(3-Mercaptopropyl)triethoxysilane - ≥96%(GC) , CAS No.14814-09-6

CAS: 14814-09-6 Cat. No.: M158078 Peso molecular: 238.42 Número EC: 238-883-1

GRADE & PURITY ≥96%(GC)

Synonyms

3-triethoxysilylpropane-1-thiol | 1-Propanethiol, 3-(triethoxysilyl)- | 3-Mercaptopropyltriethoxysilane | 3-(triethoxysilyl)propane-1-thiol | 3-(Triethoxysilyl)propanethiol | 3-Triethoxysilyl-1-propanethiol

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

3-mercaptopropyl trimethoxysilane (MPTMS) is commonly used in surface modification of silica nanoparticles by creating thiol group on the surface.

Specifications

Sinónimos

3-triethoxysilylpropane-1-thiol | 1-Propanethiol, 3-(triethoxysilyl)- | 3-Mercaptopropyltriethoxysilane | 3-(triethoxysilyl)propane-1-thiol | 3-(Triethoxysilyl)propanethiol | 3-Triethoxysilyl-1-propanethiol

Especificaciones y pureza

≥96%(GC)

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥96%(GC)

Nombres e identificadores

• Sonrisas canónicas: CCO[Si](CCCS)(OCC)OCC
• IUPAC Name: 3-triethoxysilylpropane-1-thiol
• InChIKey: DCQBZYNUSLHVJC-UHFFFAOYSA-N
• INCHI: 1S/C9H22O3SSi/c1-4-10-14(11-5-2,12-6-3)9-7-8-13/h13H,4-9H2,1-3H3
• Isómeros SMILES: CCO[Si](CCCS)(OCC)OCC
• RTECS: TZ7760000
• Peso molecular: 238.42
• Reaxy-Rn: 2039575
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=2039575&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Clase Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Alkoxysilanes
          • Level6 Trialkoxysilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Clase: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Alkoxysilanes
• Direct Parent: Trialkoxysilanes
• Alternative Parents: Silyl ethers Organoheterosilanes Organic metalloid salts Alkylthiols Organooxygen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkoxysilane - Silyl ether - Organoheterosilane - Organic metalloid salt - Alkylthiol - Organic oxygen compound - Hydrocarbon derivative - Organic salt - Organosulfur compound - Organooxygen compound - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as trialkoxysilanes. These are organosilicon compounds with the general formula RO[Si](R')(OR'')OR''' (R-R''' = aliphatic organyl group).
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Hydrolyzes slowly in water.
• Sensibilidad: Moisture sensitive&Air Sensitive
• Índice de refracción: 1.44
• Punto de inflamación (°F): 190°F
• Punto de inflamación (°C): 88°C
• Punto de ebullición (°C): 210°C
• Peso molecular: 238.420 g/mol
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 9
• Exact Mass: 238.106 Da
• Monoisotopic Mass: 238.106 Da
• Topological Polar Surface Area: 28.700 Ų
• Heavy Atom Count: 14
• Formal Charge: 0
• Complexity: 118.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

XLogP3

Referencias

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64. Xuelian Wu, Xiaodong Lv, Jixiang Wang, Lin Sun, Yongsheng Yan.  (2017)  Surface molecular imprinted polymers based on Mn-doped ZnS quantum dots by atom transfer radical polymerization for a room-temperature phosphorescence probe of bifenthrin.  Analytical Methods,  9  (31): (4609-4615).  [PMID:] [10.1039/C7AY01147D]

65. Li Liu, Lihui Tian, Guanhui Zhao, Yuzhen Huang, Qin Wei, Wei Cao.  (2017)  Ultrasensitive electrochemical immunosensor for alpha fetoprotein detection based on platinum nanoparticles anchored on cobalt oxide/graphene nanosheets for signal amplification.  ANALYTICA CHIMICA ACTA,      [PMID:28870319] [10.1016/j.aca.2017.07.025]

66. Jing Neng, Jiayuan Tan, Kan Jia, Peilong Sun.  (2017)  A Fast and Cost-Effective Detection of Melamine by Surface Enhanced Raman Spectroscopy Using a Novel Hydrogen Bonding-Assisted Supramolecular Matrix and Gold-Coated Magnetic Nanoparticles.  Applied Sciences-Basel,  7  (5): (475).  [PMID:] [10.3390/app7050475]

67. Wang Shanshan, Liu Zhonghui, Bartic Carmen, Xu Hong, Ye Jian.  (2016)  Improving SERS uniformity by isolating hot spots in gold rod-in-shell nanoparticles.  JOURNAL OF NANOPARTICLE RESEARCH,  18  (8): (1-11).  [PMID:] [10.1007/s11051-016-3546-3]

