2-Bromopropionyl bromide - ≥97% , CAS No.563-76-8

CAS: 563-76-8 Cat. No.: B106918 Molecular Weight: 215.87 Beilstein Registry Number: 1071331 EC Number: 209-261-7
AVAILABLE TO ORDER
GRADE & PURITY ≥97%
Synonyms
DTXSID00862201 | racemic 2-bromo-propionyl bromide | 2-Bromopropionyl bromide, purum, >=97.0% (AT) | 2-Bromopropanoyl bromide # | alpha-Bromopropionyl bromide | F0001-1477 | 1,2-dibromo-propionaldehyde | Benzoic acid, p-(chlorosulfonyl)- | MFCD00000142 |
Storage
Store at 2-8°C,Argon charged
Shipped In
Wet ice,FedEx DG Service
 ·  off list, applied to all prices below.
Size
Status
Price
Qty
25g
B106918-25g
2

$10.90

$19.90
Save $9.00 (45.23%)
100g
B106918-100g
3

$30.90

$36.90
Save $6.00 (16.26%)
500g
B106918-500g
1

$108.90

$136.90
Save $28.00 (20.45%)
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Why this grade

≥97% for sensitive chromatographic and analytical workflows requiring minimal baseline interference.

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Storage & shipping

Store at 2-8°C,Argon charged Ships Wet ice,FedEx DG Service Check lot-specific COA for exact specifications.

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Quality documents

SDS, COA, datasheet, and spec sheet available for download. Lot-specific COA accessible via lot number lookup.

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Literature proof

Cited in 13 peer-reviewed publications across chromatography, organic synthesis, and cross-coupling reactions.

Specifications

Synonyms
DTXSID00862201 | racemic 2-bromo-propionyl bromide | 2-Bromopropionyl bromide, purum, >=97.0% (AT) | 2-Bromopropanoyl bromide # | alpha-Bromopropionyl bromide | F0001-1477 | 1, 2-dibromo-propionaldehyde | Benzoic acid, p-(chlorosulfonyl)- | MFCD00000142 |
Specifications & Purity
≥97%
Storage
Store at 2-8°C, Argon charged
Shipped In
Wet ice, FedEx DG Service
This product requires cold chain shipping. Ground and other economy services are not available.
Purity
≥97%
Names and Identifiers
Canonical SmilesCC(C(=O)Br)Br
IUPAC Name2-bromopropanoyl bromide
InChIKeyILLHORFDXDLILE-UHFFFAOYSA-N
INCHI1S/C3H4Br2O/c1-2(4)3(5)6/h2H,1H3
Isomeric SMILES CC(C(=O)Br)Br
WGK Germany 3
UN Number 3265
Molecular Weight 215.87
Beilstein 1071331
Reaxy-Rn 5238670
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=5238670&ln=

Documentation

📋 Safety Data Sheet (SDS)

Comprehensive hazard, handling, storage, and regulatory compliance document.

Download SDS →

✅ Certificate of Analysis (COA)

Lot-specific quality data. Enter your lot number to retrieve the exact COA.

Look up COA →

📊 Datasheet

Quick-reference summary of product specifications and applications.

View datasheet →

🔬 Specification Sheet

Full quality attributes and acceptance criteria for this grade.

View spec sheet →

Advanced Data

Taxonomic Classification

Taxonomy Tree

KingdomOrganic compounds
SuperclassOrganohalogen compounds
ClassAcyl halides
SubclassAcyl bromides
Intermediate Tree Nodes Not available
Direct ParentAcyl bromides
Alternative Parents Organobromides  Organic oxides  Hydrocarbon derivatives  Carbonyl compounds  Alkyl bromides  
Molecular FrameworkAliphatic acyclic compounds
Substituents Acyl bromide - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organooxygen compound - Organobromide - Carbonyl group - Alkyl halide - Alkyl bromide - Aliphatic acyclic compound
DescriptionThis compound belongs to the class of organic compounds known as acyl bromides. These are organic compounds containing the functional group -CO-Br.
External Descriptors Not available
3D Structure
Interactive Chemical Structure Model





Certificates(CoA,COO,BSE/TSE and Analysis Chart)
C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Find and download the COA for your product by matching the lot number on the packaging.

12 results found

Lot NumberCertificate TypeDateItem
C2328142Certificate of AnalysisMay 13, 2026 B106918
C2328152Certificate of AnalysisMay 13, 2026 B106918
C2328164Certificate of AnalysisMay 13, 2026 B106918
C2328376Certificate of AnalysisMay 13, 2026 B106918
G2030093Certificate of AnalysisMar 20, 2026 B106918
L2123307Certificate of AnalysisNov 07, 2025 B106918
L2123311Certificate of AnalysisNov 07, 2025 B106918
L2123506Certificate of AnalysisNov 07, 2025 B106918
J2215189Certificate of AnalysisOct 13, 2025 B106918
J2215190Certificate of AnalysisOct 13, 2025 B106918
J2215191Certificate of AnalysisOct 13, 2025 B106918
B2224442Certificate of AnalysisFeb 28, 2022 B106918

