Pentamethylcyclopentadienylrhodium(III) chloride dimer - ≥97% , CAS No.12354-85-7

CAS: 12354-85-7 Cat. No.: P470206 Peso molecular: 618.08 Número EC: 625-704-0

GRADE & PURITY ≥97%

Synonyms

Bis(pentamethylcyclopentadienylrhodium dichloride), Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex, Dichloro(pentamethylcyclopentadienyl

Storage

Room temperature

Descripción general

Description

Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactionsUmicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactions

Specifications

Sinónimos

Bis(pentamethylcyclopentadienylrhodium dichloride), Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium, Bis(dichloro(pentamethylcyclopentadienyl)rhodium), 1, 3-Cyclopentadiene, 1, 2, 3, 4, 5-pentamethyl-, rhodium complex, Dichloro(pentamethylcyclopentadienyl

Especificaciones y pureza

≥97%

Condiciones de almacenamiento de almacenamiento

Room temperature

Pureza

≥97%

Nombres e identificadores

• Sonrisas canónicas: Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
• InChIKey: QNIVKTTWBMFSBR-UHFFFAOYSA-J
• INCHI: 1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
• WGK Alemania: 3
• Peso molecular: 618.08

Propiedades químicas y físicas

• Punto de fusión (°C): >300°C

Referencias

1. Ying Zhang, Bin Wei, Hao Liang.  (2023)  Rhodium-Based MOF-on-MOF Difunctional Core–Shell Nanoreactor for NAD(P)H Regeneration and Enzyme Directed Immobilization.  ACS Applied Materials & Interfaces,      [PMID:36609187] [10.1021/acsami.2c18440]

2. Jie Xiang, Junyi Zhang, Shunmei Li, Ruo Yuan, Yun Xiang.  (2022)  Aptamer-based and sensitive label-free colorimetric sensing of phenylalanine via cascaded signal amplifications.  ANALYTICA CHIMICA ACTA,      [PMID:36192064] [10.1016/j.aca.2022.340393]

3. Xiewen Wu, Song Wang, Jing Fang, Hui Chen, Hongbo Liu, Run Li.  (2022)  Enhanced Photocatalytic Efficiency in Visible-Light-Induced NADH Regeneration by Intramolecular Electron Transfer.  ACS Applied Materials & Interfaces,      [PMID:35986690] [10.1021/acsami.2c11174]

4. Yuanyuan Zhang, Jian Liu.  (2022)  Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction.  CHEMISTRY-A EUROPEAN JOURNAL,  28  (55): (e202201430).  [PMID:35758216] [10.1002/chem.202201430]

5. Fang Lan, Qin Wang, Hui Chen, Yi Chen, Yuanyuan Zhang, Bowen Huang, Hongbo Liu, Jian Liu, Run Li.  (2020)  Preparation of Hydrophilic Conjugated Microporous Polymers for Efficient Visible Light-Driven Nicotinamide Adenine Dinucleotide Regeneration and Photobiocatalytic Formaldehyde Reduction.  ACS Catalysis,      [PMID:] [10.1021/acscatal.0c03652]

6. Yizhou Wu, Jesse Ward-Bond, Donglin Li, Shaohua Zhang, Jiafu Shi, Zhongyi Jiang.  (2018)  g-C3N4@α-Fe2O3/C Photocatalysts: Synergistically Intensified Charge Generation and Charge Transfer for NADH Regeneration.  ACS Catalysis,      [PMID:] [10.1021/acscatal.8b00070]

7. Shihao Li, Jiafu Shi, Yu Chen, Xinyu Mao, Shusong Liu, Yang Yang, Hong Wu, Zhongyi Jiang.  (2025)  Light-Driven Synthesis of 2-Aminoethanol from Formaldehyde and Ammonia.  ACS Catalysis,      [PMID:] [10.1021/acscatal.5c00337]

8. Xinyu Chen, Jiahui Xie, Hui Wang, Yujie Tang, Yezhou Yang, Pilang Zheng, Qihua Yang, Xin Liu, Xiaobo Li.  (2025)  Multifunctional Nano-COF-Embedded Silica Composite for Efficient Photocatalytic NADH Regeneration.  CHEMISTRY-A EUROPEAN JOURNAL,      [PMID:40350757] [10.1002/chem.202500115]

9. Shihao Li, Jiafu Shi, Yu Chen, Hong Wu, Zhongyi Jiang.  (2026)  Engineering substrate reduction and product oxidation in photocatalytic NADH synthesis via interface–pore co-confinement.  AICHE JOURNAL,      [PMID:] [10.1002/aic.70263]