Diphenyl phosphite , CAS No.4712-55-4

CAS: 4712-55-4 Cat. No.: D141299 Peso molecular: 234.19 Beilstein Registry Number: 2051909 Número EC: 225-202-8 PubChem CID: 6327546

Synonyms

NSC 43786 | F8881-1175 | Phosphorous acid, diphenyl ester | SCHEMBL20943 | FT-0635408 | 5-CHLORO-2-NITRO-BENZOYLCHLORIDE | Phosphonic acid, diphenyl ester | NCGC00254867-01 | Phosphorous Acid Diphenyl Ester | NSC-45353 | Phenyl phosphonate ((PhO)2HPO) | D

Storage

Argon charged,Room temperature

Shipped In

Normal

Descripción general

contains varying amounts of phenol and (C6H5O)3P

Reactant involved in:

Synthesis of N-benzylarylamide and di-Ph α-aminomethanephosphonate derivatives used as additives for thermooxidative stability of ester-based oils One-pot three-component Kabachnik-Fields reactions Visible light mediated oxidative phosphonylations of amines Modified asymmetric Pudovik addition with haloketones Tandem decarboxylation-coupling with natural alpha-amino acids

Specifications

Sinónimos

NSC 43786 | F8881-1175 | Phosphorous acid, diphenyl ester | SCHEMBL20943 | FT-0635408 | 5-CHLORO-2-NITRO-BENZOYLCHLORIDE | Phosphonic acid, diphenyl ester | NCGC00254867-01 | Phosphorous Acid Diphenyl Ester | NSC-45353 | Phenyl phosphonate ((PhO)2HPO) | D

Condiciones de almacenamiento de almacenamiento

Argon charged, Room temperature

Enviado en

Normal

Nombres e identificadores

• Pubchem Sid: 504764052
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504764052
• Sonrisas canónicas: C1=CC=C(C=C1)O[P+](=O)OC2=CC=CC=C2
• IUPAC Name: oxo(diphenoxy)phosphanium
• InChIKey: CDXVUROVRIFQMV-UHFFFAOYSA-N
• INCHI: 1S/C12H10O3P/c13-16(14-11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10H/q+1
• Isómeros SMILES: C1=CC=C(C=C1)O[P+](=O)OC2=CC=CC=C2
• WGK Alemania: 3
• PubChem CID: 6327546
• Peso molecular: 234.19
• Beilstein: 2051909
• Reaxy-Rn: 2051909

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Phenoxy compounds

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Phenoxy compounds
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenoxy compounds
• Alternative Parents: Organooxygen compounds Organic oxides Hydrocarbon derivatives Organic cations
• Molecular Framework: Aromatic homomonocyclic compounds
• Substituents: Phenoxy compound - Organic oxygen compound - Organic oxide - Hydrocarbon derivative - Organooxygen compound - Organic cation - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as phenoxy compounds. These are aromatic compounds contaning a phenoxy group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Moisture sensitive
• Índice de refracción: 1.56
• Punto de inflamación (°F): 186°C(lit.)
• Punto de inflamación (°C): 186°C(lit.)
• Punto de ebullición (°C): 148 °C/2 mmHg
• Punto de fusión (°C): 12°C(lit.)
• Peso molecular: 233.180 g/mol
• XLogP3: 3.100
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 233.037 Da
• Monoisotopic Mass: 233.037 Da
• Topological Polar Surface Area: 35.500 Ų
• Heavy Atom Count: 16
• Formal Charge: 1
• Complexity: 198.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

Referencias

1. Chen Zhong, Haoran Zhu, Yinying Sheng, Jin Wo, Deqiang You, Guodong Sun, Zhentao Yu, Wei Li, Xiaojian Wang.  (2023)  Biocompatibility and osteogenic potential of choline phosphate chitosan-coated biodegradable Zn1Mg.  Acta Biomaterialia,      [PMID:38096961] [10.1016/j.actbio.2023.12.014]

2. Yinying Sheng, Junjie Yang, Xueyang Zhao, Hui Liu, Shaogang Cui, Lianxi Chen, Rong Zeng, Xiaojian Wang, Chi-Hsien Huang, Wei Li.  (2020)  Development and In Vitro Biodegradation of Biomimetic Zwitterionic Phosphorylcholine Chitosan Coating on Zn1Mg Alloy.  ACS Applied Materials & Interfaces,      [PMID:33231070] [10.1021/acsami.0c16662]

3. Yinying Sheng, Junjie Yang, Ruiqing Hou, Lianxi Chen, Jiesheng Xu, Hui Liu, Xueyan Zhao, Xiaojian Wang, Rong Zeng, Wei Li, Yimin (Mike) Xie.  (2020)  Improved biocompatibility and degradation behavior of biodegradable Zn-1Mg by grafting zwitterionic phosphorylcholine chitosan (PCCs) coating on silane pre-modified surface.  APPLIED SURFACE SCIENCE,      [PMID:] [10.1016/j.apsusc.2020.146914]

4. Wenwen Guo, Yuyu Zhao, Xin Wang, Wei Cai, Junling Wang, Lei Song, Yuan Hu.  (2020)  Multifunctional epoxy composites with highly flame retardant and effective electromagnetic interference shielding performances.  COMPOSITES PART B-ENGINEERING,      [PMID:] [10.1016/j.compositesb.2020.107990]