Tris(triphenylphosphine)rhodium(I) Chloride (NSC 124140) - ≥97% , CAS No.14694-95-2

CAS: 14694-95-2 Cat. No.: W106045 Formule: C₅₄H₄₅ClP₃Rh Poids moléculaire: 925.22 Beilstein Registry Number: 4581440 Numéro CE: 238-744-5 PubChem CID: 84599

GRADE & PURITY ≥97%

Synonyms

TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE | T0931 | NSC199379 | Chlorotris(triphenylphosphine)rhodium(I) | chlorotris(triphenylphosphine)-rhodium(i) | Tris(triphenylphosphine)rhodium(I) chloride | tris-(triphenylphosphine)rhodium(i) chloride | tris(trip

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Vue d’ensemble

Product class
M-P, Homogeneous Catalysts, Phosphorus Ligands - Achiral

Reaction type
Cross Coupling Reactions with Arenes, Allylic Alkylation, C-H Activation, Carbonylation, Mizoroki Heck Coupling Reaction, Decarbonylation, Hydroformylation, Isomerization, Oligomerization, Oxidation

Chemical properties

Chemical formula

C54H45ClP3Rh

Empirical formula

Rh(PPh3)3Cl

Molecular weight

925.23

Metal

Rh

Theoretical metal content

11

Physical state

crystalline

Color

red

Specifications

Synonymes

TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE | T0931 | NSC199379 | Chlorotris(triphenylphosphine)rhodium(I) | chlorotris(triphenylphosphine)-rhodium(i) | Tris(triphenylphosphine)rhodium(I) chloride | tris-(triphenylphosphine)rhodium(i) chloride | tris(trip

Spécifications et pureté

≥97%

Conditions de stockage de stockage

Store at 2-8°C,Protected from light,Argon charged

Expédié en

Wet ice

Ce produit nécessite l'expédition en chaîne froide. Les services terrestres et autres services économiques ne sont pas disponibles.

Pureté

≥97%

Noms et identifiants

• Pubchem Sid: 488186262
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/488186262
• Sourires canoniques: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
• IUPAC Name: rhodium;triphenylphosphane;chloride
• InChIKey: QBERHIJABFXGRZ-UHFFFAOYSA-M
• INCHI: 1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1
• Isomères SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
• WGK Allemagne: 3
• PubChem CID: 84599
• Numéro ONU: 1759
• Poids moléculaire: 925.22
• Beilstein: 4581440
• Reaxy-Rn: 14664394

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Classe Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Classe: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Organic phosphines and derivatives Organic transition metal salts Organopnictogen compounds Organic chloride salts Hydrocarbon derivatives Organic anions
• Molecular Framework: Not available
• Substituents: Triphenylphosphine - Phenylphosphine - Phosphine - Organic transition metal salt - Organopnictogen compound - Hydrocarbon derivative - Organic chloride salt - Organic salt - Organophosphorus compound - Organic anion - Aromatic homomonocyclic compound
• Description: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propriétés chimiques et physiques

• Solubilité: Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution.
• Sensibilité: Light, Air and Heat sensitive
• Point de fusion (°C): 245-250°C
• Poids moléculaire: 925.200 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 924.148 Da
• Monoisotopic Mass: 924.148 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 59
• Formal Charge: -1
• Complexity: 202.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 5

XLogP3

Références

1. Dou Chen, Gaoming Mo, Junmin Qian, Liu He, Qing Huang, Zhengren Huang.  (2020)  Synthesis of cyano-polycarbosilane and investigation of its pyrolysis process.  JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,      [PMID:] [10.1016/j.jeurceramsoc.2020.06.039]

Foire aux questions

What is the purity of this product?

This product is supplied at ≥97% purity (chemical assay). Lot-specific values are stated on the Certificate of Analysis.

How should this product be stored?

Store at 2–8 °C, protected from light, under argon. It is supplied under an argon blanket; reseal under inert gas after each use.

How is this product shipped?

This product ships chilled on wet ice. Unpack on arrival and transfer it to the storage condition stated above.

What are the CAS number, molecular formula and molecular weight?

The CAS Number is 14694-95-2, the molecular formula is C54H45ClP3Rh-, and the molecular weight is 925.22 g/mol. InChIKey QBERHIJABFXGRZ-UHFFFAOYSA-M.

What documentation is provided?

Available product documentation, including Certificates of Analysis (COA), Safety Data Sheets (SDS), and specification sheets, is shown in the product document area. Document availability and access follow the current site policy.