Lead(II) Thiocyanate - ≥98% , CAS No.592-87-0

CAS: 592-87-0 Cat. No.: L304085 Molecular Weight: 323.36 EC Number: 209-774-6

GRADE & PURITY ≥98%

Synonyms

Isothiocyanic acid, lead(2+) salt | LEAD THIOCYANATE [MI] | SCHEMBL107555 | Lead isothiocyanate | SCHEMBL1274475 | HSDB 641 | EINECS 209-774-6 | SCHEMBL42006 | Thiocyanic acid, lead(2+) salt | Lead thiocyanate (Pb(SCN)2) | Lead dithiocyanate | UNII-7977FZ

Storage

Room temperature,Argon charged,Desiccated

Shipped In

Normal

Overview

Product Application：

Lead (II) thiocyanate can be used: To form a complex with Schiff-base lariat crown ether, N,N′-bis(3-(salicylaldimino)benzyl)-4,13-diaza-18-crown-6.

To investigate complexing and fluorescence properties of calixarene bearing two dansyl fluorophores grafted on a large pore mesoporous silica material.

As a reagent in the 1,2-dithiocyanation of alkynes in the presence of (dichloroiodo)benzene.

As a precursor to synthesize perovskite films for solar cell applications.

Specifications

Synonyms

Isothiocyanic acid, lead(2+) salt | LEAD THIOCYANATE [MI] | SCHEMBL107555 | Lead isothiocyanate | SCHEMBL1274475 | HSDB 641 | EINECS 209-774-6 | SCHEMBL42006 | Thiocyanic acid, lead(2+) salt | Lead thiocyanate (Pb(SCN)2) | Lead dithiocyanate | UNII-7977FZ

Specifications & Purity

≥98%

Storage

Room temperature, Argon charged, Desiccated

Shipped In

Normal

Purity

≥98%

Names and Identifiers

• Pubchem Sid: 488181397
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488181397
• Canonical Smiles: C(#N)[S-].C(#N)[S-].[Pb+2]
• IUPAC Name: lead(2+);dithiocyanate
• InChIKey: VRNINGUKUJWZTH-UHFFFAOYSA-L
• INCHI: 1S/2CHNS.Pb/c2*2-1-3;/h2*3H;/q;;+2/p-2
• Isomeric SMILES: C(#N)[S-].C(#N)[S-].[Pb+2]
• WGK Germany: 3
• UN Number: 2291
• Packing Group: III
• Molecular Weight: 323.36
• Reaxy-Rn: 5423743
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=5423743&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organosulfur compounds
    • Class Thiocyanates
      • Subclass Metal thiocyanates

• Kingdom: Organic compounds
• Superclass: Organosulfur compounds
• Class: Thiocyanates
• Subclass: Metal thiocyanates
• Intermediate Tree Nodes: Not available
• Direct Parent: Metal thiocyanates
• Alternative Parents: Organopnictogen compounds Organonitrogen compounds Organic lead salts Hydrocarbon derivatives
• Molecular Framework: Not available
• Substituents: Metal thiocyanate - Organic nitrogen compound - Organopnictogen compound - Hydrocarbon derivative - Organic lead salt - Organic salt - Organonitrogen compound - Aliphatic acyclic compound
• Description: This compound belongs to the class of organic compounds known as metal thiocyanates. These are metal salts of thiocyanic acid.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Solubility: cold water: soluble 200 part(lit.) water: soluble 50 part (boiling)(lit.)
• Sensitivity: Hygroscopic
• Melt Point(°C): 190 °C (dec.) (lit.)
• Molecular Weight: 323.000 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 323.927 Da
• Monoisotopic Mass: 323.927 Da
• Topological Polar Surface Area: 49.600 Ų
• Heavy Atom Count: 7
• Formal Charge: 0
• Complexity: 31.300
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

XLogP3

References

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2. Li Hong, Zaiwei Wang, Jovana V. Milić, Claudia E. Avalos, Weihua Zhang, Dan Ren, Cheng Wang, Brian Carlsen, Yuhang Liu, Shaik Mohammed Zakeeruddin, Anders Hagfeldt, Ti Wang, Hongwei Han, Michael Graetzel.  (2022)  Thiocyanate-Mediated Dimensionality Transformation of Low-Dimensional Perovskites for Photovoltaics.  CHEMISTRY OF MATERIALS,      [PMID:] [10.1021/acs.chemmater.2c00760]

3. Meidan Que, Shenghui He, Lili Gao, Boyue Zhang, Yabo Wang, Jin Chen, Bo Li, Wei Huang, Peng Zhong.  (2024)  Dual-anchored configuration involving Pb(NO3)2 for effective and stable FAPbI3 quantum dot solar cells.  Journal of Materials Chemistry C,  12  (45): (18391-18400).  [PMID:] [10.1039/D4TC02697G]

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5. Liu Jianbo, Zhang Meng, Sun Xiaoran, Xiang Linhu, Yang Xiangyu, Hu Xin, Wang Zhicheng, Hou Tian, Qin Jinzhao, Huang Yuelong, Abdi-Jalebi Mojtaba, Hao Xiaojing.  (2025)  Scalable Fabrication of Methylammonium-Free Wide-Bandgap Perovskite Solar Cells by Blade Coating in Ambient Air.  Nano-Micro Letters,  17  (1): (1-11).  [PMID:40591204] [10.1007/s40820-025-01838-6]

6. Yue Zhao, Shujie Jiao, Song Yang, Yiyin Nie, Yajie Han, Junjie He, Chenyang Tao, Dongbo Wang, Shiyong Gao, Jinzhong Wang, Liancheng Zhao.  (2024)  High-Performance All-Inorganic Perovskite Tandem Photodetectors With Bi2TeO6 Layer Enabled by Enhanced Dual Pyro-Phototronic Effect for Triple-Encryption Imaging Sensing System with Programmable Logic Gate.  ADVANCED MATERIALS,      [PMID:39648596] [10.1002/adma.202414649]

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