Tris(triphenylphosphine)ruthenium(II) dichloride - ≥98% , CAS No.15529-49-4

CAS: 15529-49-4 Cat. No.: T111252 Peso molecular: 958.83 Beilstein Registry Number: 4935939 Número EC: 239-569-7 PubChem CID: 11007548

GRADE & PURITY ≥98%

Synonyms

tris (triphenylphosphine) ruthenium (11) chloride | RuCl2(PPh3)3 | Ruthenium, dichlorotris(triphenylphosphine)- | Dichlorotris(triphenylphosphine)ruthenium(II), Premion? | Tris(triphenylphosphine)ruthenium(II) dichloride | Dichlorotris(triphenylphosphino)

Storage

Argon charged,Room temperature

Shipped In

Normal

Specifications

Sinónimos

tris (triphenylphosphine) ruthenium (11) chloride | RuCl2(PPh3)3 | Ruthenium, dichlorotris(triphenylphosphine)- | Dichlorotris(triphenylphosphine)ruthenium(II), Premion? | Tris(triphenylphosphine)ruthenium(II) dichloride | Dichlorotris(triphenylphosphino)

Especificaciones y pureza

≥98%

Condiciones de almacenamiento de almacenamiento

Argon charged, Room temperature

Enviado en

Normal

Pureza

≥98%

Nombres e identificadores

• Pubchem Sid: 504765874
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504765874
• Sonrisas canónicas: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru]Cl
• IUPAC Name: dichlororuthenium;triphenylphosphane
• InChIKey: WIWBLJMBLGWSIN-UHFFFAOYSA-L
• INCHI: 1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
• Isómeros SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ru]Cl
• WGK Alemania: 3
• PubChem CID: 11007548
• Peso molecular: 958.83
• Beilstein: 4935939
• Reaxy-Rn: 14715227

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Benzenoids
    • Clase Benzene and substituted derivatives
      • Subclass Phenylphosphines and derivatives

• Kingdom: Organic compounds
• Superclass: Benzenoids
• Clase: Benzene and substituted derivatives
• Subclass: Phenylphosphines and derivatives
• Intermediate Tree Nodes: Not available
• Direct Parent: Phenylphosphines and derivatives
• Alternative Parents: Organic phosphines and derivatives Organic transition metal salts Organic metal halides Organopnictogen compounds Organic chloride salts Hydrocarbon derivatives
• Molecular Framework: Not available
• Substituents: Triphenylphosphine - Phenylphosphine - Phosphine - Organic metal halide - Organic transition metal salt - Organopnictogen compound - Hydrocarbon derivative - Organic chloride salt - Organic salt - Organophosphorus compound - Aromatic homomonocyclic compound
• Descripción: This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Propiedades químicas y físicas

• Solubilidad: Insoluble in water.
• Sensibilidad: Air & Moisture Sensitive
• Punto de fusión (°C): 159°C
• Peso molecular: 958.800 g/mol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 958.115 Da
• Monoisotopic Mass: 958.115 Da
• Topological Polar Surface Area: 0.000 Ų
• Heavy Atom Count: 60
• Formal Charge: 0
• Complexity: 204.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 4

XLogP3

Referencias

1. Lanqing Deng, Lang Chen, Liangdi Zhu, Yang Li, Jie Ou-Yang, Shaofeng Wu, Peng Chen, Sheng Shen, Junkang Guo, Yongbo Zhou, Chak-Tong Au, Shuang-Feng Yin.  (2022)  Green, versatile, and scale-up synthesis of amides by aerobic oxidative amination over Ag2O/P-C3N4 photocatalyst.  CHEMICAL ENGINEERING SCIENCE,      [PMID:] [10.1016/j.ces.2022.117960]