIALS, 24 (5): (1319-1326). [PMID:] [10.1007/s10934-017-0373-6] |
| 35. XueYu Tao, ShiXiang Zhou, ZhiMei Xiang, Jie Ma, RuiLin Hou, Yabo Zhu, XianYong Wei. (2016) Fabrication of continuous ZrB2 nanofibers derived from boron-containing polymeric precursors. JOURNAL OF ALLOYS AND COMPOUNDS, [PMID:] [10.1016/j.jallcom.2016.12.121] |
| 36. Guo Xingzhong, Ding Li, Ren Jing, Yang Hui. (2016) Preparation and CO2 capture properties of nanocrystalline Li2ZrO3 via an epoxide-mediated sol–gel process. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 81 (3): (844-849). [PMID:] [10.1007/s10971-016-4233-7] |
| 37. SU XINGHUA, WANG BENPAN, ZHOU JIE, SUN HAOYU. (2016) Synthesis and electrical field-assisted sintering behaviour of yttria-stabilized tetragonal ZrO2 nanopowders by polyacrylamide gel method. BULLETIN OF MATERIALS SCIENCE, 39 (3): (641-646). [PMID:] [10.1007/s12034-016-1186-y] |
| 38. Su Xinghua, Zhou Jie, Wang Benpan, Zhao Peng. (2016) Synthesis and electric field-assisted sintering behavior of Al2O3–ZrO2 composite nanopowders by polyacrylamide gel method. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 80 (1): (126-132). [PMID:] [10.1007/s10971-016-4085-1] |
| 39. Chen-Hao Ji, Shuang-Mei Xue, Zhen-Liang Xu, Xiao-Hua Ma. (2016) Fabrication and characterization of novel hollow fiber catalytic packing of PFSA–PES–ZrO2 (shell)–TiO2 (core) solid superacid via wet-spinning method. CHEMICAL ENGINEERING SCIENCE, [PMID:] [10.1016/j.ces.2016.05.021] |
| 40. Guo Xingzhong, Song Jie, Ren Jing, Yang Fanger, Kanamori Kazuyoshi, Nakanishi Kazuki. (2016) Facile preparation of well-defined macroporous yttria-stabilized zirconia monoliths via sol–gel process accompanied by phase separation. JOURNAL OF POROUS MATERIALS, 23 (4): (867-875). [PMID:] [10.1007/s10934-016-0143-x] |
| 41. Junchuan Zhao, Xingeng Ding, Cheng Meng, Chunrong Ren, Huiqin Fu, Hui Yang. (2015) Adsorption and immobilization of actinides using novel SiO2–ZrO2-calcium alginate aerogels from high level liquid waste. PROGRESS IN NUCLEAR ENERGY, [PMID:] [10.1016/j.pnucene.2015.09.006] |
| 42. Ying Pan, Haifeng Pan, Bihe Yuan, Ningning Hong, Jing Zhan, Bibo Wang, Lei Song, Yuan Hu. (2015) Construction of organic–inorganic hybrid nano-coatings containing α-zirconium phosphate with high efficiency for reducing fire hazards of flexible polyurethane foam. MATERIALS CHEMISTRY AND PHYSICS, [PMID:] [10.1016/j.matchemphys.2015.07.020] |
| 43. Chaohong Dong, Zhou Lu, Fengjun Zhang, Ping Zhu, Lin Zhang, Shuying Sui. (2015) Preparation and properties of cotton fabrics treated with a novel polysiloxane water repellent and flame retardant. MATERIALS LETTERS, [PMID:] [10.1016/j.matlet.2015.03.132] |
| 44. Xing Tang, Huawei Chen, Lei Hu, Weiwei Hao, Yong Sun, Xianhai Zeng, Lu Lin, Shijie Liu. (2013) Conversion of biomass to γ-valerolactone by catalytic transfer hydrogenation of ethyl levulinate over metal hydroxides. APPLIED CATALYSIS B-ENVIRONMENTAL, [PMID:] [10.1016/j.apcatb.2013.10.021] |
| 45. Fangfang Wu, Hongmin Gao, Ren Qiu, Hehua Zhang, Xinshui Ren, Xue Qi, Men Miao, Chuang Rui, Dong Chang, Hongzhi Pan. (2024) A novel ratiometric electrochemical immunosensor for the detection of cancer antigen 125 based on three-dimensional carbon nanomaterial and MOFs. MICROCHEMICAL JOURNAL, [PMID:] [10.1016/j.microc.2024.110372] |
