D-Psicose - ≥98%, used for D-Psicose has been used in a study to assess the bioconversion of D-fructose to D-allose. It has also been used in a study that investigated the characteristics and antioxidant activity of maillard reaction products. various ap

CAS: 551-68-8 Cat. No.: P120931 분자식: C₆H₁₂O₆ 분자량: 180.16 Beilstein Registry Number: 1(4)4400 EC 번호: 208-999-7

GRADE & PURITY ≥98%

Synonyms

(3R,4R,5R)-1,3,4,5,6- pentahydroxyhexan-2-one | (3R,4R,5R)-1,3,4,5,6-pentahydroxyhexan-2-one, D-ribo-2-Hexulose

Storage

Store at 2-8°C

Shipped In

Wet ice

개요

D-Psicose protects and preserves pancreatic β-islets through the maintenance of hyperglycemia and by the prevention of fat accumulation in Otsuka Long-Evans Tokushima Fatty rats.

Specifications

동의어

(3R,4R,5R)-1,3,4,5,6- pentahydroxyhexan-2-one | (3R,4R,5R)-1,3,4,5,6-pentahydroxyhexan-2-one, D-ribo-2-Hexulose

사양 및 순도

≥98%

애플리케이션

D-Psicose has been used in a study to assess the bioconversion of D-fructose to D-allose. It has also been used in a study that investigated the characteristics and antioxidant activity of maillard reaction products.

보관 조건

Store at 2-8°C

배송

Wet ice

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순수함

≥98%

이름과 식별자

• Pubchem Sid: 504756012
• Pubchem Sid Url: https://pubchem.ncbi.nlm.nih.gov/substance/504756012
• 정식 스마일: C(C(C(C(C(=O)CO)O)O)O)O
• IUPAC Name: (3R,4R,5R)-1,3,4,5,6-pentahydroxyhexan-2-one
• InChIKey: BJHIKXHVCXFQLS-PUFIMZNGSA-N
• INCHI: 1S/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h3,5-9,11-12H,1-2H2/t3-,5-,6+/m1/s1
• 이성체 SMILES: C([C@H]([C@H]([C@H](C(=O)CO)O)O)O)O
• WGK 독일: 3
• 분자량: 180.16
• Beilstein: 1(4)4400
• Reaxy-Rn: 2207947
• Reaxys-RN_link_address: https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=2207947&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Organic compounds
  • Superclass Organic oxygen compounds
    • 분류 Organooxygen compounds
      • Subclass Carbohydrates and carbohydrate conjugates

• Kingdom: Organic compounds
• Superclass: Organic oxygen compounds
• 분류: Organooxygen compounds
• Subclass: Carbohydrates and carbohydrate conjugates
• Intermediate Tree Nodes: Not available
• Direct Parent: Monosaccharides
• Alternative Parents: Beta-hydroxy ketones Acyloins Alpha-hydroxy ketones Secondary alcohols Polyols Primary alcohols Organic oxides Hydrocarbon derivatives
• Molecular Framework: Aliphatic acyclic compounds
• Substituents: Monosaccharide - Beta-hydroxy ketone - Acyloin - Alpha-hydroxy ketone - Secondary alcohol - Ketone - Polyol - Organic oxide - Hydrocarbon derivative - Primary alcohol - Carbonyl group - Alcohol - Aliphatic acyclic compound
• 설명: This compound belongs to the class of organic compounds known as monosaccharides. These are compounds containing one carbohydrate unit not glycosidically linked to another such unit, and no set of two or more glycosidically linked carbohydrate units. Monosaccharides have the general formula CnH2nOn.
• External Descriptors: psicose

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

작용 메커니즘

화학 및 물리적 특성

• 용해성: Soluble in water; Soluble in Methanol,Ethanol; Insoluble in Acetone
• 특정 회전[α]: 4°(C=1,H2O)
• 녹는점(°C): 109°C
• 분자량: 180.160 g/mol
• XLogP3: -3.200
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 180.063 Da
• Monoisotopic Mass: 180.063 Da
• Topological Polar Surface Area: 118.000 Ų
• Heavy Atom Count: 12
• Formal Charge: 0
• Complexity: 147.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 3
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 1

참고 문헌

1. Mei-Ling Liu, Lan Hong, Yueming Zhu, Razi Epsztein, Ting Shi, Yuanxia Sun, Zhijun Xu, Shi-Peng Sun, Weihong Xing.  (2023)  Constructing biocatalytic nanochannel membranes for unidirectional isomer conversion and separation.  AICHE JOURNAL,  69  (11): (e18187).  [PMID:] [10.1002/aic.18187]

2. Shuangshuang Duan, Yonghua Chen, Guodong Wang, Zebin Li, Shitong Dong, Yingshuai Wu, Yuanwei Wang, Chunling Ma, Ruiming Wang.  (2023)  A study of targeted mutation of l-rhamnose isomerase to improve the conversion efficiency of D-allose.  ENZYME AND MICROBIAL TECHNOLOGY,      [PMID:37245327] [10.1016/j.enzmictec.2023.110259]

3. Xiaofeng Zhang, Xinqi Xu, Xuemei Yao, Rong Wang, Hengtao Tang, Xin Ju, Liangzhi Li.  (2020)  Exploring Multifunctional Residues of Ribose-5-phosphate Isomerase B from Ochrobactrum sp. CSL1 Enhancing Isomerization of d-Allose.  JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,      [PMID:32100533] [10.1021/acs.jafc.9b07855]