68. Tao Li, Zhikun Gao, Ningwei Wang, Zhiping Zhou, Wanzhen Xu, Jianfeng Zheng, Wenming Yang.  (2016)  Synthesis and evaluation of a molecularly imprinted polymer with high-efficiency recognition for dibutyl phthalate based on Mn-doped ZnS quantum dots.  RSC Advances,  6  (59): (54615-54622).  [PMID:] [10.1039/C6RA04663K]

69. Dan Wu, Xia Xin, Xuehui Pang, Marek Pietraszkiewicz, Robert Hozyst, Xian′ge Sun, Qin Wei.  (2015)  Application of Europium Multiwalled Carbon Nanotubes as Novel Luminophores in an Electrochemiluminescent Aptasensor for Thrombin Using Multiple Amplification Strategies.  ACS Applied Materials & Interfaces,      [PMID:26005759] [10.1021/acsami.5b03381]

70. Gao Yongju, Zhao Songfang, Zhang Guoping, Deng Libo, Li Jinhui, Sun Rong, Li Liyi, Wong Ching-Ping.  (2015)  In situ assembly of dispersed Ag nanoparticles on hierarchically porous organosilica microspheres for controllable reduction of 4-nitrophenol.  JOURNAL OF MATERIALS SCIENCE,  50  (9): (3399-3408).  [PMID:] [10.1007/s10853-015-8898-z]

71. Faheem Muhammad, Mingyi Guo, Aifei Wang, Jianyun Zhao, Wenxiu Qi, Yingjie Guo, Guangshan Zhu.  (2014)  Responsive delivery of drug cocktail via mesoporous silica nanolamps.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:25151090] [10.1016/j.jcis.2014.07.024]

72. Xiao Wei, Zhiping Zhou, Jiangdong Dai, Tongfan Hao, Hongji Li, Yeqing Xu, Lin Gao, Jianming Pan, Chunxiang Li, Yongsheng Yan.  (2014)  Composites of surface imprinting polymer capped Mn-doped ZnS quantum dots for room-temperature phosphorescence probing of 2,4,5-trichlorophenol.  JOURNAL OF LUMINESCENCE,      [PMID:] [10.1016/j.jlumin.2014.07.001]

73. Yulan Wang, Yong Zhang, Yu Su, Feng Li, Hongmin Ma, He Li, Bin Du, Qin Wei.  (2014)  Ultrasensitive non-mediator electrochemical immunosensors using Au/Ag/Au core/double shell nanoparticles as enzyme-mimetic labels.  TALANTA,      [PMID:24767446] [10.1016/j.talanta.2014.02.035]

74. Qianying Sheng, Yanxiong Ke, Kuiyong Li, Dongping Yu, Xinmiao Liang.  (2013)  A novel ionic-bonded cellulose stationary phase for saccharide separation.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:23602645] [10.1016/j.chroma.2013.03.045]

75. Zhuohan Chen, Xiaojing Su, Kunquan Li, Shaoxing Niu, Zibin Shen, Xuanjun Li, Shengye Chen, Wenjian Wu.  (2024)  A thiolated TiO2-based degradable superhydrophobic wood for oil–water separation and heavy metal treatment.  SEPARATION AND PURIFICATION TECHNOLOGY,      [PMID:] [10.1016/j.seppur.2024.128949]

76. Run Gan, Yanqing Zu, Tong Zhang, Chengzhang Yang, Chujie Wang, Binglin Zeng, Peitao Liu, Xiaodong Li, Fengbo Han, Yu Qian, Lei Zhao, Ailing Feng, Zhaoxin Wu.  (2025)  Anchoring group regulation of bridging molecules enables brightly luminescent and ultra-stable Cs2ZrCl6@SiO2 scintillator for high-resolution X-ray imaging.  CERAMICS INTERNATIONAL,      [PMID:] [10.1016/j.ceramint.2025.01.111]

77. Yujie Jiang, Cancai Wang, Zhi Liu, Minghao Zhang, Jiayi Zhang, Qian Liu, Dejin Zhang, Yuetao Liu.  (2024)  Anti-corrosion and anti-fouling superhydrophobic silicone coating with continuous micro/nano structure.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2024.108230]

78. Wanmei Guo, Yongsen Yu, Chao Xin, Guangyong Jin.  (2024)  Comparative study of optical fiber immunosensors based on traditional antibody or nanobody for detecting HER2.  TALANTA,      [PMID:38810383] [10.1016/j.talanta.2024.126317]

