Jones reagent - 2 M CrO3 in aqueous H2SO4 , CAS No.65272-70-0

CAS: 65272-70-0 Cat. No.: J487208 Peso molecular: 198.08 Número EC: 863-656-4 PubChem CID: 117063819

GRADE & PURITY 2 M CrO3 in aqueous H2SO4

Synonyms

Chromium trioxide solution in sulfuric acid, Jone′s reagent, Sulfuric acid-chromium trioxide mixture

Storage

Room temperature

Descripción general

Jones reagent is a solution of chromium trioxide in aqueous sulfuric acid.Using acetone as a reaction solvent, the reagent is usually used for the oxidation of primary and secondary alcohols to carboxylic acids and ketones, respectively.The oxidation is very rapid and exothermic.The reagent tolerates a variety of functionalities, such as, for example, unsaturated bonds, which are rarely oxidized.For a comprehensive review of chromium-based reagents, see "Oxidation of Alcohols to Aldehydes and Ketones" by Tojo and Fernández, Springer Berlin, 2006, 1-97.Jones reagent can be used:In the oxidative cleavage of various alkenes into carboxylic acids and ketones using a catalytic amount of osmium tetroxide.To prepare symmetrical binaphthols by oxidative dehydrodimerization of substituted naphthols.To synthesize acyl-naphthols and substituted isocoumarins from 2-(4-hydroxy-but-1-ynyl)benzaldehydes.

Specifications

Sinónimos

Chromium trioxide solution in sulfuric acid, Jone′s reagent, Sulfuric acid-chromium trioxide mixture

Especificaciones y pureza

2 M CrO3 in aqueous H2SO4

Condiciones de almacenamiento de almacenamiento

Room temperature

Nombres e identificadores

• Sonrisas canónicas: OS(=O)(=O)O.O=[Cr](=O)=O
• IUPAC Name: sulfuric acid;trioxochromium
• InChIKey: HNPXHFOTGAXAJY-UHFFFAOYSA-N
• INCHI: 1S/Cr.H2O4S.3O/c;1-5(2,3)4;;;/h;(H2,1,2,3,4)
• Isómeros SMILES: OS(=O)(=O)O.O=[Cr](=O)=O
• PubChem CID: 117063819
• Número ONU: 3098
• Peso molecular: 198.08

Propiedades químicas y físicas

• Punto de inflamación (°F): Not applicable
• Punto de inflamación (°C): Not applicable