Tris(triphenylphosphine)rhodium(I) Chloride (NSC 124140) - ≥99.9% metals basis , CAS No.14694-95-2

CAS: 14694-95-2 Cat. No.: T475094 Peso molecular: 925.22 Beilstein Registry Number: 4581440 Número EC: 238-744-5 PubChem CID: 84599

GRADE & PURITY ≥99.9% metals basis

Synonyms

TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE | NSC199379 | Chlorotris(triphenylphosphine)rhodium(I) | chlorotris(triphenylphosphine)-rhodium(i) | Tris(triphenylphosphine)rhodium(I) chloride | tris-(triphenylphosphine)rhodium(i) chloride | tris(triphenylpho

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Descripción general

Description

Hydrosilylation CatalystsCatalyst used for many organic reactions including:Chemoselective allylic alkylationsStoichiometric activation of Si-H bonds and hydrosilylationsInter- and intramolecular hydroacylation of alkenes along with a cocatalystPolymerization of diorganostannanesUseful catalyst for the efficient cross-coupling of activated alkenyl tosylates with arylboronic acids. Also used to catalyze the cleavage of allyl phenolic ethers to phenols with DABCO.

Specifications

Sinónimos

TRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE | NSC199379 | Chlorotris(triphenylphosphine)rhodium(I) | chlorotris(triphenylphosphine)-rhodium(i) | Tris(triphenylphosphine)rhodium(I) chloride | tris-(triphenylphosphine)rhodium(i) chloride | tris(triphenylpho

Especificaciones y pureza

≥99.9% metals basis

Condiciones de almacenamiento de almacenamiento

Store at 2-8°C, Protected from light, Argon charged

Enviado en

Wet ice

Este producto requiere envío en cadena de frío. Los servicios terrestres y otros servicios económicos no están disponibles.

Pureza

≥99.9% metals basis

Nombres e identificadores

• Sonrisas canónicas: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
• IUPAC Name: rhodium;triphenylphosphane;chloride
• InChIKey: QBERHIJABFXGRZ-UHFFFAOYSA-M
• INCHI: 1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/p-1
• Isómeros SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
• WGK Alemania: 3
• PubChem CID: 84599
• Número ONU: 1759
• Peso molecular: 925.22
• Beilstein: 4581440
• Reaxy-Rn: 14664394

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Organic phosphines and derivatives Organic transition metal salts Organopnictogen compounds Organic chloride salts Hydrocarbon derivatives Organic anions
• Molecular Framework: Not available
• Substituents: Triphenylphosphine - Phenylphosphine - Phosphine - Organic transition metal salt - Organopnictogen compound - Hydrocarbon derivative - Organic chloride salt - Organic salt - Organophosphorus compound - Organic anion - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Sensibilidad: Light & Air & Heat sensitive
• Punto de fusión (°C): 245-250°C
• Peso molecular: 925.200 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 924.148 Da
• Monoisotopic Mass: 924.148 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 59
• Formal Charge: -1
• Complexity: 202.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 5

XLogP3

Referencias

1. Dou Chen, Gaoming Mo, Junmin Qian, Liu He, Qing Huang, Zhengren Huang.  (2020)  Synthesis of cyano-polycarbosilane and investigation of its pyrolysis process.  JOURNAL OF THE EUROPEAN CERAMIC SOCIETY,      [PMID:] [10.1016/j.jeurceramsoc.2020.06.039]