dichloronickel,1,2-dimethoxyethane - ≥98% , CAS No.29046-78-4

CAS: 29046-78-4 Cat. No.: D299631 Formule: NiCl₂:CH₃OCH₂CH₂OCH₃ Poids moléculaire: 219.72 Numéro CE: 627-461-6 PubChem CID: 15773433

GRADE & PURITY ≥98%

Synonyms

FT-0638826 | MFCD00013481 | A903139 | Dichloro(dimethoxyethane)nickel | dichloronickel,1,2-dimethoxyethane | dichloronickel;1,2-dimethoxyethane | OCMNCWNTDDVHFK-UHFFFAOYSA-L | nickel(II) chloride dimethoxyethane | SCHEMBL1486833 | nicl2(dme) | NICKEL(II)

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Vue d’ensemble

Application：

Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:
As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.
As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.
For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.
As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.

Specifications

Synonymes

FT-0638826 | MFCD00013481 | A903139 | Dichloro(dimethoxyethane)nickel | dichloronickel,1,2-dimethoxyethane | dichloronickel;1,2-dimethoxyethane | OCMNCWNTDDVHFK-UHFFFAOYSA-L | nickel(II) chloride dimethoxyethane | SCHEMBL1486833 | nicl2(dme) | NICKEL(II)

Spécifications et pureté

≥98%

Conditions de stockage de stockage

Store at 2-8°C,Protected from light,Argon charged

Expédié en

Wet ice

Ce produit nécessite l'expédition en chaîne froide. Les services terrestres et autres services économiques ne sont pas disponibles.

Pureté

≥98%

Product Line

D299631-1g

Noms et identifiants

Pubchem Sid

508814385

Pubchem Sid Url

https://pubchem.ncbi.nlm.nih.gov/substance/508814385

Sourires canoniques

COCCOC.Cl[Ni]Cl

IUPAC Name

dichloronickel;1,2-dimethoxyethane

InChIKey

OCMNCWNTDDVHFK-UHFFFAOYSA-L

INCHI

1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

Isomères SMILES

COCCOC.Cl[Ni]Cl

WGK Allemagne

3

PubChem CID

15773433

Poids moléculaire

219.72

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • Classe Organooxygen compounds
      • Subclass Ethers

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• Classe: Organooxygen compounds
• Subclass: Ethers
• Intermediate Tree Nodes: Not available
• Direct Parent: Dialkyl ethers
• Alternative Parents: Organic transition metal salts Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Organic metal salt - Organic transition metal salt - Dialkyl ether - Hydrocarbon derivative - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as dialkyl ethers. These are organic compounds containing the dialkyl ether functional group, with the formula ROR', where R and R' are alkyl groups.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propriétés chimiques et physiques

• Sensibilité: Hygroscopic；light and moisture and heat sensitive
• Point de fusion (°C): >300 °C
• Poids moléculaire: 219.720 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 217.941 Da
• Monoisotopic Mass: 217.941 Da
• Topological Polar Surface Area: 18.500 Ų
• Heavy Atom Count: 9
• Formal Charge: 0
• Complexity: 20.300
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 2

XLogP3