Ir[dFMeppy]₂-(4,4′-dCF₃bpy)PF₆ - ≥95% , CAS No.2229858-27-7

CAS: 2229858-27-7 Cat. No.: I463575 분자식: C₃₆H₂₂F₁₆IrN₄P 분자량: 1037.75 EC 번호: 889-021-1 PubChem CID: 166604231

GRADE & PURITY ≥95%

Synonyms

4,4'-Bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl]iridium(III)hexafluorophosphate | Photocatalyst

Storage

Protected from light,Argon charged,Room temperature

Shipped In

Normal

개요

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 and supersilanol；

Specifications

동의어

4,4'-Bis(trifluoromethyl)-2,2'-bipyridinebis[3,5-difluoro-2-[5-methyl-2-pyridinyl)phenyl]iridium(III)hexafluorophosphate | Photocatalyst

사양 및 순도

≥95%

보관 조건

Protected from light,Argon charged,Room temperature

배송

Normal

순수함

≥95%

이름과 식별자

• Pubchem Sid: 488203117
• 정식 스마일: CC1=CN=C(C=C1)C2=CC=CC=[C-]2.CC1=CN=C(C=C1)C2=CC=CC=[C-]2.C1=CN=C(C=C1C(F)(F)F)C2=NC=CC(=C2)C(F)(F)F.F[P-](F)(F)(F)(F)F.[Ir+3]
• 이성체 SMILES: CC1=CN=C(C=C1)C2=CC=CC=[C-]2.CC1=CN=C(C=C1)C2=CC=CC=[C-]2.C1=CN=C(C=C1C(F)(F)F)C2=NC=CC(=C2)C(F)(F)F.F[P-](F)(F)(F)(F)F.[Ir+3]
• PubChem CID: 166604231
• 분자량: 1037.75

화학 및 물리적 특성

• 감도: Light sensitive
• 녹는점(°C): ＞300°C