79. Jiangning Fan, Yongtao Yu, Hong Li, Jun Yan, Ying Wang, Yongping Liao.  (2025)  Controllable synthesis and functionalization of SiO2 nanoflower for fluorine-free superhydrophobic fabrics-based oil/water mixture and emulsion separation.  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D4NJ04921G]

80. Hangchuan Cai, Congzhen Xie, Bin Gou, Jiangang Zhou, An Zhong, Daoming Zhang, Huasong Xu, Chunhui Bi, Rui Wang.  (2024)  Durable superhydrophobic insulating coatings for prevention of wet flashover and icing in power system.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2024.160768]

81. Jia-Yu Zhang, Xiu Liu, Fei-Yan Luo, Li He, Yan-Tong Li, Jia-Le Li, Yuanlin Zhou, Nan Sun, Quan-Ping Zhang.  (2024)  Enhanced dielectric constant and breakdown strength of sandwiched polymer nanocomposite film for excellent energy storage.  PHYSICAL CHEMISTRY CHEMICAL PHYSICS,      [PMID:39145725] [10.1039/D4CP02081B]

82. Mengru Geng, Jiaqi Zhao, Jie Li, Boyue Liu, Ruiming Liu, Xiaojuan Wang, Wanlong Song, Mingzhe Shao, Yihao Luan, Qun Li, Meng Gao, Fengshan Zhang, Xiaosen Pan, Ning Ma, Guigan Fang.  (2024)  Facilitating Response/Recovery of cellulosic humidity sensor by Densificating fibril Arrays.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2024.157221]

83. Li Zhang, Shuya Wang, Xuelian Liu, Zhiyong Guo, Chen Zhang, Xi Chen.  (2025)  Fluorescence Sensing for Soluble Lead Using Cellulose Membrane Extraction.  ANALYTICAL LETTERS,      [PMID:] [10.1080/00032719.2025.2481523]

84. Yabing Zhang, Xiaofeng Dai, Hongbin Shi, Tao Wang.  (2025)  Highly conductive flexible printed patterns based on magnetic core-shell copper-coated-nickel nanoparticles catalyzing dimethylamine borane electroless plating copper.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2025.106128]

85. Yang Xiong, Zihong Zhang, Ying Liu, Min Ye, Chengyao Hu, Jun Chen, Hui Yan, Yawen Huang.  (2024)  Loading of aerogels in self-healable polyurea foam to prepare superhydrophobic tough coating with ultra-long freezing delay time and high durability.  Surfaces and Interfaces,      [PMID:] [10.1016/j.surfin.2024.104763]

86. Sijia Liu, Chunshuai Cao, Dan Liu, Shiguang Pan, Aijing Ma, Hua Yuan, Hu Li, Alex T. Kuvarega, Bhekie B. Mamba, Jianzhou Gui.  (2024)  Novel phase-change material based on stearic-acid@MOFs@SiO2 with perfect impermeability promoted by coordination with unsaturated metal sites.  Journal of Energy Storage,      [PMID:] [10.1016/j.est.2024.112486]

87. Wanmei Guo, Yongsen Yu, Chao Xin, Guangyong Jin.  (2024)  Optical fiber immunosensor based on nanobody for the detection of carcinoembryonic antigen.  OPTICAL FIBER TECHNOLOGY,      [PMID:] [10.1016/j.yofte.2024.103749]

88. Yan Fang, Yanyan Zheng, Chongyi Chi, Sai Jiang, Wanbang Qin, Yicheng Zhang, Haiqing Liu, Qinhui Chen.  (2024)  PAA-PU Janus Hydrogels Stabilized by Janus Particles and its Interfacial Performance During Hemostatic Processing.  Advanced Healthcare Materials,      [PMID:38341630] [10.1002/adhm.202303802]

89. Yang Xiong, Zihong Zhang, Ying Liu, Min Ye, Chengyao Hu, Jun Chen, Yawen Huang.  (2024)  Preparation of superhydrophobic asymmetric vitrimer coating with high porosity and the key role of hierarchical pocket structure on long freeze delay time and high durability.  POLYMERS FOR ADVANCED TECHNOLOGIES,  35  (4): (e6393).  [PMID:] [10.1002/pat.6393]

90. Mengya Zhao, Hong Ren, Zhuomin Yan, Jing Ma, Xiaoping Feng, Di Liu, Fangyu Long.  (2024)  Reusable thiol-modification Lactobacillus plantarum embedded in cellulose nanocrystals composite aerogel for efficient removal of Ochratoxin A in grape juice.  Food Chemistry-X,      [PMID:38623514] [10.1016/j.fochx.2024.101336]