| 46. Chengjie Huang, Xiao Zhi, Tianbao Ye, Xiuyuan Wang, Ke Li, Yiyang Li, Qiang Zhang, Lai Jiang, Xianting Ding. (2024) Boosting humoral and cellular immunity with enhanced STING activation by hierarchical mesoporous metal-organic framework adjuvants. JOURNAL OF CONTROLLED RELEASE, [PMID:38723671] [10.1016/j.jconrel.2024.05.010] |
| 47. Xiao-Ting Zhao, Wen-Dian Li, Yao Yao, Ming-Liang Shi, Yun-Jie Wei, Ru-De Lin, Fei-Yan Tao, Na Wang. (2025) Efficient chemoenzymatic cascade reaction for one-pot enantioselective synthesis of chiral indole derivatives in water. Molecular Catalysis, [PMID:] [10.1016/j.mcat.2025.115038] |
| 48. Menghuan Zhang, Yuanyuan Lu, Qingwen Lan, Yunying Fang, Tingting Ma, Shuang He, Boyi Liu, Xinqiang Liang. (2025) Paper-Based Electrochemical Approach for Highly Rapid and Sensitive Quantification of Inorganic Phosphate in Freshwater. ACS ES&T Water, [PMID:] [10.1021/acsestwater.4c01111] |
| 49. Shanshan Cong, Hongquan Yu, Sai Xu, Xiangping Li, Tianshuo Liu, Baojiu Chen. (2024) Preparation, upconversion/downshifting emissions, temperature sensing, and thermochromic properties of one-dimensional Y2Zr2O7:Er3+/Yb3+ tube-in-tube nanostructures via single-nozzle electrospinning. CERAMICS INTERNATIONAL, [PMID:] [10.1016/j.ceramint.2024.08.483] |
| 50. Jinqiu Ye, Tiancheng Ge, Xin Qu, Mohamedazeem M. Mohideen, Ce Wang, Ping Hu, Yong Liu. (2025) Spatial and anchoring effects of zirconia-doped 3D scaffolds for stable zinc anodes. CHEMICAL ENGINEERING JOURNAL, [PMID:] [10.1016/j.cej.2025.159397] |
| 51. Jinglin Zou, Xinping Duan, Xu Liu, Lele Huang, Xiaoying Liu, Jiachang Zuo, Weizhou Jiao, Haiqiang Lin, Linmin Ye, Youzhu Yuan. (2022) Identifying the activity origin of silver catalysts induced by interfacial electron localization for regioselective CO bond hydrogenation. CHEMICAL ENGINEERING JOURNAL, [PMID:] [10.1016/j.cej.2022.140110] |
| 52. Chunlei Zhang, Xia Zhu, Chenliang Peng, Chaoyi Guo. (2022) Adsorption of rare earth La3+ by α- zirconium phosphate: An experimental and density functional theory study. JOURNAL OF MOLECULAR LIQUIDS, [PMID:] [10.1016/j.molliq.2022.120668] |
| 53. Fulong Cheng, Fangui Nie, Changxin Zhao, Wei Li, Jie Pan. (2021) Efficient and stable removal of phosphate from aqueous solutions by hollow microspheres of MgO/ZrO2 composite oxide. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, [PMID:] [10.1016/j.colsurfa.2021.128095] |
| 54. Hongli Fang, Tailong Dong, ZiHuan Yuan, Xinmeng Zhang, Wei Shao. (2025) Zr4+-reinforced zwitterionic hydrogels with multiple dynamic networks for ultrasensitive strain sensing in next-generation wearable electronics. CHEMICAL ENGINEERING JOURNAL, [PMID:] [10.1016/j.cej.2025.164546] |
| 55. Diwen Xiao, Jiahao Cao, Hongjie Wang, Wenyi Dong, Fang Ma. (2026) Ce-doped MOF-801 composite sponge for high-efficiency removal of F− from wastewater: Experimental investigation and performance enhancement mechanism. SEPARATION AND PURIFICATION TECHNOLOGY, [PMID:] [10.1016/j.seppur.2026.136869] |
| 56. Diwen Xiao, Jiahao Cao, Hongjie Wang, Wenyi Dong, Fang Ma. (2026) Trimetal-organic framework composite-modified sponge for efficient removal of F− and PFAS from wastewater. CHEMICAL ENGINEERING JOURNAL, [PMID:] [10.1016/j.cej.2026.174010] |
| 57. Junjie Shu, Zongdeng Wu, Boyuan Liu, Cai Liu, Can Su, Xing Xiong, Wu Lei, Qingli Hao. (2026) One-pot hydrothermal-prepared highly electronegative ZrP-rGO nanomaterial: Enhancing corrosion resistance of low-zinc coatings by inhibiting chloride ion permeation. PROGRESS IN ORGANIC COATINGS, [PMID:] [10.1016/j.porgcoat.2026.110098] |