Trimethylsilyl azide - ≥93% , CAS No.4648-54-8

CAS: 4648-54-8 Cat. No.: T107307 Peso molecular: 115.21 Beilstein Registry Number: 1903730 Número EC: 225-078-5 PubChem CID: 78378

GRADE & PURITY ≥93%

Synonyms

Trimethylsilicon azide | azido(trimethyl)silane | Trimethylsilylazide | Silane, azidotrimethyl- | TMS azide | TMS-azide | Trimethylazidosilane | Azidotrimethylsilane

Storage

Store at 2-8°C,Argon charged

Shipped In

Wet ice

Descripción general

Trimethylsilyl azide is a versatile azidonation reagent for amines, amides, aldehydes, and ketones.
A versatile azidonation reagent

Specifications

Sinónimos

Trimethylsilicon azide | azido(trimethyl)silane | Trimethylsilylazide | Silane, azidotrimethyl- | TMS azide | TMS-azide | Trimethylazidosilane | Azidotrimethylsilane

Especificaciones y pureza

≥93%

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Argon charged

Enviado en

Wet ice

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Pureza

≥93%

Nombres e identificadores

• Sonrisas canónicas: C[Si](C)(C)N=[N+]=[N-]
• IUPAC Name: azido(trimethyl)silane
• InChIKey: SEDZOYHHAIAQIW-UHFFFAOYSA-N
• INCHI: 1S/C3H9N3Si/c1-7(2,3)6-5-4/h1-3H3
• Isómeros SMILES: C[Si](C)(C)N=[N+]=[N-]
• WGK Alemania: 3
• PubChem CID: 78378
• Número ONU: 1992
• Peso molecular: 115.21
• Beilstein: 1903730
• Reaxy-Rn: 1903730

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organometallic compounds
    • Clase Organometalloid compounds
      • Subclass Organosilicon compounds
        • Level5 Organoheterosilanes
          • Level6 Trialkylheterosilanes

• Kingdom: Organic compounds
• Superclass: Organometallic compounds
• Clase: Organometalloid compounds
• Subclass: Organosilicon compounds
• Intermediate Tree Nodes: Organoheterosilanes
• Direct Parent: Trialkylheterosilanes
• Alternative Parents: Organic azides Organic metalloid salts N-silyl compounds Organic nitrogen compounds Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Trialkylheterosilane - Organic azide - N-silyl compound - Organic metalloid salt - Organic nitrogen compound - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound
• Descripción: This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Soluble in water (decomposes), dichloromethane, ether, chloroform, and ethyl acetate.
• Sensibilidad: Moisture and Heat sensitive
• Índice de refracción: 1.415
• Punto de inflamación (°F): 73.4 °F
• Punto de inflamación (°C): 6 °C
• Punto de ebullición (°C): 97°C
• Punto de fusión (°C): -95℃
• Peso molecular: 115.210 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 115.057 Da
• Monoisotopic Mass: 115.057 Da
• Topological Polar Surface Area: 14.400 Ų
• Heavy Atom Count: 7
• Formal Charge: 0
• Complexity: 97.200
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 1
• The total count of all stereochemical bonds: 1
• Covalently-Bonded Unit Count: 1

XLogP3

Referencias

1. Bin Zhang, Jia Hao, Zheng Sun, Xiaomin Zhao, Jing Zhang, Zhiqing Ma.  (2022)  Non-food bioactive products for botanical pesticides: Insights into residue and dissipation kinetics of matrine-type alkaloids from Sophora alopecuroides.  INDUSTRIAL CROPS AND PRODUCTS,      [PMID:] [10.1016/j.indcrop.2022.116032]

2. Henghui Huang, Qi Yao, Xiuping Zhang, Haijiang Wang.  (2022)  Microporous expanded polytetrafluoroethylene layer functionalized hydrophilic groups for excellent mechanical durability and superior performance in proton exchange membrane fuel cell.  JOURNAL OF POWER SOURCES,      [PMID:] [10.1016/j.jpowsour.2022.231130]

3. Wenpeng Gong, Li Zhang, Ying Yu, Bixia Lin, Yumin Wang, Manli Guo, Yujuan Cao.  (2021)  A novel fluorescent strategy based on double modifications of metal organic framework material CAU-10-NH2 for low background and high sensitivity determination of H2S.  TALANTA,      [PMID:33838773] [10.1016/j.talanta.2021.122271]

4. Chen Jiakai, Wang Danni, Wang Bing, Zhou Chengwei, Ding Chuan-Fan, Yan Yinghua.  (2024)  Ti4+ functionalized zirconium metal-organic frameworks with polymer brushes for specific identification of phosphopeptides in human serum and skimmed milk.  ANALYTICAL AND BIOANALYTICAL CHEMISTRY,      [PMID:38877148] [10.1007/s00216-024-05388-5]