91. Binbin Xu, Xiaohui Meng, Juan Huang, Yun Shan, Dong Qiu, Qianjin Chen.  (2024)  Revealing the Heterogeneous Bubble Nucleation at Individual Silica Nanoparticles.  ANALYTICAL CHEMISTRY,      [PMID:38319065] [10.1021/acs.analchem.3c04411]

92. Manyi Gu, Mengyao He, Xinqing Wang, Chunyu Ding, Kunlin Chen, Yangyi Sun, Dongming Qi.  (2025)  Stretchable and robust superhydrophobic fabrics.  PROGRESS IN ORGANIC COATINGS,      [PMID:] [10.1016/j.porgcoat.2025.109239]

93. Ma Juan, Qian Lili, Jin Fei, Zheng Weiying, Li Tong, Wei Zhidong, Wang Ting, Feng Zhang-Qi.  (2024)  Super-Elastic Phenylalanine Dipeptide Crystal Fibers Enable Monolithic Stretchable Piezoelectrics for Wearable and Implantable Bioelectronics.  Advanced Fiber Materials,      [PMID:] [10.1007/s42765-024-00490-w]

94. Li Hui, Zhu Maxiaoqi, Bai Xiaolong, Xu Chenwei, Wang Tianjie, Huang Guinian, Lin Lina, Cai Yingjie.  (2024)  Synthesis of novel high-performance cotton-based superhydrophobic membranes for separation of oil/water mixtures and emulsions.  CELLULOSE,  31  (7): (4367-4380).  [PMID:] [10.1007/s10570-024-05848-2]

95. Wenjie Ma, Ru Jia, Lanlan Dong, Cijun Shuai, Wurikaixi Aiyiti, Chongxian He.  (2025)  A Ti3C2Tx-based nanosystem triggers in situ nitric oxide release to boost the antibacterial capability of scaffolds.  JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,      [PMID:] [10.1016/j.jphotochem.2025.116686]

96. Yi Niu, Xiaosen Pan, Jia Zhao, Xueyong Xie, Yuheng Lv, Yuyang Sun, Zhao Wei, Jun Wang, Yunsheng Fang.  (2025)  Pressure-Activated Breathable Liquid-Metal Electrodes for Long-Term Sleep Electroencephalogram Monitoring.  LANGMUIR,      [PMID:40864662] [10.1021/acs.langmuir.5c03081]

97. Yang Wang, Yafei Wen, Yun Qu, Zhichao Pei, Yuxin Pei.  (2022)  Pillar[5]arene based glyco-targeting nitric oxide nanogenerator for hyperthermia-induced triple-mode cancer therapy.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,      [PMID:35149352] [10.1016/j.jcis.2022.01.189]

98. Chenjian Li, Huaqing Zhang, Yiheng Song, Lixin Cai, Jima Wu, Jinxing Wu, Shan Wang, Chuanxi Xiong.  (2021)  Robust superhydrophobic and porous melamine-formaldehyde based composites for high-performance electromagnetic interference shielding.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,      [PMID:] [10.1016/j.colsurfa.2021.126742]

99. Ran Yu, Liying Pu, Xiaofang Wang, Peng Liu, Xiang Shen.  (2025)  Bioinspired Design of PVDF/SiO2-g-PEGDA Membranes Via Vapor-Induced Phase Separation for Oil/Water Separation.  LANGMUIR,      [PMID:40817872] [10.1021/acs.langmuir.5c02623]

100. Yulu Yang, Bailong Tao, Yi Gong, Rui Chen, Weihu Yang, Chuanchuan Lin, Maowen Chen, Lu Qin, Yile Jia, Kaiyong Cai.  (2020)  Functionalization of Ti substrate with pH-responsive naringin-ZnO nanoparticles for the reconstruction of large bony after osteosarcoma resection.  JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A,  108  (11): (2190-2205).  [PMID:32363788] [10.1002/jbm.a.36977]

101. Yongxing Hu, Tianpei Cai, Haijuan Zhang, Jia Chen, Zhan Li, Liang Zhao, Zuguang Li, Hongdeng Qiu.  (2019)  Two copolymer-grafted silica stationary phases prepared by surface thiol-ene click reaction in deep eutectic solvents for hydrophilic interaction chromatography.  JOURNAL OF CHROMATOGRAPHY A,      [PMID:31420178] [10.1016/j.chroma.2019.460446]