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Chemical and Physical Properties
SolubilityMiscible with trichloromethane, diethyl ether, benzene and acetone.
SensitivityHygroscopic.
Refractive Index1.518
Flash Point(°F)235.4 °F
Flash Point(°C)109 °C
Boil Point(°C)48-50°C/10 mmHg(155℃)
Molecular Weight215.870 g/mol
XLogP32.000
Hydrogen Bond Donor Count0
Hydrogen Bond Acceptor Count1
Rotatable Bond Count1
Exact Mass215.861 Da
Monoisotopic Mass213.863 Da
Topological Polar Surface Area17.100 Ų
Heavy Atom Count6
Formal Charge0
Complexity61.800
Isotope Atom Count0
Defined Atom Stereocenter Count0
Undefined Atom Stereocenter Count1
Defined Bond Stereocenter Count0
Undefined Bond Stereocenter Count0
The total count of all stereochemical bonds0
Covalently-Bonded Unit Count1
Citations of This Product
References
1. Jiajun Feng, Yuxian Xing, Chuantao Yin, Pengfei Tang, Feng Jiang.  (2023)  Wholly sustainable graft copolymers derived from cellulose, lignin, and hemicellulose for high-performance elastomers, adhesives, and UV-blocking materials.  CARBOHYDRATE POLYMERS,      [PMID:38142094] [10.1016/j.carbpol.2023.121606]
2. Yuye Zhu, Mengdi Liu, Min Chen, Limin Wu.  (2022)  Synthesis of blue light-responsive microspheres for autonomous self-healing coatings.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2022.138306]
3. Zhiqiang Wang, Lujun Zhang, Jiajun Feng, Pengfei Tang, Shuaishuai Chen, Hanqing Yu, Yueyao Hu, Zhongkai Wang, Feng Jiang.  (2022)  Ultra-stretchable chitin-based branched elastomers with enhanced mechanical properties via RAFT polymerization.  CARBOHYDRATE POLYMERS,      [PMID:35450643] [10.1016/j.carbpol.2022.119381]
4. Yi Zhang, Zhongning Yu, Zhenfeng Yue, Jiamin Gao, Shaojing Wu, Zhuomin Zhang, Gongke Li.  (2019)  Rapid determination of trace nitrofurantoin in cosmetics by surface enhanced Raman spectroscopy using nanoarrayed hydroxyl polystyrene-based substrate.  JOURNAL OF RAMAN SPECTROSCOPY,  50  (8): (1094-1102).  [PMID:] [10.1002/jrs.5636]
5. Liwen Wang, Yongjia Liu, Lei Bao, Dongdong Hu, Yuan Zong, Gangsheng Tong, Ling Zhao, Tao Liu.  (2018)  Preparation of acrylamide-based poly-HIPEs with enhanced mechanical strength using PVDBM-b-PEG-emulsified CO2-in-water emulsions.  JOURNAL OF APPLIED POLYMER SCIENCE,  135  (23): (46346).  [PMID:] [10.1002/app.46346]
6. Ruirui Cao, Sai Chen, Huanbing Liu, Haihui Liu, Xingxiang Zhang.  (2017)  Fabrication and characterization of thermo-responsive GO nanosheets with controllable grafting of poly(hexadecyl acrylate) chains.  JOURNAL OF MATERIALS SCIENCE,  53  (6): (4103-4117).  [PMID:] [10.1007/s10853-017-1864-1]
7. Jiayu Wu, Haiming Song, Dan Li, Weifeng Zhao, Weijie Zhang, Long Kang, Fen Ran, Changsheng Zhao.  (2017)  A effective approach for surface modification of polymer membrane via SI-eATRP in an electrochemical cell with a three electrode system.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2017.05.006]
8. Zhuomin Zhang, Cheng Zhao, Gongke Li.  (2016)  Sequential determination of trace 4-aminoazobenzene in multiple textiles based on nanoarrayed functionalized polystyrene substrate by surface enhanced Raman spectroscopy.  TALANTA,      [PMID:27154685] [10.1016/j.talanta.2016.03.068]
9. Weiya Chen, Yanbo Liu, Ying Ma, Wenxiu Yang.  (2014)  Improved performance of lithium ion battery separator enabled by co-electrospinnig polyimide/poly(vinylidene fluoride-co-hexafluoropropylene) and the incorporation of TiO2-(2-hydroxyethyl methacrylate).  JOURNAL OF POWER SOURCES,      [PMID:] [10.1016/j.jpowsour.2014.10.026]
10. Guoliang Zhang, Shufei Lu, Liang Zhang, Qin Meng, Chong Shen, Jiwei Zhang.  (2013)  Novel polysulfone hybrid ultrafiltration membrane prepared with TiO2-g-HEMA and its antifouling characteristics.  JOURNAL OF MEMBRANE SCIENCE,      [PMID:] [10.1016/j.memsci.2013.02.009]
11. Chongxiao Ge, Rui Hu, Jingyan Zhu, Jiajing Huang, Cancan Zhang, Yaqiong Zhang, Yuxian Xing, Bin Zhang, Feng Jiang.  (2025)  Combination of chitin, lignin, and plant oil for high-performance sustainable elastomers with UV-shielding and photothermal properties.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:40032115] [10.1016/j.ijbiomac.2025.141553]
12. Yuxian Xing, Yi Wei, Chongxiao Ge, Rui Hu, Yaqiong Zhang, Baoxia Wang, Zhiqiang Wang, Feng Jiang.  (2024)  Sustainable chitin-derived elastomers via grafting strategy with tunable mechanical and adhesion properties.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:39236958] [10.1016/j.ijbiomac.2024.135289]
13. Hanqing Yu, Jiajun Feng, Pengfei Tang, Shuaishuai Chen, Zhiqiang Wang, Zhongkai Wang, Feng Jiang.  (2022)  Combination of cellulose and plant oil toward sustainable bottlebrush copolymer elastomers with tunable mechanical performance.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,      [PMID:35487380] [10.1016/j.ijbiomac.2022.04.159]
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