102. Wenlin Zhong, Fangping Liang, Lingling Zhong, Jiming Ou, Jianfeng He, Quanzhou Wu.  (2025)  Kaempferol Molecularly Imprinted Monolithic Columns Prepared by a Surface Imprinting Method and Their Applications to Direct Separation of Flavonoids From Ginkgo Leaves by Liquid Chromatography.  JOURNAL OF SEPARATION SCIENCE,  48  (4): (e70126).  [PMID:40205661] [10.1002/jssc.70126]

103. Zhuohui Liang, Bin Zhang, Wanying Yue, Siqi Zhang, Yuanchen Xia, Boqiao Wang, Wenbin Zhu, Jinnan Zhang.  (2025)  Suppression effects of PA@SH-SiC porous materials on hydrogen-air deflagration.  JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES,      [PMID:] [10.1016/j.jlp.2025.105664]

104. Ya-Zhao Gao, Imran Muhammad, Chun-Mei Zha, Tie-Zhen Ren, Guan Zhang, Zhi-Jun Ren, Jin-Shan Yan, Xue-Jun Zhang.  (2025)  Enhanced corrosion resistance of silicone resin: grafting nano-TiO2 onto graphene oxide via thiol–ene click chemistry.  NEW JOURNAL OF CHEMISTRY,      [PMID:] [10.1039/D5NJ00855G]

105. Xiaowen Yao, Hui Zhuang, Haotian Guo, Xinhuan Lu, Qinghua Xia, Dan Zhou.  (2025)  Catalytic hydration/hydrolysis of bulky and hydrophobic organic compounds in aqueous phase over zeolite-based catalyst efficiently.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2025.163514]

106. Chenyang Wang, Tiantian Guo, Rong Li, Shujuan Ma, Yinmao Wei, Junjie Ou.  (2025)  One-pot construction of monodisperse core-shell silica microsphere with quinine-containing hybrid fibrous shell for racemates separation.  ANALYTICA CHIMICA ACTA,      [PMID:40701719] [10.1016/j.aca.2025.344350]

107. Wei Wang, Chunlai Liu, Na Wang, Shuai Bai, Yang Wang, Jianglei Hu, Junnan Wu.  (2025)  Synthesis, characterization, and catalytic performance of tiny au nanoparticles and -SO3H bifunctionalized thick-walled organosilicon nanotubes.  INORGANIC CHEMISTRY COMMUNICATIONS,      [PMID:] [10.1016/j.inoche.2025.114921]

108. Kangwei Gongsun, Zhuyin Gang, Xiang Gao, Juan Qiu, Kanglu Feng, Chunchao Chen, Changming Bu, Xiaofan Li, Houyi Ma.  (2025)  Anion-trapping polyhedral oligomeric silsesquioxane cage structures to modify interfacial architecture for exceptional multifunctional coatings.  CHEMICAL ENGINEERING JOURNAL,      [PMID:] [10.1016/j.cej.2025.171176]

109. Tong Li, Fei Jin, Lisha Hua, Juan Ma, Fuyi Wang, Zhidong Wei, Ting Wang, Steven Wang, Zhang-Qi Feng.  (2025)  Articular neural bioelectronics by decoupling mechanical strain from electron transport.  Science Advances,  11  (48):   [PMID:41296843] [10.1126/sciadv.aea3345]

110. Feng Ding, Xiong Shuai, Shuping Peng, Cijun Shuai.  (2025)  GSNO-Loaded Mesoporous Silica/Ti3C2Tx Nanosheet Composites as Magnetic Field-Responsive Scaffolds for Nerve Differentiation via Synergistic Electrostimulation and Nitric Oxide Release.  ACS Applied Nano Materials,      [PMID:] [10.1021/acsanm.5c03899]

111. Junmeng Zhai, Zongwu Zhang, Yijie Zhou, Hanbin Zhang, Jian Jiao, Xiaoyan Ma.  (2025)  Open-cage POSS modified bismaleimide aerogels with excellent thermal properties and low dielectric constant properties via ambient pressure drying.  Materials Today Chemistry,      [PMID:] [10.1016/j.mtchem.2025.103254]

112. Feng Xiao, Yimeng Zhang, Haoran Wang, Ji Wei, Linlin Li, Hualin Wang.  (2026)  3-mercaptopropyltriethoxysilane modified zein electrospun membrane for ethylene removal and its application to banana preservation.  Food Packaging and Shelf Life,      [PMID:] [10.1016/j.fpsl.2026.101743]